African biomass burning emission inventories for gaseous and particulate species have been constructed at a resolution of 1 km by 1km with daily coverage for the 2000-2007 period. These inventories ...are higher than the GFED2 inventories, which are currently widely in use. Evaluation specifically focusing on combustion aerosol has been carried out with the ORISAM-TM4 global chemistry transport model which includes a detailed aerosol module. This paper compares modeled results with measurements of surface BC concentrations and scattering coefficients from the AMMA Enhanced Observations period, aerosol optical depths and single scattering albedo from AERONET sunphotometers, LIDAR vertical distributions of extinction coefficients as well as satellite data. Aerosol seasonal and interannual evolutions over the 2004-2007 period observed at regional scale and more specifically at the Djougou (Benin) and Banizoumbou (Niger) AMMA/IDAF sites are well reproduced by our global model, indicating that our biomass burning emission inventory appears reasonable.
Surface emission and deposition fluxes of reactive nitrogen compounds have been studied in five sites of West Africa during the period 2002 to 2007. Measurements of N deposition fluxes have been ...performed in IDAF sites representative of main west and central African ecosystems, i.e., 3 stations in dry savanna ecosystems (from 15° N to 12° N), and 2 stations in wet savanna ecosystems (from 9° N to 6° N). Dry deposition fluxes are calculated from surface measurements of NO2, HNO3 and NH3 concentrations and simulated deposition velocities, and wet deposition fluxes are calculated from NH4+ and NO3− concentration in samples of rain. Emission fluxes are evaluated including simulated NO biogenic emission from soils, emissions of NOx and NH3 from biomass burning and domestic fires, and volatilization of NH3 from animal excreta. This paper is a tentative to understand the eventual impact of the monsoon variability from year to year, with the natural variability of local sources, on the emission and deposition N fluxes, and to compare these evolutions between dry and wet savanna ecosystems. In dry savanna ecosystems where the rain season lasts mainly from June to September, the occurence of rain correlates with the beginning of emission and deposition fluxes. This link is less obvious in wet savanna ecosystems (wet season mainly from May to October), where the surface is less submitted to drastic changes in terms of water content. Whatever the location, the natural variability of rain from year to year does not exceed 15 %, and the variability of emission and deposition magnitude ranges between 15 % and 28 %. While quasi providing the same total N budget, and due to the presence of different types of soils and vegetation, wet and dry savanna do not present the same distribution in emission and deposition fluxes contributions: in dry savanna, the emission is dominated by ammonia volatilization, and the deposition is dominated by the dry contribution. In wet savanna, emission is equally distributed between ammonia volatilization, emissions from biomass burning and natural NO emissions from soils, and wet and dry deposition are equivalent. Due to the scarcity of available data on the African continent, and despite the numerous uncertainties resulting from the different calculations and assumptions, this work is a combination of data from different origins (surface measurements, satellite and modelling) to document the atmospheric Nitrogen cycle in tropical regions.
In the framework of the IDAF (IGAC/DEBITS/AFrica) international program, this study aims to study the chemical composition of precipitation and associated wet deposition at the rural site of Djougou ...in Benin, representative of a West and Central African wet savanna. Five hundred and thirty rainfall samples were collected at Djougou, Benin, from July 2005 to December 2009 to provide a unique database. The chemical composition of precipitation was analyzed for inorganic (Ca2+, Mg2+, Na+, NH4+, K+, NO3−, Cl−, SO42−) and organic (HCOO−, CH3COO−, C2H5COO−, C2O42−) ions, using ion chromatography. The 530 collected rain events represent a total of 5706.1 mm of rainfall compared to the measured pluviometry 6138.9 mm, indicating that the collection efficiency is about 93%. The order of total annual loading rates for soluble cations is NH4+ > Ca2+ > Mg2+ > K+. For soluble anions the order of loading is carbonates > HCOO− > NO3− > CH3COO− > SO42− > Cl− > C2O42− > C2H5COO−. In the wet savanna of Djougou, 86% of the measured pH values range between 4.7 and 5.7 with a median pH of 5.19, corresponding to a VWM (Volume Weighed Mean) H+ concentration of 6.46 μeq·L−1. This acidity results from a mixture of mineral and organic acids. The annual sea salt contribution was computed for K+, Mg2+, Ca2+ and SO42− and represents 4.2% of K+, 41% of Mg2+, 1.3% of Ca2+, and 7.4% of SO42−. These results show that K+, Ca2+, SO42−, and Mg2+ were mainly of non-marine origin. The marine contribution is estimated at 9%. The results of the chemical composition of rainwater of Djougou indicates that, except