High N depositions of past decades brought changes to European forests including impacts on forest soil nutrition status. However, the ecosystem responses to declining atmospheric N inputs or ...moderate N depositions attracted only less attention so far. Our study investigated macronutrient (N, S, Ca2+, Mg2+, K+) pools and fluxes at forest conversion sites over 80 years old in Central Germany with European beech (so-called “Green Eyes” (GE)). The GE are embedded in large spruce and pine stands (coniferous stands: CS) and all investigated forest stands were exposed to moderate N deposition rates (6.8 ± 0.9 kg ha−1 yr−1) and acidic soil conditions (pHH2O < 4.7). Since the understanding of forest soil chemical and macronutrient status is essential for the evaluation of forest conversion approaches, we linked patterns in water-bound nutrient fluxes (2001–2018) and in predicted macronutrient storage in the herbaceous and tree layer to patterns in litter fall (2016–2017) and in forest floor and mineral soil macronutrient stocks at GE and CS assessed in 2018. Our results exhibited 43% (Nt) and 21% (S) higher annual throughfall fluxes at CS than at GE. Seepage water at 100 cm mineral soil depth (2001–2018) of CS is characterized by up to fivefold higher NO3− (GE: 2 ± 0.7 µmolc L−1; CS: 9 ± 1.4 µmolc L−1) and sevenfold higher SO42− (GE: 492 ± 220 µmolc L−1; CS: 3672 ± 2613 µmolc L−1) concentrations. High base cation (∑ Ca2+, Mg2+, K+) concentrations in CS mineral soil seepage water (100 cm depth: 2224 ± 1297 µmolc L−1) show significant positive correlations with SO42−. Tree uptake of base cations at GE is associated especially with a Ca2+ depletion from deeper mineral soil. Foliar litter fall turns out to be the main pathway for litter base cation return to the topsoil at GE (>59%) and CS (>66%). The litter fall base cation return at GE (59 ± 6 kg ha−1 yr−1) is almost twice as large as the base cation deposition (30 ± 5 kg ha−1 yr−1) via throughfall and stemflow. At CS, base cation inputs to the topsoil via litter fall and depositions are at the same magnitude (24 ± 4 kg ha−1 yr−1). Macronutrient turnover is higher at GE and decomposition processes are hampered at CS maybe through higher N inputs. Due to its little biomass and only small coverage, the herbaceous layer at GE and CS do not exert a strong influence on macronutrient storage. Changes in soil base cation pools are tree species-, depth- and might be time-dependent, with recently growing forest floor stocks. An ongoing mineral soil acidification seems to be related to decreasing mineral soil base cation stocks (through NO3− and especially SO42− leaching as well as through tree uptake).
Upper Turonian to lower Coniacian marls of the Strehlen Formation of the Graupa 60/1 core were investigated for their foraminiferal content to add stratigraphical and palaeoenvironmental information ...about the transitional facies zone of the Saxonian Cretaceous Basin. Further comparison with foraminiferal faunas of the Brausnitzbach Marl (Schrammstein Formation) were carried out to clarify its relationship to the marls of the Graupa 60/1 core. Tethyan agglutinated marker species for the late Turonian to early Coniacian confirm the proposed age of the marls of the Graupa 60/1 core and the Brausnitzbach Marl. The palaeoenvironment of the marls reflects middle to outer shelf conditions. The maximum flooding zones of genetic sequences TUR6, TUR7 and CON1 could be linked to acmes of foraminiferal species and foraminiferal morphogroups. In general, a rise of the relative sea-level can be recognised from the base to the top of the marls of the Graupa 60/1 core. While agglutinated foraminiferal assemblages suggest a generally high organic matter influx and variable but high productivity in the Graupa 60/1 core, the Brausnitzbach Marl deposition was characterized by moderate productivity and a generally shallower water depth.