•Ultrasonic pretreatment of the galvanocoagulant for wastewater treatment was proposed.•A mathematical model of this process was developed and confirmed experimentally.•The efficiency of preliminary ...ultrasonic treatment of the galvanocoagulant was proved.•The process duration was reduced by 20–25%.•A pilot semi industrial complex based on the method was developed and tested.
Two general methodologies adopted for the decontamination of industrial wastewater containing oil and metal ions are flocculation and coagulation. Both methods require the addition of chemicals and in the case of electrocoagulation the additional use of electrical power. Another methodology that was developed in Russia some years ago involves the production of Fe2O3 particles as coagulants by a galvanochemical reaction between iron and coke. Both of these materials are inexpensive and generally available in bulk. Ultrasonic processing of the particles generated in this reaction reduces the particle size of the Fe2O3 particles and provides surface cleaning making them more effective. Trials have proved their efficiency for the decontamination of wastewater made up in a laboratory and real wastewater from a carriage cleaning station on the St. Petersburg Metro. A mathematical model for the process has been developed.
Two new methods of preparation of nanocrystalline scintillators are described. Laser ablation of microscopic powders immersed in optically transparent liquid was used to produce spherical ...nanoparticles, which preserved the initial compositions. Electric arc discharge between electrodes of definite metals immersed in water solutions of different salts produces a vast variety of scintillating compounds with nanoscopic dimensions and morphologies having crystallographic symmetry of the corresponding equilibrium phases. A wide range of different compositions and structures of tungsten oxides are obtained during one synthesis process, which is due to variety of temperatures and other conditions around the arc channel. It was found that the light emission spectroscopy of the discharge is a rather informative method of diagnostics of the process of the nanoparticle synthesis inside the discharge chamber. The synthesis of nanoscintillators by arc discharge turned out to be rather efficient and capable to create nanocrystalline scintillators of easily regulated compositions. Hydrogen injection into nanoparticles of tungsten oxide is detected by light emission and infrared absorption spectroscopy. Hydrogenated nanoscintillators obtained by this method are interesting for registration of fast neutrons.
•An ultrasonic method for treatment of horizontal oil wells for water cut reduction is developed.•The developed method was tested on a horizontal well in Western Siberia.•A decrease of the water cut ...by 20% was observed in the tested well.•An increase of oil production by 91% after treatment of the test well was observed.
A technique for treatment of perforation zones of horizontal oil wells for water cut reduction based on selective ultrasonic treatment was suggested. The technique involves online geophysical studies of horizontal wells, determination of treatment intervals based on these studies, selective ultrasonic treatment of the chosen interval and subsequent pump-out using a specially designed jet pump. The technology does not involve reduction of the flow in the well. The developed innovative technique of water cut reduction using selective ultrasonic treatment is studied within this article. Theoretical estimations and computer modeling revealed that the position of the downhole ultrasonic tool near the sidewall of the well leads to more homogeneous distribution of the induced acoustical field and wider penetration of the acoustical waves. The developed method was tested on a horizontal well in Western Siberia, which was characterized by high water cut. Based on geophysical studies only zones with low water and high oil production were treated, this lead to a decrease of the water cut by 20% and an increase of oil production by 91% after treatment of the test well.
This paper reports the results of the large-scale field testing of composite materials with antibacterial properties in a tropical climate. The composite materials, based on a cotton fabric with a ...coating of metal oxide nanoparticles (TiO2 and/or ZnO), were produced using high-power ultrasonic treatment. The antibacterial properties of the materials were studied in laboratory tests on solid and liquid nutrient media using bacteria of different taxonomic groups (Escherichia coli, Chromobacterium violaceum, Pseudomonas chlororaphis). On solid media, the coatings were able to achieve a >50% decrease in the number of bacteria. The field tests were carried out in a tropical climate, at the Climate test station “Hoa Lac” (Hanoi city, Vietnam). The composite materials demonstrated long-term antibacterial activity in the tropical climate: the number of microorganisms remained within the range of 1−3% in comparison with the control sample for the duration of the experiment (3 months). Ten of the microorganisms that most frequently occurred on the surface of the coated textiles were identified. The bacteria were harmless, while the fungi were pathogenic and contributed to fabric deterioration. Tensile strength deterioration was also studied, with the fabrics coated with metal oxides demonstrating a better preservation of their mechanical characteristics over time, (there was a 42% tensile strength decrease for the reference non-coated sample and a 21% decrease for the sample with a ZnO + CTAB coating).
