ABSTRACT The Advanced LIGO and Virgo detectors opened a new era to study black holes (BHs) in our Universe. A population of stellar-mass binary black holes (BBHs) are discovered to be heavier than previously expected. These heavy BBHs provide us an opportunity to achieve multiband observation with ground-based and space-based gravitational-wave (GW) detectors. In this work, we use BBHs discovered by the LIGO/Virgo Collaboration as indubitable examples, and study in great detail the prospects for multiband observation with GW detectors in the near future. We apply the Fisher matrix to spinning, non-precessing inspiral-merger-ringdown waveforms, while taking the motion of space-based GW detectors fully into account. Our analysis shows that, detectors with decihertz sensitivity are expected to log stellar-mass BBH signals with very large signal-to-noise ratio and provide accurate parameter estimation, including the sky location and time to coalescence. Furthermore, the combination of multiple detectors will achieve unprecedented measurement of BBH properties. As an explicit example, we present the multiband sensitivity to the generic dipole radiation for BHs, which is vastly important for the equivalence principle in the foundation of gravitation, in particular for those theories that predict curvature-induced scalarization of BHs.