Cage-rearranged and cage-intact syntheses of azido-functionalized larger T10 and T12 POSSs

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Cage-rearranged and cage-intact syntheses of azido-functionalized larger T10 and T12 POSSs

Wang, Hui; Ming-Xi Nie; Lin, Xiong; Xiang-Qian, Li; Liu, Hao; Qing-Yun Guo; Han, Di; Fu, Qiang

Dalton transactions : an international journal of inorganic chemistry, 06/2024, Volume: 53, Issue: 22

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Herein, we investigate the product type and distribution during the synthesis of azido-functionalized larger polyhedral oligomeric silsesquioxanes (POSSs) using 3-chloropropyl- and chloromethyldimethylsilylethyl-functionalized T8, T10, and T12 POSSs as precursors. Our findings indicate that cage rearrangement occurs for the 3-chloropropyl-functionalized POSS cages with a stability order of T12 > T10 > T8, while the chloromethyldimethylsilylethyl-functionalized POSS cages remain structurally intact after the nucleophilic substitution.

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