High-temperature crystallization domains (HTCDs) including spherulites and lithophysae form during cooling of silica-rich lava and welded ignimbrites. Spherulites grow in silicate melts or hot glass ...and they display a radiating or microcrystalline texture, typically consisting of cristobalite, tridymite, and sanidine. Lithophysae are HTCDs comprising one or more cavities. This contribution reviews the research and discussions on HTCDs carried out over the last 200 years. The emphasis, here, is on lithophysae and summarizes current knowledge of their formation. A number of parameters influence the initiation and growth of lithophysae, as well as, their shapes and internal textures. The most likely cause of cavity formation is transient tensional stress that produces a mechanical opening and widening at the interface between the crystallization front and the host melt (e.g., where
T
>
T
g
). Cavity growth and expansion forced by rising vapor pressure is considered less important. In some cases, further growth of HTCD cavities results from vapor phase corrosion and brecciation.
Textures and whole-rock chemistry, as well as mineral composition, were analyzed in megaspherulites (high-temperature crystallization domains HTCDs) that formed in different geographical and ...geotectonic contexts and during different geological periods (Silver Cliff, CO, USA—Paleogene; El Quevar, Argentina—Miocene; Meissen Volcanic Complex, Germany—Late Carboniferous). All of these megaspherulites have formed exclusively in rhyolitic lava, and their mineral composition is dominated by K-feldspar (sanidine) and SiO
2
phases (quartz, cristobalite, tridymite). All megaspherulites represent composite HTCDs, comprising three zones: inner domain (ID), outer domain (OD), and a marginal domain (MD). Early evolution of megaspherulites is characterized by either central cavities and sector- to full-sphere spherulites or dendritic quartz-sanidine domains. The latter consist of bundles of fibrils each radiating from a single point reflecting relatively high growth rates. A common feature of OD and MD of all three megaspherulite occurrences is autocyclic banding. It mainly comprises fibrous (≤ 100 μm length), radially oriented sanidine and quartz, which formed at a temperature close to glass transition temperature (
T
g
). The termination of megaspherulite growth is marked by centimeter-sized sector-sphere spherulites on the surface. Megaspherulite formation requires limited nucleation, which is probably related to the low phenocryst content of the hosting lava. Latent heat from overlying crystallizing lithoidal rhyolite maintained low undercooling conditions keeping nucleation density low and facilitating high diffusion and growth rates. Late megaspherulite growth and its termination under low diffusion conditions is controlled by cooling close to
T
g
. Calculations based on literature data suggest that the megaspherulite growth presumably lasted less than 60 years, perhaps 30 to 40 years.
Samples and documentation of outcrops and drillings, facies analysis, whole rock geochemistry and radiometric ages have been employed to re-evaluate the Late Carboniferous Tharandt Forest caldera ...(TFC) and the co-genetic Niederbobritzsch granite (NBG) in the eastern Erzgebirge near Dresden, Germany. The c. 52 km
2
TFC harbours strongly welded ignimbrites with a preserved minimum thickness of 550 m. Composition of initial fallout tephra at the base of the TFC fill, comprising lithics of rhyolitic and basic lava, and of silica-rich pyroclastic rocks, suggests a bimodal volcanic activity in the area prior to the climactic TFC eruption. The lower part of the TFC fill comprises quartz-poor ignimbrites, overlain by quartz-rich ignimbrites, apparently without a depositional break. Landslides originating from the collapse collar of the caldera plunged into the still hot TFC fill producing monolithic gneiss mesobreccia with clasts ≤ 1 m in a pyroclastic matrix. Aphanitic and porphyritic rhyolitic magma formed ring- and radial dykes, and subvolcanic bodies in the centre of TFC. Whole rock geochemical data indicate a high silica (most samples have > 73 wt% SiO
2
) rhyolitic composition of the TFC magma, and a similar granodiorite–granitic composition for the NBG. Based on drillings and caldera extent, a minimum volume of 22 km
3
of TFC fill is preserved, the original fill is assumed at about 33 km
3
. This estimate translates into a denudation of at least c. 210 m during Late Paleozoic to pre-Cenomanian. Telescopic subsidence of the TFC took place in two, perhaps three stages. A possible TFC outflow facies has been completely eroded and distal TFC tuff has not been recognized in neighboring basins. New CA-ID-TIMS measurements on two TFC samples gave mean zircon ages of 313.4 ± 0.4 Ma and 311.9 ± 0.4 Ma; two samples from NBG resulted in 318.2 ± 0.5 Ma and 319.5 ± 0.4 Ma. In addition, for one sample of the ring dyke an age of ca. 314.5 ± 0.5 Ma has been obtained. These ages, together with field relations, allow for a model of a long-standing evolution of an upper crustal magmatic system (~ 5 Ma?), where pulses of magmatic injection and crustal doming alternate with magmatic quietness and erosion. Together with the Altenberg–Teplice Volcanic Complex, located some 10 km to the southeast, the TFC–NBG Complex represents an early post-Variscan magmatic activity in central Europe.