for the carbonates, ammonium has the highest VWM concentration (14.3 μeq·L−1) and nitrate concentration is 8.2 μeq·L−1. The distribution of monthly VWM concentration for all ions is computed and shows the highest values during the dry season, comparing to the wet season. Identified nitrogenous compound sources (NOx and NH3) are domestic animals, natural emissions from savanna soils, biomass burning and biofuel combustions. The second highest contribution is the calcium ion (13.3 μeq·L−1), characteristic of dust aerosols from terrigenous sources, Calcium contributes up to 46% of the precipitation chemistry in Djougou. Finally, these results are compared to those obtained for other selected African sites representative of other main natural ecosystems: dry savanna and forest. The study of the African ecosystem transect indicates a pH gradient with more acidic pH in the forested ecosystem. Nitrogenous contribution to the chemical composition of rain in Lamto, wet savanna, (24%) is equivalent to the one estimated in Djougou (24%). The last contribution concerns organic acidity, which represents 7% of total ionic content of precipitation at Djougou. The relative particulate contribution PC and the relative gaseous contribution GC are calculated using the mean chemical composition measured in Djougou for the studied period. The comparison with other African sites gives 40% and 43% PC in wet savannas of Lamto (Côte d’Ivoire) and Djougou (Benin) respectively, 20% PC in the equatorial forest of Zoetele (Cameroon) and 80% PC in dry savanna of Banizoumbou (Niger). The results shown here indicate the existence of a North-South gradients of organic, marine, terrigenous and nitrogenous contributions along the transect in West and Central Africa.
•We provide a background study of the rain chemistry of a rural wet savanna site.•The frequency distribution of pH of rainwater at Djougou (Benin) is computed.•We estimate the nitrogenous compound emitted monthly by different sources.•We compute the distribution of monthly means of the wet deposition of major ions.•We estimate the sources contributions to the rain chemical content in West Africa.
The purpose of this study is to analyze a long term database of the chemical composition of precipitation at three African dry savanna sites in the Sahel. The precipitation samples were collected ...during the monsoon season at Agoufou (15°20′N, 01°29′W, Mali) from 2004 to 2006, Banizoumbou (13°31′N, 02°38′E, Niger) from 1994 to 2009 and Katibougou (12°56′N, 07°32′ W, Mali) from 1997 to 2008. pH and major inorganic and organic ions in precipitation were analyzed by ionic chromatography. A characterization of mean precipitation chemistry with the associated wet deposition fluxes for each species is presented. The first important result is that interannual variability of all volume-weighted mean (VWM) concentrations is low, ranging between ±5% and ±25%. Acidity in dry savannas is low and indicates the strong alkaline nature of the precipitation. The average annual pH at Agoufou is 6.28, 5.75 at Banizoumbou and 5.54 at Katibougou. This result is correlated with the important terrigenous contribution measured in the chemical content of precipitation, implying acidity neutralization by mineral species such as Ca2+ and NH4+. Mg2+ and K+ are found to play a minor role in neutralization. Enrichment factor calculations for Ca2+, SO42−, K+ and Mg2+ with respect to the sea reference reveal a significant influence of Saharan and Sahelian crustal sources. VWM concentrations of these species dominate the composition of measured precipitation. An estimation of the potential particulate and gas contribution to the total precipitation composition is given for each site: At Agoufou, the mean relative contribution in rainwater is 80% for particles and 20% for gases, while at the Banizoumbou and Katibougou sites, results indicate 70% for particles and 30% for gases. The high particulate phase contribution to precipitation emphasizes the importance of multiphase processes between gases and particles in the atmospheric chemistry typical of African semi-arid savanna ecosystems. The second highest contribution is nitrogenous, with high VWM concentrations of NO3− and NH4+ measured at the three sites. Monthly evolution of NO3− and NH4+ concentrations are studied in relation to gaseous emission sources in the Sahelian region, i.e. biogenic soil emission and ammonia sources from animals. The calculated wet nitrogen deposition flux presents a regular increase throughout the wet season at the three sites. Results suggest total mean nitrogen deposition fluxes of 1.80 kg N ha−1 yr−1 at Agoufou, 2.10 kg N ha−1 yr−1 at Banizoumbou, and 3.30 kg N ha−1 yr−1 at Katibougou. The marine contribution is lower, 23% at Agoufou, 17% at Banizoumbou and 13% at Katibougou. The last contribution concerns organic acidity, which ranges from 5% at Agoufou, 10% at Banizoumbou to 14% at Katibougou. Terrigenous and marine contributions present a negative gradient, whereas nitrogenous and organic contributions a positive gradient along the Sahelian transect defined by Agoufou–Banizoumbou–Katibougou.
