By using the real-place Recursion method,the effects of alloying additions (Nb, Ta, Y, La) on glass forming ability(GFA) and corrosion resistance of bulk Zr-based amorphous alloys are studied. An atomic group model in the Zr2Ni primary crystalline phase centered to Ni atom are constructed by computer programming. We have calculated the total bond order integral (£BOI) between Ni atom and its neighbor elements (Nb, Ta, Y, La), also calculated the Fermi energy level of alloying elements. The calculation results show that the XBOI and the glass forming ability are greatly enhanced after Y substitution. Nb, Ta, La decrease the GFA and La has little influence on the GFA of the alloys.Nb, Y, La enable Zr-based amorphous easy to passive and increase corrosion resistance. Therefore, Y and La are most effective on glass forming ability and corrosion resistance of Zr-based amorphous alloys. By addition of minor Y and La can produce the new bulk amorphous alloys with good corrosion resistance.