We study the influence of the turbulent transport on ice chemistry in protoplanetary disks, focusing on carbon- and nitrogen-bearing molecules. Chemical rate equations are solved with the diffusion ...term, mimicking the turbulent mixing in the vertical direction. Turbulence can bring ice-coated dust grains from the midplane to the warm irradiated disk surface, and the ice mantles are reprocessed by photoreactions, thermal desorption, and surface reactions. The upward transport decreases the abundance of methanol and ammonia ices at r lap 30 AU because warm dust temperature prohibits their reformation on grain surfaces. This reprocessing could explain the smaller abundances of carbon and nitrogen bearing molecules in cometary coma than those in low-mass protostellar envelopes. We also show the effect of mixing on the synthesis of complex organic molecules (COMs) in two ways: (1) transport of ices from the midplane to the disk surface and (2) transport of atomic hydrogen from the surface to the midplane. The former enhances the COMs formation in the disk surface, while the latter suppresses it in the midplane. Then, when mixing is strong, COMs are predominantly formed in the disk surface, while their parent molecules are (re)formed in the midplane. This cycle expands the COMs distribution both vertically and radially outward compared with that in the non-turbulent model. We derive the timescale of the sink mechanism by which CO and N sub(2) are converted to less volatile molecules to be depleted from the gas phase and find that the vertical mixing suppresses this mechanism in the inner disks.
We investigate nitrogen-isotope fractionation in forming and evolving molecular clouds using gas-ice astrochemical simulations. We find that the bulk gas can become depleted in heavy nitrogen (15N) ...due to the formation of 15N-enriched ices. Around the chemical transition from atomic nitrogen to N2, N15N is selectively photodissociated, which results in the enrichment of 15N in atomic nitrogen. As 15N-enriched atomic nitrogen is converted to ammonia ice via grain surface reactions, the bulk gas is depleted in 15N. The level of 15N depletion in the bulk gas can be up to a factor of two compared to the elemental nitrogen-isotope ratio, depending on the photodesorption yield of ammonia ice. Once the nitrogen isotopes are differentially partitioned between gas and solids in a molecular cloud, the condition should remain in the later stages of star formation (e.g., prestellar core) as long as the sublimation of ammonia ice is inefficient. Our model suggests that all of the N-bearing molecules in the cold gas of star-forming regions can be depleted in 15N, which is at least qualitatively consistent with the observations toward prestellar core L1544. In our models, icy species show both 15N and deuterium fractionation. The fractionation pattern within ice mantles is different between 15N and deuterium, reflecting their fractionation mechanisms; while the concentration of deuterium almost monotonically increases from the lower layers of the ice mantles to the upper layers, the concentration of 15N reaches the maximum at a certain depth and declines toward the surface.
Hot corino chemistry and warm carbon chain chemistry (WCCC) are driven by gas-grain interactions in star-forming cores: radical-radical recombination reactions to form complex organic molecules ...(COMs) in the ice mantle, sublimation of CH4 and COMs, and their subsequent gas-phase reactions. These chemical features are expected to depend on the composition of the ice mantle, which is set in the prestellar phase. We calculated the gas-grain chemical reaction network considering a layered ice mantle structure in star-forming cores to investigate how the hot corino chemistry and WCCC depend on the physical condition of the static phase before the onset of gravitational collapse. We found that WCCC becomes more active if the temperature is lower, or the visual extinction is lower in the static phase, or the static phase is longer. The dependence of hot corino chemistry on the static-phase condition is more complex. While CH3OH is less abundant in the models with a warmer static phase, some COMs are formed efficiently in those warm models because there are various formation paths of COMs. If the visual extinction is lower, photolysis makes COMs less abundant in the static phase. Once the collapse starts and visual extinction increases, however, COMs can be formed efficiently. The duration of the static phase does not largely affect COM abundances. The chemical diversity between prototypical hot corinos and hybrid sources, in which both COMs and carbon chains are reasonably abundant, can be explained by the variation of prestellar conditions. Deficiency of gaseous COMs in prototypical WCCC sources is, however, hard to reproduce within our models.
