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Lamare, Raphaël; Ruppert, Romain; Boudon, Corinne; Ruhlmann, Laurent; Weiss, Jean
Chemistry : a European journal, November 22, 2021, 2021-11-22, 20211122, Volume: 27, Issue: 65Journal Article
Polyoxometalates (POMs) can act as unique reservoirs for multiple electron transfers. As POMs display only weak absorption in the visible spectrum, they can be associated with chromophores such as porphyrins and porphyrin antennae. In this Minireview, the research dedicated to the combination of porphyrins and polyoxometalates is put in context and the state of the art identifying the challenges addressed in the optimization of hybrid materials for applications is detailed. Winning combo: Porphyrins and polyoxometalates can be combined into useful architectures for energy conversion, this minireview highlights the most successful strategies developed to date.