► Analysis of quality controlled rain chemical data for three sahelian savannas in Africa. ► Characterization of mean precipitation chemistry composition for each chemical species. ► Characterization of mean deposition fluxes for each chemical species. ► Interannual and seasonal variability of concentrations and deposition. ► Focus on nitrogen deposition fluxes in Sahelian ecosystems.
Background and Objectives: The recent use of Structure-from-Motion with Multi-View Stereo photogrammetry (SfM-MVS) in forestry has underscored its robustness in tree mensuration. This study evaluated ...the differences in tree metrics resulting from various related SfM-MVS photogrammetric image acquisition scenarios. Materials and Methods: Scaled tri-dimensional models of 30 savanna trees belonging to five species were built from photographs acquired in a factorial design with shooting distance (d = 1, 2, 3, 4 and 5 m away from tree) and angular shift (α = 15°, 30°, 45° and 60°; nested in d). Tree stem circumference at 1.3 m and bole volume were estimated using models resulting from each of the 20 scenarios/tree. Mean absolute percent error (MAPE) was computed for both metrics in order to compare the performance of each scenario in relation to reference data collected using a measuring tape. Results: An assessment of the effect of species identity (s), shooting distance and angular shift showed that photographic point cloud density was dependent on α and s, and optimal for 15° and 30°. MAPEs calculated on stem circumferences and volumes significantly differed with d and α, respectively. There was a significant interaction between α and s for both circumference and volume MAPEs, which varied widely (1.6 ± 0.4%–20.8 ± 23.7% and 2.0 ± 0.6%–36.5 ± 48.7% respectively), and were consistently lower for smaller values of d and α. Conclusion: The accuracy of photogrammetric estimation of individual tree attributes depended on image-capture approach. Acquiring images 2 m away and with 30° intervals around trees produced reliable estimates of stem circumference and bole volume. Research Highlights: This study indicates that the accuracy of photogrammetric estimations of individual tree attributes is species-dependent. Camera positions in relation to the subject substantially influence the level of uncertainty in measurements.
There is an increase in the use of photogrammetric point clouds for tree attribute mensuration. Stem diameter and circumference can be estimated from point clouds using stem disks of varying ...thicknesses along the bole. However, there is a dearth of information on the effect of the thickness of point cloud-based stem disks on the accuracy of diameter and circumference estimations. In this study, we outlined a GIS-based procedure for analysing Structure from Motion-derived photogrammetric point clouds with a view to providing an optimal disk thickness for accurate circumference estimates. Geo-referenced point clouds were created from photographs of 30 trees belonging to five savanna species. For each tree, 20 horizontal stem disks, with increasing thicknesses of 1 to 20 mm were made at breast height using the open source QGIS software. The resulting cross-sections were manually delineated and digitised. The difference between reference (manually measured) and point cloud-based circumferences at breast height was expressed as mean absolute percent error (MAPE) and compared across tree species, size and disk thickness. We found significant effects of species identity, tree size and disk thickness on MAPE. A stem disk of 7 mm in thickness provided consistently lower MAPE values (< 6%). This suggests that the accuracy of tree stem circumference estimations from photogrammetric point clouds depends on stem disk thickness.
