Akademska digitalna zbirka SLovenije - logo
VSE knjižnice (vzajemna bibliografsko-kataložna baza podatkov COBIB.SI)
  • Nanoprecipitation of cellulose acetate using solvent/nonsolvent mixtures as dispersive media
    Kulterer, Martin R. ...
    An efficient nanoprecipitation technique using good cellulose acetate (CA) solvents as modifier for the dispersive media (nonsolvent) was developed for the generation of CA nanoparticles. Addition of ... tetrahydrofuran (THF) to the nonsolvent leads to smaller particles than obtained with pure water or standard stabilizing agents like surfactants and block copolymers. Sonication, efficient agitation, and optimization of process parameters like temperature, THF content, pH value and stirrer velocity reduces nanoparticle sizes and improves substrate recoveries. With the optimized process, spherical nanoparticles of 60 nm with 87% yield can be generated reproducibly. This is obtained by addition of good polymer solvents (tetrahydrofuran (THF)) to a nonsolvent (water) and applying those mixtures as nonsolvents for nanoprecipitation. Main theoretical models in discussion are not able to explain sufficiently the particle size reduction by the addition of a good polymer solvent to the nonsolvent. CA nanoparticles can be used to produce ultrathin layers deposited onto positively charged surfaces. Possible applications are seen in surface science (e.g. surface modifications and surface functionalization of CA foils and membranes).
    Vir: Colloids and surfaces. A, Physicochemical and Engineering Aspects. - ISSN 0927-7757 (Vol. 375, iss. 1/3, 2011, str. 23-29)
    Vrsta gradiva - članek, sestavni del
    Leto - 2011
    Jezik - angleški
    COBISS.SI-ID - 14756886
    DOI

Vnos na polico