E-resources
Peer reviewed
-
Shan, Yun; Sun, Xuhao; Zhu, Yuan; Wang, Ying; Li, Tinghui
Catalysis letters, 06/2023, Volume: 153, Issue: 6Journal Article
The electrocatalysis of CO.sub.2 reduction to formic acid (HCOOH) as a useful chemical fuel has attracted much attention, but is facing the dilemma of low conversion efficiency. Herein, a series of transition elements were intentionally implanted into layered Bi.sub.2SeO.sub.2 surface to act as bimetallic reactive sites for decreasing the rate-limiting barriers. The calculations disclose that the doped 3d-metals can partially changes the electronic state distribution of 6 s lone pair electrons in Bi.sup.3+cation, in which this particular orbital hybridization leads to an intriguing bonding interaction between dopants and neighboring Se/O atomic layers. This interlayer electronic state coupling makes the half-filled dopants demonstrate the spin-resolved charge transfer and orbital interaction between bimetallic sites and reactants, because of the localized atomic distortion and electronic reconfiguration. This work provides a new insight into engineering surficial electronic structure and catalytic activity.
Shelf entry
Permalink
- URL:
Impact factor
Access to the JCR database is permitted only to users from Slovenia. Your current IP address is not on the list of IP addresses with access permission, and authentication with the relevant AAI accout is required.
Year | Impact factor | Edition | Category | Classification | ||||
---|---|---|---|---|---|---|---|---|
JCR | SNIP | JCR | SNIP | JCR | SNIP | JCR | SNIP |
Select the library membership card:
If the library membership card is not in the list,
add a new one.
DRS, in which the journal is indexed
Database name | Field | Year |
---|
Links to authors' personal bibliographies | Links to information on researchers in the SICRIS system |
---|
Source: Personal bibliographies
and: SICRIS
The material is available in full text. If you wish to order the material anyway, click the Continue button.