Thiazolium salt-catalyzed C-C triple bond cleavage for accessing substituted 1-naphthols via benzannulation

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Thiazolium salt-catalyzed C-C triple bond cleavage for accessing substituted 1-naphthols via benzannulation

Zhou, Peng; Wang, Jia-Yin; Zhang, Tian-Shu; Li, Guigen; Hao, Wen-Juan; Tu, Shu-Jiang; Jiang, Bo

Chemical communications (Cambridge, England), 01/2018, Volume: 54, Issue: 2

Journal Article

The first thiazolium salt-catalyzed C-C triple bond cleavage of benzene-linked allene-ynes has been established. The reaction pathway involves 2+2 cycloaddition and ring-opening of in situ generated cyclobutenes with H O under mild and convenient conditions, and provides practical access to substituted 1-naphthols with potentially valuable applications.

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