Constructing four six-dimensional mutually unbiased bases (MUBs) is an open problem in quantum physics and measurement. We investigate the existence of four MUBs including the identity, and a complex Hadamard matrix (CHM) of Schmidt rank three. The CHM is equivalent to a controlled unitary operation on the qubit-qutrit system via local unitary transformation  ⊗  and  ⊗  . We show that and have no zero entry, and apply it to exclude constructed examples as members of MUBs. We further show that the maximum of entangling power of controlled unitary operation is log 3 ebits. We derive the condition under which the maximum is achieved, and construct concrete examples. Our results describe the phenomenon that if a CHM of Schmidt rank three belongs to an MUB then its entangling power may not reach the maximum.