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Xi-Meng, Chen; Xing-Chao, Yu; Jing-Xian Chi; Yi, Jing; Wang, Hongju; Zhang, Na; Zhang, Chen; Yi-Wen, Ge; Chen, Xuenian
Dalton transactions : an international journal of inorganic chemistry, 12/2023, Volume: 52, Issue: 47Journal Article
An efficient method for the synthesis of M2B10H14 (M = Na and K) has been developed. The two possible formation mechanisms of the B10H142− anion are proposed, in which the NH2BH3− anion acts as a proton abstractor and a hydride donor. Furthermore, the B10H13− and B10H15− intermediates were detected.
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