Polimerizacija 4-(supstituiranih amino)stirena: III. dio – spontana polimerizacija 4-(benzilamino) stirenskih soli

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Polimerizacija 4-(supstituiranih amino)stirena: III. dio – spontana polimerizacija 4-(benzilamino) stirenskih soli

GABR, Yasin A

Polimeri, 10/2003, Volume: 24, Issue: 1

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Ispitana je spontana polimerizacija 4-aminostiren-benzil klorida i / ili benzil bromida. Rezultati ukazuju da 4-aminostiren reakcijom s benzil halidima i / ili nekim od supstituenata tvori odgovarajuće 4-(benzilamino) stirenske soli koje spontano polimeriziraju u vodenoj otopini kao i u organskim otapalima. Polimerizacijom nastaju poli 4-(benzilamino)stiren soli. Brzine reakcija ukazuju da je tok reakcije određen polarnošću otapala, vrstom halidnog iona i temperaturom, pri čemu nije primijećen bitan utjecaj supstituenata na benzilnom dijelu molekule.

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