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Wu, Fu‐Peng; Yuan, Yang; Schünemann, Claas; Kamer, Paul C. J.; Wu, Xiao‐Feng
Angewandte Chemie International Edition, June 22, 2020, Volume: 59, Issue: 26Journal Article
The borocarbonylative coupling of unactivated alkenes with alkyl halides remains a challenge. In this communication, a Cu‐catalyzed borocarbonylative coupling of unactivated alkenes with alkyl halides for the synthesis of β‐boryl ketones has been developed. A broad range of β‐boryl ketone derivatives was prepared in moderate to excellent yields with complete regioselectivity. The borocarbonylative coupling of unactivated alkenes with alkyl halides remains a challenge. A Cu‐catalyzed borocarbonylative coupling of unactivated alkenes with alkyl halides for the synthesis of β‐boryl ketones has been developed. A broad range of β‐boryl ketone derivatives was prepared in moderate to excellent yields with complete regioselectivity.
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