H-Bonded anion–anion complex trapped in a squaramido-based receptor

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H-Bonded anion–anion complex trapped in a squaramido-based receptor

Prohens, Rafel; Portell, Anna; Font-Bardia, Mercè; Bauzá, Antonio; Frontera, Antonio

Chemical communications (Cambridge, England), 2018, Volume: 54, Issue: 15

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Herein we report the experimental observation (X-ray characterization) of an anion–anion complex (anion = hydrogen fumarate) stabilized by H-bonds that is trapped in a secondary squaramide receptor. High level ab initio calculations indicate that the anion–anion complex is thermodynamically unstable but kinetically stable with respect to the isolated anions.

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Prohens, Rafel | Portell, Anna | Font-Bardia, Mercè | Bauzá, Antonio | Frontera, Antonio

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