All life on Earth contains amino acids and carbonaceous chondrite meteorites have been suggested as their source at the origin of life on Earth. While many meteoritic amino acids are considered ...indigenous, deciphering the extent of terrestrial contamination remains an issue. The Ryugu asteroid fragments (JAXA Hayabusa2 mission), represent the most uncontaminated primitive extraterrestrial material available. Here, the concentrations of amino acids from two particles from different touchdown sites (TD1 and TD2) are reported. The concentrations show that N,N-dimethylglycine (DMG) is the most abundant amino acid in the TD1 particle, but below detection limit in the other. The TD1 particle mineral components indicate it experienced more aqueous alteration. Furthermore, the relationships between the amino acids and the geochemistry suggest that DMG formed on the Ryugu progenitor body during aqueous alteration. The findings highlight the importance of aqueous chemistry for defining the ultimate concentrations of amino acids in primitive extraterrestrial samples.
The pristine sample from the near-Earth carbonaceous asteroid (162173) Ryugu collected by the Hayabusa2 spacecraft enabled us to analyze the pristine extraterrestrial material without uncontrolled ...exposure to the Earth's atmosphere and biosphere. The initial analysis team for the soluble organic matter reported the detection of wide variety of organic molecules including racemic amino acids in the Ryugu samples. Here we report the detection of uracil, one of the four nucleobases in ribonucleic acid, in aqueous extracts from Ryugu samples. In addition, nicotinic acid (niacin, a B
vitamer), its derivatives, and imidazoles were detected in search for nitrogen heterocyclic molecules. The observed difference in the concentration of uracil between A0106 and C0107 may be related to the possible differences in the degree of alteration induced by energetic particles such as ultraviolet photons and cosmic rays. The present study strongly suggests that such molecules of prebiotic interest commonly formed in carbonaceous asteroids including Ryugu and were delivered to the early Earth.
We developed universal sample holders the Kochi grid, Kochi clamp, and Okazaki cell) and a transfer vessel (facility-to-facility transfer container (FFTC) to analyze sensitive and fragile samples, ...such as extremely small extraterrestrial materials. The holders and container prevent degradation, contamination due to the terrestrial atmosphere (water vapor and oxygen gas) and small particles, as well as mechanical sample damage. The FFTC can isolate the samples from the effects of the atmosphere for more than a week. The Kochi grid and clamp were made for a coordinated micro/nano-analysis that utilizes a focused-ion beam apparatus, transmission electron microscope, and nanoscale secondary ion mass spectrometry. The Okazaki cell was developed as an additional attachment for a scanning transmission X-ray microscope that uses near-edge X-ray absorption fine structure (NEXAFS). These new apparatuses help to minimize possible alterations from the exposure of the samples to air. The coordinated analysis involving these holders was successfully carried out without any sample damage or loss, thereby enabling us to obtain sufficient analytical datasets of textures, crystallography, elemental/isotopic abundances, and molecular functional groups for µm-sized minerals and organics in both the Antarctic micrometeorite and a carbonaceous chondrite. We will apply the coordinated analysis to acquire the complex characteristics in samples obtained by the future spacecraft sample return mission.
Japan Aerospace Exploration Agency (JAXA) launched the asteroid exploration probe “Hayabusa2” in December 3rd, 2014, following the 1st Hayabusa mission. With technological and scientific improvements ...from the Hayabusa probe, we plan to visit the C-type asteroid 162137 Ryugu (1999 JU3), and to sample surface materials of the C-type asteroid that is likely to be different from the S-type asteroid Itokawa and contain more pristine materials, including organic matter and/or hydrated minerals, than S-type asteroids. We developed the Hayabusa2 sampler to collect a minimum of 100 mg of surface samples including several mm-sized particles at three surface locations without any severe terrestrial contamination. The basic configuration of the sampler design is mainly as same as the 1st Hayabusa (Yano et al. in Science, 312(5778):1350–1353,
2006
), with several minor but important modifications based on lessons learned from the Hayabusa to fulfill the scientific requirements and to raise the scientific value of the returned samples.
In this paper, we will report the details of the sampling system of Hayabusa2 with results of performance tests during the development and the current status of the sampling system.
