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Xiang, Shengchang; Zhou, Wei; Zhang, Zhangjing; Green, Mark A; Liu, Yun; Chen, Banglin
Angewandte Chemie (International ed.), June 21, 2010, Volume: 49, Issue: 27Journal Article
On the metal: Open metal sites within isostructural M2(DHTP) metal–organic frameworks (M=Co2+, Mn2+, Mg2+, and Zn2+; DHTP=2,5‐dihydroxyterephthalate) exhibit differential molecular recognition with acetylene. The extremely strong interaction of Co2+ with acetylene (see structure) makes Co2(DHTP) the highest volumetric acetylene storage material with a capacity of 230 cm3 cm−3 at 295 K and 1 atm.
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