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Schumacher, Daniel; Wilhelm, Michaela; Rezwan, Kurosch
Materials & design, 12/2018, Volume: 160Journal Article
Applications such as filtration require not only control over the pore structure but also over properties like surface characteristics and mechanical strength. The addition of filler particles to solution based freeze casting of preceramic polymers combines the flexibilities of freeze casting and preceramic polymers. Alumina platelets, silica spheres and preceramic filler particles with different compositions were frozen in solution based freeze casting of preceramic polymers with cyclohexane as solvent. Methyl- and methyl-phenyl polysiloxanes as well as (3-aminopropyl)triethoxysilane were used as precursors and cross-linking agent, respectively. The compressive strength increases by factors of up to 1.9 (25 vol% preceramic filler) due to enhanced isotropy of the dendritic pore structure. At lower concentrations (1.7 vol%), alumina platelets are more effective in strengthening than spherical particles. In dependence on the composition of the preceramic filler, BET surface area and the ratio of vapor uptake between water and heptane change by factors of up to 1.19 and 16, respectively. Calculations according to a linear rule of mixture fit very well with the experimental data. In summary, the versatile approach to add differing filler particles to solution based freeze casting allows for tailoring the pore structure as well as surface characteristics of macroporous monolithic samples. Display omitted •Addition of preceramic and ceramic fillers overcomes limitations of solution based freeze-casting of polysiloxanes.•Enhanced isotropy of pore structure increases the compressive strength by factors of up to 1.9.•Different chemical compositions of filler particles allow for altering the BET surface area from 276.4-535.2 m2g-1.•Ratio of water to heptane uptake as a measure of hydrophilicity can be adjusted in a range from 0.13-2.86.•Linear rule of mixture precisely predicts hydrophilicity and BET surface area and allows design of properties.
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