The magneto‐optical ceramics of terbium oxide doped with different rare earth elements (REE) REE:Tb2O3 (REE—Y3+, Lu3+, Sc3+, Ce3+, Dy3+, Ho3+, Yb3+, Nd3+) are successfully fabricated by hot pressing ...using powders obtained by the self‐propagating high‐temperature synthesis (SHS) method. The prepared REE:Tb2O3 ceramics have good optical quality and magneto‐optical properties. The in‐line transmittance of Tb2O3 ceramics doped with REE except Sc3+ is close to undoped terbium oxide, especially in the long‐wavelength region. The Verdet constant of the REE:Tb2O3 samples considered at 633 nm is about 3.3 and 2.6 times higher in absolute value than that of the commercial terbium–gallium garnet (TGG) single crystal and terbium–aluminum garnet (TAG) ceramics, respectively. It is noted that REE (except Yb3+ and Nd3+) doping only slightly increases the Verdet constant of pure Tb2O3 (when the content of terbium ions in the optical element is taken into consideration in the calculation). The dilution of the Tb2O3 matrix with REE in relatively high concentrations leads to a decrease in the absolute value of the Verdet constant.
Rare earth elements in terbium oxide ceramics increase its Verdet constant, normalized to the concentration of terbium ions. However, the Verdet constant absolute value decreases due to the dilution of the Tb2O3 matrix with rare earth elements. Thus, pure terbium oxide has a record Verdet value among the studied materials.
Simultaneous dual-wavelength laser oscillation of Tm:YLF at 1.9 and 2.3 µm were successfully realized. The three-mirror cavity was exploited to study dual-wavelength laser performance, which is ...formed by a shared input mirror and two independent output couplers for the two laser wavelengths. Under an absorbed pump power of 15.2 W, the maximum CW output powers of 5.49 W around 1908nm and 1.12 W around 2305 nm were simultaneously obtained, corresponding to a total optical-to-optical conversion efficiency of 43.5%. A Cr
:ZnSe was further used to passively Q-switch the dual-wavelength laser, generating pulses with pulse widths of 554 ns at 1.9 µm and 4 µs at 2.3 µm. To the best of our knowledge, this is the first report on the dual-wavelength laser operation of Tm
-single-doped solid-state laser at 1.9 and 2.3 µm. The higher optical conversion efficiency, smaller wavelength competition effect and simultaneous dual-wavelength output make this Tm-doped solid-state laser have potential application in medical surgery.
A cycle of works on manufacturing and studying laser and magnetooptical ceramics with a focus on their thermo-optical characteristics performed by the research team is analyzed. Original results that ...have not been published before such as measurements of the Verdet constant in the Zr:TAG, Re:MgAl2O4, and ZnAl2O4 ceramics are also presented.
ZnO samples with an addition of 0, 0.035, 0.1, and 0.35 mol.% Bi2O3 were microwave sintered at heating rates 10 and 50°C/min to a maximum temperature of 1200°C with zero hold time. The densification ...curves obtained by optical dilatometry have been studied in their dependence on the dopant concentration and the heating rate. Direct volumetric absorption of microwave radiation resulted in a 50–60°C shift of the densification curves toward low temperatures compared to susceptor‐assisted heating. An analysis of the effect of the volumetrically absorbed microwave power on the formation of grain‐boundary phases that facilitate densification is presented.
MgAl2O4 samples were microwave sintered to near‐full density in rapid processes with heating rates on the order of 100°C/min and zero isothermal hold. The experiments were carried out using a ...gyrotron system for microwave processing of materials operating at a frequency of 24 GHz with a maximum power of 6 kW. In the regimes with a preset heating rate sustained by the automatically regulated microwave power, the maximum achieved density was about 95% of the theoretical value in pristine MgAl2O4 samples (maximum sintering temperature 1650°C) and about 97% in 1 wt.% Y2O3‐doped samples (1700°C). In the regimes with a fixed microwave power (about 3.5 kW), translucent spinel samples with a relative density above 99% were obtained at 1700°C. The duration of the high‐temperature stage of sintering was 1.5‐10 minutes. The suggested mechanism responsible for the enhanced densification involves development of a thermal instability and formation of transient liquid phases at grain boundaries. The estimated specific absorbed power in the samples during the high‐temperature stage of ultra‐rapid microwave sintering was 27‐80 W/cm3, similar to the values observed in dc field‐assisted flash sintering experiments.
