E-resources
Peer reviewed
-
Yang, Ji-Min; Hu, Xiao-Wei; Liu, Yi-Xuan; Zhang, Wei
Microporous and mesoporous materials, 01/2019, Volume: 274Journal Article
Metal-organic framework-based composite nanomaterials usually exhibit synergetic properties of their components leading to new functionalities and can be used for a wide range of applications. In this study, we designed and synthesized an amine-CQDs@UiO-66 composite fluorescence sensor by integrating amine-functionalized carbon quantum dots (amine-CQDs) and the zirconium-based metal-organic frameworkUiO-66 using a post-synthetic modification approach (PSMA). Herein, UiO-66 was used as an adsorbent to capture and enrich the target molecules selectively and the amine-CQDs were employed as a functional monomer to selectively and sensitively sense the bonding interactions between UiO-66 and the target molecules, andfurther transduce these chemical events into detectable fluorescence signals. The resulting amine-CQDs@UiO-66 sensor exhibited excellent fluorescence selectivity and sensitivity toward 4-nitrophenol (4-NP) because of the immobilized highly fluorescent amine-CQDs. The fluorescence sensitivity was increased because of the enrichment of 4-NP that originated from the well-defined microporous MOF. Moreover, 4-NP could be detected in a wide concentration range of 0.01–20.0 μM with a detectionlimit as low as 3.5 nM. To the best of our knowledge, this work presents the first combination of the fluorescence functional monomer amine-CQDs with the favorable properties of MOFs by PSMA for selective fluorescence sensing. We fabricated amine-CQDs@UiO-66 composites via a post-synthetic modification approach, incorporating amine-functionalized carbon quantum dots functional monomers that could respond to the analyte 4-nitrophenol (4-NP). We found it to be highly selective and sensitive for 4-NP, detecting this species even in mixtures of metal ions and other phenols. Display omitted •Amine-CQDs@UiO-66 composites were prepared via post-synthetic approach.•Amine-CQDs@UiO-66 composites were found to be excellent FL probes for 4-NP detection.•Amine-CQDs@UiO-66 composites have high selective sensing performance for 4-NP.
Shelf entry
Permalink
- URL:
Impact factor
Access to the JCR database is permitted only to users from Slovenia. Your current IP address is not on the list of IP addresses with access permission, and authentication with the relevant AAI accout is required.
Year | Impact factor | Edition | Category | Classification | ||||
---|---|---|---|---|---|---|---|---|
JCR | SNIP | JCR | SNIP | JCR | SNIP | JCR | SNIP |
Select the library membership card:
If the library membership card is not in the list,
add a new one.
DRS, in which the journal is indexed
Database name | Field | Year |
---|
Links to authors' personal bibliographies | Links to information on researchers in the SICRIS system |
---|
Source: Personal bibliographies
and: SICRIS
The material is available in full text. If you wish to order the material anyway, click the Continue button.