•LMO with specific facets and different morphologies are controlled synthesized.•LMO-MST delivers superior rate capability up to 124.2 mAh g−1 at 10 C.•LMO-MST demonstrates 84.3 % capacity retention after 1000 cycles at 10 C.•LMO-MST cathodes still maintains optimal cycling stability at 55 and -5°C.•The superior performance results from sphere-bridged-tube structure and {111} facets. Recently, spinel-type LiMn2O4 (LMO) cathode has attracted great attention to mitigate manganese dissolution especially at elevated temperature. In this work, LMO with surface specific facets and different morphologies are successfully controlled synthesized via a facile solvothermal-lithiation method. It suggests that microspheres, micro-tubes and hybrid sphere-interconnected-tube microstructures with different surface lattice orientation using urea, oxalic acid and mixture of urea and oxalic acid as precipitants at solvothermal stage, respectively. Specifically, LMO microspheres (LMO-MS) display (111) facets and the micro-tubular LMO materials (LMO-MT) exhibit the high index lattice (311). It is more interesting is that hybrid sphere-interconnected-tube microstructures (LMO-MST) are clearly observed the densest (111) facets at the micro-spherical surface and a new (111) plane appearance on the surface of microtubes. LMO-MST demonstrates excellent cycling performance (84.3 % capacity retention after 1000 cycles at 10 C) and superior rate capability up to 10 C (124.2 mAh g−1 at 10 C). The electrochemical performances of LMO-MST cathodes are also investigated at elevated (55°C) and lower (-5°C) temperatures, under which LMO-MST still maintains optimal cycling stability. The superior electrochemical performance of LMO-MST cathodes can be attributed to the unique sphere-bridged-tube seamless outer structure and the preferentially exposed stable facets on the crystal surface. Hybrid micro-nanostructured LMO sphere-bridged-tube with {111} facets demonstrates superior rate capability and cycling performance both under 55 and -5°C. Display omitted