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  • An investigation of the role of acetone on the synthesis of two porous iron carboxylates [Elektronski vir]
    Birsa Čelič, Tadeja ...
    Metal-organic framework materials (MOFs) are currently attracting a tremendous amount of interest because of their unique chemical and structural characteristics, which enable a variety of ... applications. Many researches have focused on the synthesis of new MOF materials and systematically investigated the role of pH, temperature, concentration, and time on their crystallisation. Special emphasis has been recently put on the influence of the solvent properties, typically DMF, alcohols, ketones, alkanes, water and their mixtures, on the formation and structure transformations of MOFs. Here we report on the controlling role of acetone in the syntheses of two iron benzene-1,3,5-tricarboxylates MIL-45(Fe) [4] and MIL-100(Fe) [5] from the same reagents.
    Vrsta gradiva - prispevek na konferenci
    Leto - 2011
    Jezik - angleški
    COBISS.SI-ID - 4751386