Chondrule-like objects and Ca-Al-rich inclusions (CAIs) are discovered in the retuned samples from asteroid Ryugu. Here we report results of oxygen isotope, mineralogical, and compositional analysis ...of the chondrule-like objects and CAIs. Three chondrule-like objects dominated by Mg-rich olivine are
O-rich and -poor with Δ
O (=δ
O - 0.52 × δ
O) values of ~ -23‰ and ~ -3‰, resembling what has been proposed as early generations of chondrules. The
O-rich objects are likely to be melted amoeboid olivine aggregates that escaped from incorporation into
O-poor chondrule precursor dust. Two CAIs composed of refractory minerals are
O-rich with Δ
O of ~ -23‰ and possibly as old as the oldest CAIs. The discovered objects (<30 µm) are as small as those from comets, suggesting radial transport favoring smaller objects from the inner solar nebula to the formation location of the Ryugu original parent body, which is farther from the Sun and scarce in chondrules. The transported objects may have been mostly destroyed during aqueous alteration in the Ryugu parent body.
Abstract The analysis of samples returned from the C-type asteroid Ryugu has drastically advanced our knowledge of the evolution of early solar system materials. However, no consensus has been ...obtained on the chronological data, which is important for understanding the evolution of the asteroid Ryugu. Here, the aqueous alteration age of Ryugu particles was determined by the Mn–Cr method using bulk samples, yielding an age of 4.13 + 0.62/−0.55 Myr after the formation of Ca–Al-rich inclusions (CAI). The age corresponds to 4563.17 + 0.60/−0.67 Myr ago. The higher 55 Mn/ 52 Cr, ε 54 Cr, and initial ε 53 Cr values of the Ryugu samples relative to any carbonaceous chondrite samples implies that its progenitor body formed from the least thermally processed precursors in the outermost region of the protoplanetary disk. Despite accreting at different distances from the Sun, the hydrous asteroids (Ryugu and the parent bodies of CI, CM, CR, and ungrouped C2 meteorites) underwent aqueous alteration during a period of limited duration (3.8 ± 1.8 Myr after CAI). These ages are identical to the crystallization age of the carbonaceous achondirtes NWA 6704/6693 within the error. The ε 54 Cr and initial ε 53 Cr values of Ryugu and NWA 6704/6693 are also identical, while they show distinct Δ' 17 O values. This suggests that the precursors that formed the progenitor bodies of Ryugu and NWA 6703/6693 were formed in close proximity and experienced a similar degree of thermal processing in the protosolar nebula. However, the progenitor body of Ryugu was formed by a higher ice/dust ratio, than NWA6703/6693, in the outer region of the protoplanetary disk.
Hayabusa2 collected 5.4 g of samples from asteroid (162173) Ryugu and brought them back to Earth. Obtaining multiband images of these samples with spectral bands comparable to those used for ...remote-sensing observations is important for characterizing the collected samples and examining how representative they are compared with spacecraft observations of Ryugu. In this study, we constructed a multiband microscopic camera system that enables both visual multispectral imaging at 390 (ul), 475 (b), 550 (v), 590 (Na), 700 (w), and 850 nm (x), and three-dimensional (3D) shape reconstruction of individual grain samples based on stereo imaging. The imaging system yields images of 4096 × 2160 pixels with a pixel resolution of 1.93 μm/pix and field of view of 7.9 mm × 4.2 mm. Our multispectral imaging system observes the samples with spectral bands comparable to those on the telescopic optical navigation camera (ONC-T) onboard Hayabusa2, and our validation measurements yielded reflectance spectra and a 3D model with a relative error of 3% and 5%, respectively. These results indicate that the multiband imaging system with a 3D shape reconstruction capability yields accurate spectral and shape data of the returned samples. Using this instrument, we conducted multispectral measurements of two Ryugu samples (grains in dishes A3 and C1) acquired from two locations on the asteroid. The average spectra of the measured Ryugu samples were flat and consistent with the global averaged spectrum of Ryugu. The 550-nm band (v-band) reflectance of the returned grains in the dishes was 2.4% on average, higher than that of the global averaged spectrum of Ryugu observed with ONC-T. This apparent difference could be because the returned grains have greater specular reflectance. In this paper, a hardware description, development, and experimental results are presented.
•Multispectral imaging system was developed to observe samples from asteroid Ryugu.•The instrument observes samples in the same wavelengths as ONC-T onboard Hayabusa2.•The system enables 3D stereo analysis of individual grain samples.•The instrument was characterized and Ryugu samples were measured.•Relative accuracies of 3% and 5% were achieved for spectra and 3D model, respectively.
