E-resources
-
He, Hongming; Sun, Qi; Gao, Wenyang; Perman, Jason A.; Sun, Fuxing; Zhu, Guangshan; Aguila, Briana; Forrest, Katherine; Space, Brian; Ma, Shengqian
Angewandte Chemie International Edition, April 16, 2018, Volume: 57, Issue: 17Journal Article
A majority of metal–organic frameworks (MOFs) fail to preserve their physical and chemical properties after exposure to acidic, neutral, or alkaline aqueous solutions, therefore limiting their practical applications in many areas. The strategy demonstrated herein is the design and synthesis of an organic ligand that behaves as a buffer to drastically boost the aqueous stability of a porous MOF (JUC‐1000), which maintains its structural integrity at low and high pH values. The local buffer environment resulting from the weak acid–base pairs of the custom‐designed organic ligand also greatly facilitates the performance of JUC‐1000 in the chemical fixation of carbon dioxide under ambient conditions, outperforming a series of benchmark catalysts. A buffer strategy boosts the aqueous stability of a MOF over a broad range of pH values. The local buffer environment resulting from the weak acid–base pairs (green/blue bars on right of picture) of the custom‐designed organic ligand also greatly facilitates the performance of MOF in chemical fixation of carbon dioxide under ambient conditions.
Author
![loading ... loading ...](themes/default/img/ajax-loading.gif)
Shelf entry
Permalink
- URL:
Impact factor
Access to the JCR database is permitted only to users from Slovenia. Your current IP address is not on the list of IP addresses with access permission, and authentication with the relevant AAI accout is required.
Year | Impact factor | Edition | Category | Classification | ||||
---|---|---|---|---|---|---|---|---|
JCR | SNIP | JCR | SNIP | JCR | SNIP | JCR | SNIP |
Select the library membership card:
If the library membership card is not in the list,
add a new one.
DRS, in which the journal is indexed
Database name | Field | Year |
---|
Links to authors' personal bibliographies | Links to information on researchers in the SICRIS system |
---|
Source: Personal bibliographies
and: SICRIS
The material is available in full text. If you wish to order the material anyway, click the Continue button.