Extensional tectonics in the Late Paleozoic Central Europe was accompanied by rift magmatism that triggered voluminous intracontinental caldera-forming eruptions. Among these, the Lower Permian ...Rochlitz Volcanic System (RVS) in the North Saxon Volcanic Complex (Eastern Germany, Saxony) represents a supereruption (VEI 8, estimated volume of 1056 km
3
) of monotonous rhyolites followed by monotonous intermediates. Mapping, petrography, whole-rock geochemistry along with mineral chemistry and oxygen isotopes in zircon display its complex eruption history and magma evolution. Crystal-rich (> 35 vol%), rhyolitic Rochlitz-α Ignimbrite with strong to moderate welding compaction erupted in the climactic stage after reheating of the magma by basaltic injections. Due to magma mixing, low-volume trachydacitic-to-rhyolitic Rochlitz-β Ignimbrite succeeded, characterized by high Ti and Zr-values and zircon with mantle δ
18
O. Randomly oriented, sub-horizontally bedded fiamme, and NW–SE striking subvolcanic bodies and faults suggest pyroclastic fountaining along NW–SE-oriented fissures as the dominant eruption style. Intrusion of the Leisnig and the Grimma Laccoliths caused resurgence of the Rochlitz caldera forming several peripheral subbasins. In the post-climactic stage, these were filled with lava complexes, ignimbrites and alluvial to lacustrine sediments. Significant Nb and Ta anomalies and high Nb/Ta ratios (11.8–17.9) display a high degree of crustal contamination for the melts of the RVS. Based on homogenous petrographic and geochemical composition along with a narrow range of δ
18
O in zircon Rochlitz-α Ignimbrite were classified as monotonous rhyolites. For the Rochlitz-β Ignimbrites, underplating and mixing with basic melts are indicated by Mg-rich annite–siderophyllite and δ
18
O < 6.0 in zircon. The wide spectrum of δ
18
O on zircon suggests an incomplete mixing process during the formation of monotonous intermediates in the RVS.
The Skoura inlier in the Moroccan High Atlas consists of thick Precambrian–Paleozoic formations. It displays, in the western part near Aguerzega village, a volcano-sedimentary succession of about ...400 m thickness. It includes a variety of welded and non-welded ignimbrites, lapilli-tuff fallout deposit, coherent lava, sedimentary mass flow deposit and fluvial sediments, which are grouped into three lithofacies associations, corresponding to different depositional environments. The volcanic activity in the studied area represents successive volcanic eruptions, alternating with phases of quiescence (sedimentary beds). The Ediacaran volcano-sedimentary succession of the Skoura inlier represents an evolution in four stages in a subaerial environment. The geochemical results obtained from Skoura volcanic rocks display high silica-rich composition ranging from dacite to rhyolite. Major and trace elements show high-K calc-alkaline and alkali-calcic to alkaline affinities and reflect an active continental margin signature. In addition, the studied rocks show enriched LILE compared to HFSE with negative Nb-, Ta- and Ti anomalies. This is consistent with a post-collisional setting, documented for the final phase of the Pan-African orogeny. Laser ablation U–Pb zircon dating on three rhyolitic ignimbrites from the base and top of two profiles, yielded ages of 580 ± 7 Ma, 574 ± 14 Ma and 571 ± 4 Ma. These ages compare well with the lower Ouarzazate Supergroup, widespread in the Anti-Atlas, as well as in the High Atlas and with rare exposures in the Meseta domain in northern Morocco.
Subvolcanic intrusions are highly variable in shape and structure, and occur in nearly all parts of the upper crust, as a result of extensive volcanic activity. Processes of subvolcanics interacting ...with the host rock are insufficiently understood, as they are rarely exposed. In the southernmost part of the Flechtingen-Altmark Subprovince, (sub)volcanic rocks of the Flechtingen Volcanic Complex (FVC) are exposed in several quarries. It is built up of silicic tuffs, ignimbrites and lava flows, but also of intermediate lavas and extended sill sheets. Additionally, major granitic intrusions exposed by drillings are associated with the FVC. In the Mammendorf quarry, a sill intruded in between lithified turbiditic series of early Carboniferous (Visean–Serphukovian) age at the base, and widely consolidated volcanoclastic deposits of late Carboniferous (late Pennsylvanian) age at the top. Various magma-host rock interactions were found indicating brittle and ductile deformation patterns occurring at the basal contact, and secondary fluidal mixing predominantly occurring at the top contact, most probably caused by fluids accompanying the intruding magma. We present an extended volcanogenetic model for the FVC. Volcanic activity initiated at 302 ± 3 Ma with fallout deposits represented by mostly re-deposited silicic ashfall deposits of the Flechtingen Formation, and cumulated in depositing major ignimbrite series, most likely forming a caldera. Later, the sills intruded at the rheological boundary of the lithified Mississippian turbiditic series and the partly consolidated volcanoclastic series. Finally, major granitic intrusions emplaced in the basement rocks at around 298 ± 4 Ma. The study contributes to clarify stratigraphic constraints of late Carboniferous to early Permian continental deposits and sheds light on stratigraphy of significant late Paleozoic volcanic deposits of the Flechtingen-Altmark Subprovince in the Southern Permian Basin.