We investigate deuterium chemistry coupled with the nuclear spin-state chemistry of H2 and in protoplanetary disks. Multiple paths of deuterium fractionation are found; exchange reactions with D ...atoms, such as HCO+ + D, are effective in addition to those with HD. In a disk model with grain sizes appropriate for dark clouds, the freeze-out of molecules is severe in the outer midplane, while the disk surface is shielded from UV radiation. Gaseous molecules, including DCO+, thus become abundant at the disk surface, which tends to make their column density distribution relatively flat. If the dust grains have grown to millimeter size, the freeze-out rate of neutral species is reduced and the abundances of gaseous molecules, including DCO+ and N2D+, are enhanced in the cold midplane. Turbulent diffusion transports D atoms and radicals at the disk surface to the midplane, and stable ice species in the midplane to the disk surface. The effects of turbulence on chemistry are thus multifold; while DCO+ and N2D+ abundances increase or decrease depending on the regions, HCN and DCN in the gas and ice are greatly reduced at the innermost radii, compared to the model without turbulence. When cosmic rays penetrate the disk, the ortho-to-para ratio (OPR) of H2 is found to be thermal in the disk, except in the cold ( 10 K) midplane. We also analyze the OPR of and H2D+, as well as the main reactions of H2D+, DCO+, and N2D+, in order to analytically derive their abundances in the cold midplane.
Abstract
Debris disks are classically considered to be gas-less systems, but recent (sub)millimeter observations have detected tens of those with rich gas content. The origin of the gas component ...remains unclear, but it could be protoplanetary remnants and/or secondary products from large bodies. In order to be protoplanetary in origin, the gas component of the parental protoplanetary disk is required to survive for
≳
10
Myr
. However, previous models predict
≲
10
Myr
lifetimes because of efficient photoevaporation at the late stage of disk evolution. We investigate photoevaporation of gas-rich, optically-thin disks around intermediate-mass stars at a late stage of the disk evolution. The evolved system is modeled like those devoid of small grains (
≲
4
μ
m
). We find that grain depletion reduces photoelectric heating so that far-ultraviolet photoevaporation is not excited. Extreme-ultraviolet (EUV) photoevaporation is dominant and yields a mass-loss rate of the order of
1
×
10
−
11
(
Φ
EUV
/
10
38
s
−
1
)
1
/
2
M
⊙
yr
−
1
, where
Φ
EUV
is the EUV emission rate of the host star. The estimated gas–disk lifetimes are
∼
100
(
M
disk
/
10
−
3
M
⊙
)
(
Φ
EUV
/
10
38
s
−
1
)
1
/
2
Myr
and depend on the “initial” disk mass at the point small grains have been depleted in the system. We show that the gas component can survive for a much longer time around A-type stars than lower-mass (F-, G-, K-type) stars owing to their atypical low EUV (and X-ray) luminosities. This trend is consistent with the higher frequency of gas-rich debris disks around A-type stars, implying the possibility of the gas component being protoplanetary remnants.
ABSTRACT We investigate the chemistry in a radiation-hydrodynamics model of a star-forming core that evolves from a cold (∼10 K) prestellar core to the main accretion phase in ∼105 years. A ...rotationally supported gravitationally unstable disk is formed around a protostar. We extract the temporal variation of physical parameters in ∼1.5 × 103 SPH particles that end up in the disk, and perform post-processing calculations of the gas-grain chemistry adopting a three-phase model. Inside the disk, the SPH particles migrate both inward and outward. Since a significant fraction of volatiles such as CO can be trapped in the water-dominant ice in the three-phase model, the ice mantle composition depends not only on the current position in the disk, but also on whether the dust grain has ever experienced higher temperatures than the water sublimation temperature. Stable molecules such as H2O, CH4, NH3, and CH3OH are already abundant at the onset of gravitational collapse and are simply sublimated as the fluid parcels migrate inside the water snow line. On the other hand, various molecules such as carbon chains and complex organic molecules (COMs) are formed in the disk. The COMs abundance sensitively depends on the outcomes of photodissociation and diffusion rates of photofragments in bulk ice mantle. As for S-bearing species, H2S ice is abundant in the collapse phase. In the warm regions in the disk, H2S is sublimated to be destroyed, while SO, H2CS, OCS, and SO2 become abundant.