The atmospheric nitrogen budget depends on emission and deposition fluxes both as reduced and oxidized nitrogen compounds. In this study, a first attempt at estimating the Sahel nitrogen budget for ...the year 2006 is made, through measurements and simulations at three stations from the IDAF network situated in dry savanna ecosystems. Dry deposition fluxes are estimated from measurements of NO2, HNO3 and NH3 gaseous concentrations and from simulated dry deposition velocities, and wet deposition fluxes are calculated from NH4+ and NO3− concentrations in samples of rain. Emission fluxes are estimated including biogenic emission of NO from soils (an Artificial Neural Network module has been inserted into the ISBA-SURFEX surface model), emission of NOx and NH3 from domestic fires and biomass burning, and volatilization of NH3 from animal excreta. Uncertainties are calculated for each contribution of the budget. This study uses original and unique data from remote and hardly-ever-explored regions.The monthly evolution of oxidized N compounds shows that emission and deposition increase at the beginning of the rainy season because of large emissions of biogenic NO (pulse events). Emission of oxidized compounds is dominated by biogenic emission from soils (domestic fires and biomass burning of oxidized compounds account for 0 to 13% at the most at the annual scale, depending on the station), whereas emission of NH3 is dominated by the process of volatilization from soils. At the annual scale, the average gaseous dry deposition accounts for 47% of the total estimated deposition flux, for both oxidized and reduced compounds. The average estimated wet plus dry deposition flux in dry savanna ecosystems is 7.5±1.8 kgN ha−1 yr−1, with approximately 30% attributed to oxidized compounds, and the rest attributed to NHx. The average estimated emission flux ranges from 8.4(±3.8) to 12.4(±5.9) kgN ha−1 yr−1, dominated by NH3 volatilization (72–82%) and biogenic emission from soils (11–17%), depending on the applied volatilization rate of NH3. While larger, emission fluxes are on the same order of magnitude as deposition fluxes. The main uncertainties are linked to the NH3 emission from volatilization. When scaled up from the 3 measurement sites to the Sahelian region (12° N:18° N, 15° W:10° E), the estimated total emission ranges from 2(±0.9) to 3(±1.4) TgN yr−1, depending on the applied volatilization rate of NH3 and estimated total deposition is 1.8(±0.4) TgN yr−1. The dry savanna ecosystems of the Sahel contribute around 2% to the global (biogenic + anthropogenic) nitrogen budget.
Recent applications of digital photogrammetry in forestry have highlighted its utility as a viable mensuration technique. However, in tropical regions little research has been done on the accuracy of ...this approach for stem volume calculation. In this study, the performance of Structure from Motion photogrammetry for estimating individual tree stem volume in relation to traditional approaches was evaluated. We selected 30 trees from five savanna species growing at the periphery of the W National Park in northern Benin and measured their circumferences at different heights using traditional tape and clinometer. Stem volumes of sample trees were estimated from the measured circumferences using nine volumetric formulae for solids of revolution, including cylinder, cone, paraboloid, neiloid and their respective fustrums. Each tree was photographed and stem volume determined using a taper function derived from tri-dimensional stem models. This reference volume was compared with the results of formulaic estimations. Tree stem profiles were further decomposed into different portions, approximately corresponding to the stump, butt logs and logs, and the suitability of each solid of revolution was assessed for simulating the resulting shapes. Stem volumes calculated using the fustrums of paraboloid and neiloid formulae were the closest to reference volumes with a bias and root mean square error of 8.0% and 24.4%, respectively. Stems closely resembled fustrums of a paraboloid and a neiloid. Individual stem portions assumed different solids as follows: fustrums of paraboloid and neiloid were more prevalent from the stump to breast height, while a paraboloid closely matched stem shapes beyond this point. Therefore, a more accurate stem volumetric estimate was attained when stems were considered as a composite of at least three geometric solids.
