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Zhang, Ze Ping; Rong, Min Zhi; Zhang, Ming Qiu
Advanced functional materials, March 14, 2018, Volume: 28, Issue: 11Journal Article
Stimuli‐responsive polymers built by reversible covalent bonds used to possess unbalanced mechanical properties. Here, a crosslinked polyurethane containing aromatic pinacol as a novel reversible CC bond provider is synthesized, whose tensile strength and failure strain are tunable from 27.3 MPa to as high as 115.2 MPa and from 324% to 1501%, respectively, owing to the relatively high bond energy of the CC bond of pinacol as well as the hydrogen bond between hard segments and semicrystalline soft segments. Moreover, the dynamic equilibrium of pinacol enables self‐healing and recycling of the polymer. Interestingly, the dynamic exchange among macromolecules, for the first time, successfully cooperates with solid‐state drawing that applies to thermoplastics, realizing strengthening of thermoset. Meanwhile, the radicals derived from homolysis of pinacol can repeatedly initiate polymerization of vinyl monomers. The fruitful outcomes of this work may create a series of promising new techniques. The CC bond of pinacol is dynamically reversible at moderate temperature. A crosslinked polyurethane carrying pinacol unit is synthesized, which can be self‐healed, reprocessed, and recycled via the catalyst‐free reversible homolysis/radicals recombination of the CC bond. Moreover, its strength can be greatly improved by solid‐state drawing. The radicals created during homolysis are enabled to repeatedly initiate polymerization of vinyl monomers.
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