This paper reports the results of the large-scale field testing of composite materials with antibacterial properties in a tropical climate. The composite materials, based on a cotton fabric with a ...coating of metal oxide nanoparticles (TiOsub.2 and/or ZnO), were produced using high-power ultrasonic treatment. The antibacterial properties of the materials were studied in laboratory tests on solid and liquid nutrient media using bacteria of different taxonomic groups (Escherichia coli, Chromobacterium violaceum, Pseudomonas chlororaphis). On solid media, the coatings were able to achieve a >50% decrease in the number of bacteria. The field tests were carried out in a tropical climate, at the Climate test station "Hoa Lac" (Hanoi city, Vietnam). The composite materials demonstrated long-term antibacterial activity in the tropical climate: the number of microorganisms remained within the range of 1-3% in comparison with the control sample for the duration of the experiment (3 months). Ten of the microorganisms that most frequently occurred on the surface of the coated textiles were identified. The bacteria were harmless, while the fungi were pathogenic and contributed to fabric deterioration. Tensile strength deterioration was also studied, with the fabrics coated with metal oxides demonstrating a better preservation of their mechanical characteristics over time, (there was a 42% tensile strength decrease for the reference non-coated sample and a 21% decrease for the sample with a ZnO + CTAB coating).
Thermal state of permafrost in Russia Romanovsky, V. E.; Drozdov, D. S.; Oberman, N. G. ...
Permafrost and periglacial processes,
April/June 2010, Letnik:
21, Številka:
2
Journal Article
Abstract
All forms of dementia including Alzheimer’s disease are currently incurable. Mitochondrial dysfunction and calcium alterations are shown to be involved in the mechanism of neurodegeneration ...in Alzheimer’s disease. Previously we have described the ability of compound Tg-2112x to protect neurons via sequestration of mitochondrial calcium uptake and we suggest that it can also be protective against neurodegeneration and development of dementia. Using primary co-culture neurons and astrocytes we studied the effect of Tg-2112x and its derivative Tg-2113x on β-amyloid-induced changes in calcium signal, mitochondrial membrane potential, mitochondrial calcium, and cell death. We have found that both compounds had no effect on β-amyloid or acetylcholine-induced calcium changes in the cytosol although Tg2113x, but not Tg2112x reduced glutamate-induced calcium signal. Both compounds were able to reduce mitochondrial calcium uptake and protected cells against β-amyloid-induced mitochondrial depolarization and cell death. Behavioral effects of Tg-2113x on learning and memory in fear conditioning were also studied in 3 mouse models of neurodegeneration: aged (16-month-old) C57Bl/6j mice, scopolamine-induced amnesia (3-month-old mice), and 9-month-old 5xFAD mice. It was found that Tg-2113x prevented age-, scopolamine- and cerebral amyloidosis-induced decrease in fear conditioning. In addition, Tg-2113x restored fear extinction of aged mice. Thus, reduction of the mitochondrial calcium uptake protects neurons and astrocytes against β-amyloid-induced cell death and contributes to protection against dementia of different ethology. These compounds could be used as background for the developing of a novel generation of disease-modifying neuroprotective agents.
Evolution of the crystal structure of ceramics BiFeO3–BaTiO3 across the morphotropic phase boundary was analyzed using the results of macroscopic measuring techniques such as X-ray diffraction, ...differential scanning calorimetry, and differential thermal analysis, as well as the data obtained by local scale methods of scanning probe microscopy. The obtained results allowed to specify the concentration and temperature regions of the single phase and phase coexistent regions as well as to clarify a modification of the structural parameters across the rhombohedral–cubic phase boundary. The structural data show unexpected strengthening of structural distortion specific for the rhombohedral phase, which occurs upon dopant concentration and temperature-driven phase transitions to the cubic phase. The obtained results point to the non-monotonous character of the phase evolution, which is specific for metastable phases. The compounds with metastable structural state are characterized by enhanced sensitivity to external stimuli, which significantly expands the perspectives of their particular use.
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