Many interpretations have been proposed to explain the presence of jarosite within Martian surficial sediments, including the possibility that it precipitated within paleo-ice deposits owing to ...englacial weathering of dust. However, until now a similar geochemical process was not observed on Earth nor in other planetary settings. We report a multi-analytical indication of jarosite formation within deep ice. Below 1000 m depth, jarosite crystals adhering on residual silica-rich particles have been identified in the Talos Dome ice core (East Antarctica) and interpreted as products of weathering involving aeolian dust and acidic atmospheric aerosols. The progressive increase of ice metamorphism and re-crystallization with depth, favours the relocation and concentration of dust and the formation of acidic brines in isolated environments, allowing chemical reactions and mineral neo-formation to occur. This is the first described englacial diagenetic mechanism occurring in deep Antarctic ice and supports the ice-weathering model for jarosite formation on Mars, highlighting the geologic importance of paleo ice-related processes on this planet. Additional implications concern the preservation of dust-related signals in deep ice cores with respect to paleoclimatic reconstructions and the englacial history of meteorites from Antarctic blue ice fields.
Accurate estimates of the past extent of the Greenland ice sheet provide critical constraints for ice sheet models used to determine Greenland's response to climate forcing and contribution to global ...sea level. Here we use a continuous ice core dust record from the Renland ice cap on the east coast of Greenland to constrain the timing of changes to the ice sheet margin and relative sea level over the last glacial cycle. During the Holocene and the previous interglacial period (Eemian) the dust record was dominated by coarse particles consistent with rock samples from central East Greenland. From the coarse particle concentration record we infer the East Greenland ice sheet margin advanced from 113.4 ± 0.4 to 111.0 ± 0.4 ka BP during the glacial onset and retreated from 12.1 ± 0.1 to 9.0 ± 0.1 ka BP during the last deglaciation. These findings constrain the possible response of the Greenland ice sheet to climate forcings.
We here investigate the spatial and temporal variability of eolian dust particle sorting recorded in the Dome B (77° 05′ S, 94° 55’ E) ice core, central East Antarctica, during Marine Isotope Stage ...(MIS) 2. We address the question whether such changes reflect variable transport pathways from a unique source area or rather a variable apportionment from diverse Southern Hemisphere sources transported at different elevation in the troposphere. The Sr-Nd radiogenic isotope composition of glacial dust samples as well as single-particle Raman mineralogy support the hypothesis of a single dust provenance both for coarse and fine mode dust events at Dome B. The southern South American provenance of glacial dust in Antarctica deduced from these results indicate a dust composition coherent with a mixture of volcanic material and minerals derived from metamorphic and plutonic rocks. Additionally, Dome B glacial samples contain aragonite particles along with diatom valves of marine benthic/epiphytic species and freshwater species living today in the northern Antarctic Peninsula and southern South America. These data suggest contribution from the exposed Patagonian continental shelf and glacial outwash plains of southern Patagonia at the time when sea level reached its minimum. Our results confirm that dust sorting is controlled by the relative intensity of the two main patterns of tropospheric dust transport onto the inner Plateau, i.e. fast low-level advection and long-range high-altitude transport including air subsidence over Antarctica.
•South American provenance of coarse- and fine-mode dust events at Dome B (Antarctica).•Atmospheric circulation controls dust size variability in Antarctic ice cores.•The Patagonian shelf became an important dust source during MIS 2 sea level minimum.•Importance of Southern Patagonian glacial dust sources.•Raman determination of micron-size mineral grains.
