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Liu, Hao‐Yang; Zhang, Jia‐Rong; Huang, Guo‐Bao; Zhou, Yi‐Huan; Chen, Yan‐Yan; Xu, Yan‐Li
Advanced synthesis & catalysis, March 16, 2021, Volume: 363, Issue: 6Journal Article
A simple and efficient visible‐light‐promoted selenylation/cyclization of enaminones have been realized for the practical synthesis of 3‐selanyl‐4H‐chromen‐4‐ones. This reaction is performed in the mild conditions, no transition metal catalyst or photocatalysts and no additional oxidants are required. In addition, the 3‐selanyl‐4H‐chromen‐4‐ones could be easily converted to selanyl‐functionalized pyrimidines by reacting with benzamidine substrates.
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