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Xu, Gang; Otsubo, Kazuya; Yamada, Teppei; Sakaida, Shun; Kitagawa, Hiroshi
Journal of the American Chemical Society, 05/2013, Volume: 135, Issue: 20Journal Article
The electrical properties of a highly oriented crystalline MOF nanofilm were studied. This nanofilm has low activation energy and a proton conductivity that is among the highest value reported for MOF materials. The study uncovered the reasons for the excellent performance of this nanofilm and revealed a new pathway for proton transport in MOF materials; besides the channels inside a MOF, the surface of the MOF nanocrystal can also dominate proton transport.
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