This work is part of the DACCIWA FP7 project (Dynamics-Aerosol-Chemistry-Cloud Interactions in West Africa) in the framework of the Work Package 2 Air Pollution and Health. This study aims to ...characterize urban air pollution levels through the measurement of NO2, SO2, NH3, HNO3 and O3 in Abidjan, the economic capital of Côte d'Ivoire. Measurements of inorganic gaseous pollutants, i.e. NO2, SO2, NH3, HNO3 and O3 were performed in Abidjan during an intensive campaign within the dry season (15 December 2015 to 16 February 2016), using INDAAF (International Network to study Deposition and Atmospheric chemistry in AFrica) passive samplers exposed in duplicate for 2-week periods. Twenty-one sites were selected in the district of Abidjan to be representative of various anthropogenic and natural sources of air pollution in the city. Results from this intensive campaign show that gas concentrations are strongly linked to surrounding pollution sources and show a high spatial variability. Also, NH3, NO2 and O3 gases were present at relatively higher concentrations at all the sites. NH3 average concentrations varied between 9.1 ± 1.7 ppb at a suburban site and 102.1 ± 9.1 ppb at a domestic fires site. NO2 mean concentration varied from 2.7 ± 0.1 ppb at a suburban site to 25.0 ± 1.7 ppb at an industrial site. Moreover, we measured the highest O3 concentration at the two coastal sites of Gonzagueville and Félix-Houphouët-Boigny International Airport located in the southeast of the city, with average concentrations of 19.1 ± 1.7 and 18.8 ± 3.0 ppb, respectively. The SO2 average concentration never exceeded 7.2 ± 1.2 ppb over all the sites, with 71.5 % of the sampling sites showing concentrations ranging between 0.4 and 1.9 ppb. The HNO3 average concentration ranged between 0.2 and 1.4 ppb. All these results were combined with meteorological parameters to provide the first mapping of gaseous pollutants on the scale of the district of Abidjan using geostatistical analysis (ArcGIS software). Spatial distribution results emphasize the importance of the domestic fires source and the significant impact of the traffic emissions on the scale of the city. In addition, in this work we propose a first overview of gaseous SO2 and NO2 concentrations on the scale of several African cities by comparing literature to our values. The daily SO2 standard of World Health Organization (WHO) is exceeded in most of the cities reported in the overview, with concentrations ranging from 0.2 to 3662 µg m−3. Annual NO2 concentrations ranged from 2 to 175 µg m−3, which are lower than the WHO threshold. As a conclusion, this study constitutes an original database to characterize urban air pollution and a first attempt towards presenting a spatial distribution of the pollution levels at the scale of the metropolis of Abidjan. This work should draw the attention of the African public authorities to the necessity of building an air quality monitoring network in order to (1) to define national standards and to better control the pollutants emissions and (2) to investigate the impact on the health of the growing population in developing African countries.
A number of campaigns have been
carried out to establish the emission factors of pollutants from fuel
combustion in West Africa, as part of work package 2 (“Air Pollution and
Health”) of the DACCIWA ...(Dynamics-Aerosol-Chemistry-Cloud Interactions in
West Africa) FP7 program. Emission sources considered here include wood
(hevea and iroko) and charcoal burning, charcoal making, open trash burning,
and vehicle emissions, including trucks, cars, buses and two-wheeled
vehicles. Emission factors of total particulate matter (TPM), elemental
carbon (EC), primary organic carbon (OC) and volatile organic compounds
(VOCs) have been established. In addition, emission factor measurements were
performed in combustion chambers in order to reproduce field burning
conditions for a tropical hardwood (hevea), and obtain particulate emission
factors by size (PM0.25, PM1, PM2.5 and PM10). Particle
samples were collected on quartz fiber filters and analyzed using gravimetric
method for TPM and thermal methods for EC and OC. The emission factors of 58
VOC species were determined using offline sampling on a sorbent tube.
Emission factor results for two species of tropical hardwood burning of EC,
OC and TPM are 0.98 ± 0.46 g kg−1 of fuel burned (g kg−1),
11.05 ± 4.55 and 41.12 ± 24.62 g kg−1, respectively. For
traffic sources, the highest emission factors among particulate species are
found for the two-wheeled vehicles with two-stroke engines
(2.74 g kg−1 fuel for EC, 65.11 g kg−1 fuel for OC and
496 g kg−1 fuel for TPM). The largest VOC emissions are observed for
two-stroke two-wheeled vehicles, which are up to 3 times higher than
emissions from light-duty and heavy-duty vehicles. Isoprene and monoterpenes,
which are usually associated with biogenic emissions, are present in almost
all anthropogenic sources investigated during this work and could be as
significant as aromatic emissions in wood burning (1 g kg−1 fuel). EC
is primarily emitted in the ultrafine fraction, with 77 % of the total mass
being emitted as particles smaller than 0.25 µm. The particles and
VOC emission factors obtained in this study are generally higher than those
in the literature whose values are discussed in this paper. This study
underlines the important role of in situ measurements in deriving realistic
and representative emission factors.
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