Selectfluor-mediated regioselective nucleophilic functionalization of N-heterocycles under metal- and base-free conditions

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Selectfluor-mediated regioselective nucleophilic functionalization of N-heterocycles under metal- and base-free conditions

Xie, Long-Yong; Qu, Jie; Peng, Sha; Liu, Kai-Jian; Wang, Zheng; Ding, Man-Hua; Wang, Yi; Cao, Zhong; He, Wei-Min

Green chemistry : an international journal and green chemistry resource : GC, 2018, Volume: 20, Issue: 3

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A practical and environmentally attractive methodology for the direct diversification of N-heterocycles at ambient temperature under open-air conditions was developed. The obvious advantage of the process is that no toxic reagent, transition metal, base or other additive is employed, thus greatly reducing costs, facilitating post-reaction neutralization and purification and minimizing the environmental impact.

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