Copper(I)-Catalyzed Carboxylation of Aryl- and Alkenylboronic Esters

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Copper(I)-Catalyzed Carboxylation of Aryl- and Alkenylboronic Esters

Takaya, Jun; Tadami, Satoshi; Ukai, Kazutoshi; Iwasawa, Nobuharu

Organic letters, 07/2008, Volume: 10, Issue: 13

Journal Article

The copper(I)-catalyzed carboxylation reaction of aryl- and alkenylboronic esters proceeded smoothly under CO2 to give the corresponding carboxylic acid in good yield. This reaction showed wide generality with higher functional group tolerance compared to the corresponding Rh(I)-catalyzed reaction.

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Takaya, Jun | Tadami, Satoshi | Ukai, Kazutoshi | Iwasawa, Nobuharu

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