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Cheng, Dao-Juan; Yan, Liang; Tian, Shi-Kai; Wu, Ming-Yue; Wang, Lu-Xin; Fan, Zi-Li; Zheng, Sheng-Cai; Liu, Xin-Yuan; Tan, Bin
Angewandte Chemie (International ed.), April 1, 2014, Volume: 53, Issue: 14Journal Article
A highly efficient strategy for the kinetic resolution of axially chiral BINAM derivatives involving a chiral Brønsted acid‐catalyzed imine formation and transfer hydrogenation cascade process was developed. The kinetic resolution provides a convenient route to chiral BINAM derivatives in high yields with excellent enantioselectivities. Chiral BINAMs on demand: A highly efficient strategy for the kinetic resolution of axially chiral BINAM derivatives involving a chiral Brønsted acid catalyzed imine formation and transfer hydrogenation cascade process was developed. The kinetic resolution provides a convenient route to chiral BINAM derivatives in high yields with excellent enantioselectivities.
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