Observations of comets and asteroids show that the solar nebula that spawned our planetary system was rich in water and organic molecules. Bombardment brought these organics to the young Earth's ...surface. Unlike asteroids, comets preserve a nearly pristine record of the solar nebula composition. The presence of cyanides in comets, including 0.01 per cent of methyl cyanide (CH3CN) with respect to water, is of special interest because of the importance of C-N bonds for abiotic amino acid synthesis. Comet-like compositions of simple and complex volatiles are found in protostars, and can readily be explained by a combination of gas-phase chemistry (to form, for example, HCN) and an active ice-phase chemistry on grain surfaces that advances complexity. Simple volatiles, including water and HCN, have been detected previously in solar nebula analogues, indicating that they survive disk formation or are re-formed in situ. It has hitherto been unclear whether the same holds for more complex organic molecules outside the solar nebula, given that recent observations show a marked change in the chemistry at the boundary between nascent envelopes and young disks due to accretion shocks. Here we report the detection of the complex cyanides CH3CN and HC3N (and HCN) in the protoplanetary disk around the young star MWC 480. We find that the abundance ratios of these nitrogen-bearing organics in the gas phase are similar to those in comets, which suggests an even higher relative abundance of complex cyanides in the disk ice. This implies that complex organics accompany simpler volatiles in protoplanetary disks, and that the rich organic chemistry of our solar nebula was not unique.
Celotno besedilo
Dostopno za:
DOBA, IJS, IZUM, KILJ, KISLJ, NUK, PILJ, PNG, SAZU, SBMB, SIK, UILJ, UKNU, UL, UM, UPUK
Abstract
We performed synthetic observations of the Ulrich, Cassen, and Moosman (UCM) model to understand the relation between the physical structures of the infalling envelope around a protostar and ...their observational features in molecular lines, adopting L1527 as an example. We also compared the physical structure and synthetic position–velocity (
P–V
) diagrams of the UCM model and a simple ballistic (SB) model. There are multiple ways to compare synthetic data with observational data. We first calculated the correlation coefficient. The UCM model and the SB model show similarly good correlation with the observational data. While the correlation reflects the overall similarity between the cube datasets, we can alternatively compare specific local features, such as the centrifugal barrier in the SB model or the centrifugal radius in the UCM model. We evaluated systematic uncertainties in these methods. In the case of L1527, the stellar mass values estimated using these methods are all lower than the value derived from previous Keplerian analysis of the disk. This may indicate that the gas infall motion in the envelope is retarded by, e.g., magnetic fields. We also showed analytically that, in the UCM model, the spin-up feature of the
P–V
diagram is due to the infall velocity rather than the rotation. The line-of-sight velocity
V
is thus ∝
x
−0.5
, where
x
is the offset. If the infall is retarded, rotational velocity should dominate so that
V
is proportional to
x
−1
, as is often observed in the protostellar envelope.
We investigate the evolution of the ortho-to-para ratio of overall (gas + ice) via the nuclear spin conversion on grain surfaces coated with water ice under physical conditions that are relevant to ...star- and planet-forming regions. We utilize the rate equation model that considers adsorption of gaseous on grain surfaces, which have a variety of binding sites with a different potential energy depth, thermal hopping, desorption, and the nuclear spin conversion of adsorbed . It is found that the spin conversion efficiency depends on the gas density and the surface temperature. As a general trend, enhanced gas density reduces the efficiency, while the temperature dependence is not monotonic; there is a critical surface temperature at which the efficiency is the maximum. At low temperatures, the exchange of gaseous and icy is inefficient (i.e., adsorbed does not desorb and hinders another gaseous to be adsorbed), while at warm temperatures, the residence time of on surfaces is too short for the spin conversion. Additionally, the spin conversion becomes more efficient with lowering the activation barriers for thermal hopping. We discuss whether the spin conversion on surfaces can dominate over that in the gas phase in star- and planet-forming regions. Finally, we establish a simple, but accurate way to implement the spin conversion on grain surfaces in existing gas-ice astrochemical models.