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An approach to calculate thermodynamic properties of mixtures including Propane, n-Butane, and IsobutaneAvsec, Jurij ; Watanabe, Koichi, 1938-This paper discusses a mathematical model for computing the thermodynamic properties of propane, n-butane, isobutane, and their mixtures, in the fluid phase using a method based upon statistical ... chain theory. The constants necessary for computations such as the characteristic temperatures of rotation, electronic state, etc. and the moments of inertia are obtained analytically applying a knowledge of the atomic structure of the molecule. The paper presents a procedure for calculating thermodynamic properties such aspressure, speed of sound, the Joule-Thomson coefficient, compressibility, enthalpy, and thermal expansion coefficient. This paper will discuss, for the first time, the application of statistical chain theory for accurate properties of binary and ternary mixtures including propane, n-butane, and isobutane, in their entire fluid phases. To calculate the thermodynamic properties of Lennard-Jones chains, the Liu-Li-Lu model has been used. The thermodynamic properties of the hydrocarbon mixtures are obtained using the one-fluid theory.Vir: International journal of thermophysics. - ISSN 0195-928X (Vol. 26, no 6, Nov. 2005, str. 1769-1780)Vrsta gradiva - članek, sestavni delLeto - 2005Jezik - angleškiCOBISS.SI-ID - 10086678
Avtor
Avsec, Jurij |
Watanabe, Koichi, 1938-
Teme
statistična termodinamika |
teorija verig |
mešanice |
transportne lastnosti |
ogljikovodiki |
izobutan |
n-butan |
propan |
hladila |
statistical thermodynamics |
chain theory |
mixtures |
transport properties |
hydrocarbons |
isobutane |
n-butane |
propane |
refrigerants
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Avsec, Jurij | 10827 |
Watanabe, Koichi, 1938- | ![]() |
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