Guest-induced symmetry lowering of an ionic clathrate material for carbon capture

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Guest-induced symmetry lowering of an ionic clathrate material for carbon capture

Muromachi, S; Udachin, K A; Shin, K; Alavi, S; Moudrakovski, I L; Ohmura, R; Ripmeester, J A

Chemical communications (Cambridge, England), 2014-Oct-09, Volume: 50, Issue: 78

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We report a new lattice structure of the ionic clathrate hydrate of tetra-n-butylammonium bromide induced by guest CO2 molecules, which is found to provide high CO2 storage capacity. The structure was characterized by a set of methods, including single crystal X-ray diffraction, NMR, and MD simulations.

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