Cryoconite is a mixture of mineral and organic material covering glacial ice, playing important roles in biogeochemical cycles and lowering the albedo of a glacier surface. Understanding the ...differences in structure of cryoconite across the globe can be important in recognizing past and future changes in supraglacial environments and ice-organisms-minerals interactions. Despite the worldwide distribution and over a century of studies, the basic characteristics of cryoconite, including its forms and geochemistry, remain poorly studied. The major purpose of our study is the presentation and description of morphological diversity, chemical and photoautotrophs composition, and organic matter content of cryoconite sampled from 33 polar and mountain glaciers around the globe. Observations revealed that cryoconite is represented by various morphologies including loose and granular forms. Granular cryoconite includes smooth, rounded, or irregularly shaped forms; with some having their surfaces covered by cyanobacteria filaments. The occurrence of granules increased with the organic matter content in cryoconite. Moreover, a major driver of cryoconite colouring was the concentration of organic matter and its interplay with minerals. The structure of cyanobacteria and algae communities in cryoconite differs between glaciers, but representatives of cyanobacteria families Pseudanabaenaceae and Phormidiaceae, and algae families Mesotaeniaceae and Ulotrichaceae were the most common. The most of detected cyanobacterial taxa are known to produce polymeric substances (EPS) that may cement granules. Organic matter content in cryoconite varied between glaciers, ranging from 1% to 38%. The geochemistry of all the investigated samples reflected local sediment sources, except of highly concentrated Pb and Hg in cryoconite collected from European glaciers near industrialized regions, corroborating cryoconite as element-specific collector and potential environmental indicator of anthropogenic activity. Our work supports a notion that cryoconite may be more than just simple sediment and instead exhibits complex structure with relevance for biodiversity and the functioning of glacial ecosystems.
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•The morphology of cryoconite varies greatly between regions.•Cryoconite consists of loose mineral material or various types of granules.•Colour of cryoconite depends on organic matter content and its interplay with minerals.•Cryoconite is a complex structure providing various ecological niches for glacial microbes.
The input of mineral dust from arid regions impacts snow
optical properties. The induced albedo reduction generally alters the
melting dynamics of the snowpack, resulting in earlier snowmelt. In this
...paper, we evaluate the impact of dust depositions on the melting dynamics of
snowpack at a high-elevation site (2160 m) in the European Alps (Torgnon,
Aosta Valley, Italy) during three hydrological years (2013–2016). These
years were characterized by several Saharan dust events that deposited
significant amounts of mineral dust in the European Alps. We quantify the
shortening of the snow season due to dust deposition by comparing observed snow
depths and those simulated with the Crocus model accounting, or not, for the
impact of impurities. The model was run and tested using meteorological data
from an automated weather station. We propose the use of repeated digital
images for tracking dust deposition and resurfacing in the snowpack. The
good agreement between model prediction and digital images allowed us to
propose the use of an RGB index (i.e. snow darkening index – SDI) for
monitoring dust on snow using images from a digital camera. We also present
a geochemical characterization of dust reaching the Alpine chain during
spring in 2014. Elements found in dust were classified as a function of
their origin and compared with Saharan sources. A strong enrichment in Fe
was observed in snow containing Saharan dust. In our case study, the
comparison between modelling results and observations showed that impurities
deposited in snow anticipated the disappearance of snow up to 38 d a out of
a total 7 months of typical snow duration. This happened for the season
2015–2016 that was characterized by a strong dust deposition event. During
the other seasons considered here (2013–2014 and 2014–2015), the snow
melt-out date was 18 and 11 d earlier, respectively. We conclude that the
effect of the Saharan dust is expected to reduce snow cover duration through
the snow-albedo feedback. This process is known to have a series of further
hydrological and phenological feedback effects that should be characterized
in future research.
Cryoconite, the typical sediment found on the surface of glaciers, is mainly known in relation to its role in glacial microbiology and in altering the glacier albedo. But if these aspects are ...relatively well addressed, the same cannot be said about the geochemical properties of cryoconite and the possible interactions with glacial and peri-glacial environment. Current glacier retreat is responsible for the secondary emission of species deposited in high-altitude regions in the last decades. The role played by cryoconite in relation to such novel geochemical fluxes is largely unknown. Few and scarce observations suggest that it could interact with these processes, accumulating specific substances, but why, how and to what extent remain open questions. Through a multi-disciplinary approach we tried to shed lights. Results reveal that the peculiar composition of cryoconite is responsible for an extreme accumulation capability of this sediment, in particular for some, specific, anthropogenic substances.