C-type rubble pile asteroid (162173) Ryugu was observed and characterized up close for a year and a half by the instruments on-board the Japanese Aerospace eXploration Agency (JAXA) Hayabusa2 ...spacecraft. The asteroid exhibits relatively homogeneous spectral characteristics at near-infrared wavelengths (~1.8–3.2 μm), including a very low reflectance factor, a slight positive (“red”) slope towards longer wavelengths, and a narrow absorption feature centered at 2.72 μm that is attributed to the presence of OH− in phyllosilicate minerals. Numerous craters have been identified at the surface that provide good candidates for identifying and studying younger and/or more recently exposed near-surface material to further assess potential spectral/compositional heterogeneities. We present here the results of a spectral survey of all previously identified and referenced craters (Hirata et al. 2020) based on reflectance data acquired by the NIRS3 spectrometer, with an emphasis on the spectral characteristics between different craters as well as with their surrounding terrain. At a global scale, the spectral properties inside and outside of craters are found to be very similar, indicating that subsurface material is either compositionally similar to material at the surface that has a longer exposure age or that material at Ryugu's optical surface is spectrally altered over relatively short timescales by external factors such as space weathering. Although, the imaging data from ONC camera suites show more morphological and color diversity in craters at a smaller scale than the resolution provided by the NIRS3 instrument, which could indicate a wider compositional diversity on Ryugu than that observed in the near-infrared and discussed in this paper. The 2.72 μm band depth exhibit a slight anti-correlation with the reflectance factor selected at 2 μm, which could indicate different surface properties (e.g., grain size and/or porosity) or different alteration processes (e.g., space weathering, shock metamorphism and/or solar heating). Four different spectral classes were identified based on their reflectance factor at 2 μm and 2.72 μm absorption strength. The most commonly spectral behavior associated with crater floors, is defined by a slightly lower reflectance at 2 μm and deeper band depth. These spectral characteristics are similar to those of subsurface material excavated by the Hayabusa2 small carry-on impactor (SCI) experiment, suggesting these spectral characteristics may represent materials with a younger surface exposure age. Alternatively, these materials may have experienced significant solar heating and desiccation to form finer grains that subsequently migrated towards and preferentially accumulated in areas of low geopotential, such as craters floors. It is believed that the Hayabusa2 mission successfully collected typical surface material as well as darker material excavated by the SCI experiment, and detailed analyses of those samples upon their return will allow for further testing of these formation and alteration hypotheses.
•We present a spectral survey of all craters detected at the surface of asteroid (1621173) Ryugu.•The majority of crater floors present a lower reflectance factor and a deeper hydration band than their vicinity.•These spectral characteristics similarly to the newly created SCI crater could be representative of fresher material.•Conversely, they could be fine-grained porous material that would preferentially settle in region of low-geopotential•Returned samples will help decipher between these two origins hypothesis.
Extraterrestrial minerals on the surface of airless Solar System bodies undergo gradual alteration processes known as space weathering over long periods of time. The signatures of space weathering ...help us understand the phenomena occurring in the Solar System. However, meteorites rarely retain the signatures, making it impossible to study the space weathering processes precisely. Here, we examine samples retrieved from the asteroid Ryugu by the Hayabusa2 spacecraft and discover the presence of nonmagnetic framboids through electron holography measurements that can visualize magnetic flux. Magnetite particles, which normally provide a record of the nebular magnetic field, have lost their magnetic properties by reduction via a high-velocity (>5 km s
) impact of a micrometeoroid with a diameter ranging from 2 to 20 μm after destruction of the parent body of Ryugu. Around these particles, thousands of metallic-iron nanoparticles with a vortex magnetic domain structure, which could have recorded a magnetic field in the impact event, are found. Through measuring the remanent magnetization of the iron nanoparticles, future studies are expected to elucidate the nature of the nebular/interplanetary magnetic fields after the termination of aqueous alteration in an asteroid.
We report ground-based environmental assessments performed during development of the sampler system until the launch of the Hayabusa2 spacecraft. We conducted static monitoring of potential ...contaminants to assess the environmental cleanliness during (1) laboratory work performed throughout the development and manufacturing processes of the sampler devices, (2) installation of the sampler system on the spacecraft, and (3) transportation to the launch site at the Japan Aerospace Exploration Agency’s (JAXA’s) Tanegashima Space Center. Major elements and ions detected in our inorganic analyses were sodium (Na), potassium (K), and ionized chloride (Cl
–
); those elements and ions were positively correlated with the total organic content and with exposure duration in the range from 10
1
to 10
3
nanograms per monitor coupon within an ~ 30-mm diameter scale. We confirmed that total deposits on the coupon were below the microgram-scale order during manufacturing, installation, and transportation in the prelaunch phase. The present assessment yields a nominal safety declaration for analysis of the pristine sample (> 5.4 g) returned from asteroid (162173) Ryugu combined with a highly clean environmental background level. We expect that the sample returned from Ryugu by Hayabusa2 will be free of severe and/or unknown contamination and will allow us to provide native profiles recorded for the carbonaceous asteroid history.
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