The synthesis of nanopowders of terbia compounds with scandia, yttria, and lutetia was carried out using a self-propagating high-temperature synthesis method involving a mixture of nitrates of metals ...and glycine as a precursor. The nanopowder phase transformations were investigated using X-ray diffraction analysis. It was found that lutetia has a negligible effect on the phase formation in terbia. On the other hand, yttrium and scandium ions significantly suppressed crystallization. The densification kinetics of nanopowders of the Tb
2
O
3
compounds and the microstructure of ceramics after microwave sintering were studied using dilatometry and scanning electron microscopy. The introduction of scandia, yttria, or lutetia contributed to the intensification of the densification of the terbia ceramics when heated in a microwave field. Near full-density materials of terbia solid solutions with lutetia and yttria were obtained at about 1600–1640 °C. The ceramics of scandia–terbia compounds contained the second phase, which causes light scattering.
A glycine-nitrate self-propagating high-temperature synthesis (SHS) was developed to produce composite MgO-Gd
2
O
3
nanopowders. The X-ray powder diffraction (XRD) analysis confirmed the SHS-product ...consists of cubic MgO and Gd
2
O
3
phases with nanometer crystallite size and retains this structure after annealing at temperatures up to 1200 °C. Near full dense high IR-transparent composite ceramics were fabricated by spark plasma sintering (SPS) at 1140 °C and 60 MPa. The in-line transmittance of 1 mm thick MgO-Gd
2
O
3
ceramics exceeded 70% in the range of 4–5 mm and reached a maximum of 77% at a wavelength of 5.3 mm. The measured microhardness HV0.5 of the MgO-Gd
2
O
3
ceramics is 9.5±0.4 GPa, while the fracture toughness (
K
IC
) amounted to 2.0±0.5 MPa·m
1/2
. These characteristics demonstrate that obtained composite MgO-Gd
2
O
3
ceramic is a promising material for protective infra-red (IR) windows.
Transparent ceramics based on ytterbium oxide have been successfully produced by vacuum sintering of self-propagating high-temperature synthesized powders with use of a La2O3 sintering aid. Phase ...composition and microstructure of the initial powders were studied by X-ray diffraction analysis and scanning electron microscopy. It was found that addition of 5 mol.% of La2O3 does not cause formation of secondary phases in the Yb2O3 powders. The 4% La:Yb2O3 ceramics showed the best in-line transmittance of 73% at a wavelength of 2 μm among the studied samples. Dependence of the Verdet constant on wavelength was investigated in the range of 0.4–2 μm. The most promising finding is use of the obtained material as Faraday isolators in the wavelength region of ~1.5 μm, where there are no absorption bands, and the Verdet constant is 8.6 rad/(T*m).
In the presented work, the prospects for using pure ZnS and CdSe semiconductors for the development of Faraday isolators are investigated. Both materials have advantages over conventional ...magnetoactive materials. Their use can make it possible to expand the spectral range, in which isolators for high-power laser radiation can be implemented, both in the long-wavelength and short-wavelength regions. Measurements of the Verdet constant of crystals and the dependence of thermally induced depolarization caused by stress-induced birefringence on laser power were carried out. Based on the obtained experimental data, the parameters of the magneto-optical figure of merit were determined. The studied samples showed promising results, while the potential for increasing the magneto-optical figure of merit by optimizing the parameters of the production process is assessed as high. This possibility is illustrated by the example of ZnSe crystal samples obtained in various technological processes.
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(Dy0.7Y0.25La0.05)2O3 magneto-optical transparent ceramics were successfully fabricated by pressureless sintering in reductive H2 atmosphere (PLSH). The raw powder of (Dy0.7Y0.25La0.05)2O3 was ...synthesized by a modified self-propagating high-temperature synthesis (SHS) and sintered to transparent ceramics at 1400–1600 °C in a flowing H2 atmosphere, showing good sinterability of the as-synthesized raw powder. The magneto-optical Verdet constant of (Dy0.7Y0.25La0.05)2O3 transparent ceramics was measured to be −191.57 rad/(T·m) at a wavelength of 632.8 nm. In this magneto-optical material of (Dy0.7Y0.25La0.05)2O3, relative cheaper Dy and Y were used to replace Tb, and the low cost and good magneto-optical property showed the advantage of application on Faraday isolators (FIs) and Faraday rotators (FRs).
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