In this paper, we provide a comprehensive overview of the state-of-knowledge of dust flux and variability in time and space in different sectors of East Antarctica during the Holocene. By integrating ...the literature data with new evidences, we discuss the dust flux and grain-size variability during the current interglacial and its provenance in the innermost part of the East Antarctic plateau as well as in peripheral regions located close to the Transantarctic Mountains. The local importance of aeolian mineral dust aerosol deflated from low-elevation areas of peripheral East Antarctica is also discussed in the light of new data from several coastal, low-elevation sites.
The amount of reflected energy by snow and ice plays a fundamental role in their melting processes. Different non-ice materials (carbonaceous particles, mineral dust (MD), microorganisms, algae, ...etc.) can decrease the reflectance of snow and ice promoting the melt. The object of this paper is to assess the capability of field and satellite (EO-1 Hyperion) hyperspectral data to characterize the impact of light-absorbing impurities (LAIs) on the surface reflectance of ice and snow of the Vadret da Morteratsch, a large valley glacier in the Swiss Alps. The spatial distribution of both narrow-band and broad-band indices derived from Hyperion was analyzed in relation to ice and snow impurities. In situ and laboratory reflectance spectra were acquired to characterize the optical properties of ice and cryoconite samples. The concentrations of elemental carbon (EC), organic carbon (OC) and levoglucosan were also determined to characterize the impurities found in cryoconite. Multi-wavelength absorbance spectra were measured to compare the optical properties of cryoconite samples and local moraine sediments. In situ reflectance spectra showed that the presence of impurities reduced ice reflectance in visible wavelengths by 80–90 %. Satellite data also showed the outcropping of dust during the melting season in the upper parts of the glacier, revealing that seasonal input of atmospheric dust can decrease the reflectance also in the accumulation zone of the glacier. The presence of EC and OC in cryoconite samples suggests a relevant role of carbonaceous and organic material in the darkening of the ablation zone. This darkening effect is added to that caused by fine debris from lateral moraines, which is assumed to represent a large fraction of cryoconite. Possible input of anthropogenic activity cannot be excluded and further research is needed to assess the role of human activities in the darkening process of glaciers observed in recent years.
•Cryoconite accumulates fallout radionuclides with unprecedented efficiency.•Radioactivity in cryoconite is not uniform across the glacier surface.•Supraglacial dynamics and age influence the ...radioactive of cryoconite.•Natural and artificial radionuclides can be used to explore supraglacial dynamics.
Cryoconite, a sediment found on the surface of glaciers, is known for its ability to accumulate radionuclides. New data on cryoconite from the Morteratsch glacier (Switzerland) are presented to shed light on the mechanisms that control the distribution of radioactivity in cryoconite. Among the radionuclides detected in our samples, we have identified 108mAg, an artificial species which has never been observed in terrestrial environments before. This finding supports that cryoconite has an extraordinary ability to accumulate radioactivity. Our results also show that the radioactivity of cryoconite from a single glacier is far from uniform. Both the absolute amount of radioactivity and the relative contribution of single radionuclides are highly variable in samples from the Morteratsch glacier. To investigate the processes responsible for such variability, we have explored the correlation between radionuclides, organic and inorganic carbon fractions and the morphological features of cryoconite deposits. We have found that the degree of connection between cryoconite and supraglacial hydrology is particularly important, since it strongly influences the accumulation of radionuclides in cryoconite. Cryoconite holes connected with supraglacial channels are rich in cosmogenic 7Be; in contrast, poorly connected deposits are rich in artificial fallout radionuclides and elemental carbon. The very different half-lives of 7Be and artificial radionuclides allowed us to discuss our findings in relation to the age and maturity of cryoconite deposits, highlighting the potential use of radionuclides to investigate hydrological supraglacial processes and material cycling at the surface of glaciers.
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