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Lehn, Jean-Marie
Angewandte Chemie (International ed.), March 4, 2013, Volume: 52, Issue: 10Journal Article
Chemistry is progressively unraveling the processes that underlie the evolution of matter towards states of higher complexity and the generation of novel features along the way by self‐organization under the pressure of information. Chemistry has evolved from molecular to supramolecular to become adaptive chemistry by way of constitutional dynamics, which allow for adaptation, through component selection in an equilibrating set. Dynamic systems can be represented by weighted dynamic networks that define the agonistic and antagonistic relationships between the different constituents linked through component exchange. Such networks can be switched through amplification/up‐regulation of the best adapted/fittest constituent(s) in a dynamic set. Accessing higher level functions such as training, learning, and decision making represent future lines of development for adaptive chemical systems. Chemistry is key for understanding the fundamental processes that underlie the evolution of matter towards states of increasing complexity through self‐organization. It has developed from the molecular to the supramolecular level and has, through constitution dynamic systems, acquired the features of adaptive chemistry. Hence, chemistry opens the door towards complex matter.
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