Akademska digitalna zbirka SLovenije - logo
VSE knjižnice (vzajemna bibliografsko-kataložna baza podatkov COBIB.SI)
  • Profiling the tuneable R-SMS-Phos structure in the rhodium(I)-catalyzed hydrogenation of olefins : the last stand?
    Stephan, Michel ...
    A diversified family of enantiopure P-stereogenic ĆR-SMS-PhosĆ {R-SMS-Phos = 1,2-bis[(o-RO-phenyl)(phenyl)phosphino]ethane} ligands wherein R = branched orheteroatom-substituted alkyl, aralkyl, ... silyl, acyl, sulfonyl, etc. was screened for the Rh(I)-catalyzed hydrogenation of a representative set of olefinic substrates. This systematic and detailed investigation revealed a marked beneficial impact on enantioselectivity and catalyst activity in comparison to Knowlesć ultimate DiPAMP {DiPAMP = 1,2-bis[(o-anisyl)(phenyl)phosphino]ethane} design. Mutant ligands with highlyenhanced properties possessing particular features wherein the DiPAMP structure is found embedded were identified.
    Vir: Organic and Biomolecular Chemistry. - ISSN 1477-0520 (Vol. 9, issue 14, 2011, str. 5266-5271)
    Vrsta gradiva - članek, sestavni del
    Leto - 2011
    Jezik - angleški
    COBISS.SI-ID - 4698650
    DOI

vir: Organic and Biomolecular Chemistry. - ISSN 1477-0520 (Vol. 9, issue 14, 2011, str. 5266-5271)
loading ...
loading ...
loading ...