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Xie, Hexin; Zhang, Yinan; Zhang, Shilei; Chen, Xiaobei; Wang, Wei
Angewandte Chemie (International ed.), December 2, 2011, Volume: 50, Issue: 49Journal Article
Highly efficient: The title reaction provides biologically interesting chiral trifluoromethyl dihydroquinazolinone frameworks in high yields (up to 97 %) and with high enantioselectivities (up to 98 % ee), using as low as 1 mol % of catalyst (see scheme). Moreover, anti‐HIV drug candidate DPC 083 was efficiently synthesized using the highly enantioselective aza‐Henry reaction as a key step.
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