Zircon is a main mineral used for dating rhyolitic magmas as well as reconstructing their differentiation. It is common that different populations of zircon grains occur in a single rhyolitic sample. ...The presence of both autocrystic and antecrystic zircon grains is reflected in their strongly varied chemical compositions and slight spread of ages. However, postmagmatic processes may induce lead loss, which is also recorded as a spread of zircon ages. Therefore, new approaches to identify different zircon populations in rhyolitic rocks are needed. In this study, we suggest that detailed examination of zircon positions in the thin sections of rhyolitic rocks provides valuable information on zircon sources that can be used to identify autocrystic and antecrystic zircon populations. Automated Scanning Electron Microscope (SEM) analyses are of great applicability in determining this, as they return both qualitative and quantitative information and allow for quick comparisons between different rhyolite localities. Five localities of Permo-Carboniferous rhyolites related to post-Variscan extension in Central Europe (Organy, Bieberstein, Halle, Chemnitz, Krucze) were analyzed by automated SEM (MLA-SEM). The samples covered a range of Zr whole rock contents and displayed both crystalline and glassy groundmass. Surprisingly, each locality seemed to have its own special zircon fingerprint. Based on comparisons of whole rocks, modal composition and SEM images Chemnitz ignimbrite was interpreted as containing mostly (or fully) antecrystic zircon, whereas the Bieberstein dyke was shown to possibly contain both types, with the antecrystic zircon being associated with disturbed cumulates. On the other hand, Organy was probably dominated by autocrystic zircon, and Krucze contained dismembered, subhedral zircon in its matrix, whereas Halle zircon was located partly in late veins, filling cracks in laccolith. Both localities may, therefore, contain zircon populations that represent later stages than the crystallization of the main rhyolitic body.
Compositionally zoned plutons, both layered and concentrically arranged, provide granitic exposures where the mechanisms and timing of the magmatic emplacement processes can be studied. The ...importance of in-situ geochemical differentiation and the magma replenishment rates are revealed by geochemistry and field relations, together with the increasingly accurate U–Pb geochronology, which has promoted the knowledge about the pluton incremental assembly theories.
The Flamenco pluton, located in the Coastal Range of northern Chile, is part of the Upper Triassic to Early Cretaceous Andean intrusives formed in the western active margin of South America, and present a normal zoned structure with mafic magmatic facies (mostly gabbros and Qtz-diorites) close to the contacts with the host metasediments, and tonalites, granodiorites and granites in the inner areas. A combined study of the field relations, geochemistry and zircon geochronology of the magmatic facies was applied to determine the emplacement sequence of the Flamenco pluton, revealing three distinguishable domains separated by metasedimentary septa. The SW area is constituted by mostly homogeneous leucocratic granodiorites that yielded an age of 213 Ma as the best estimation for their emplacement age. Distinctive geochemical characteristics, such as the absence of an Eu anomaly, the depletion in HREE, or the highest Sr, Sr/Y and Ce/Yb values among the granodioritic facies of the pluton, involve lower T and/or higher P conditions at the magmatic source according to experimental studies. These conditions were established during an early stage of the Andean magmatic arc building that is firstly defined here as Upper Triassic. The NW and E domains of the pluton were sequentially emplaced between 194 Ma and 186 Ma and both the field relations and the detailed geochronological results suggest that the mafic facies intruded latter in the emplacement sequence. To the NW, Qtz-dioritic and gabbroic externally emplaced pulses gave a younger crystallization age of 186.3 ± 1.8 Ma, and promoted the granoblastic textures and metamorphic zircon overgrowths that characterize the granodiorites located in the contact with the intermediate and felsic inner magmas, which yielded a best estimation of their emplacement age of 192 ± 1.5 Ma. On the other hand, in the eastern domain, magma-magma relations are observed between gabbros and previously intruded tonalites and granodiorites. Both the mafic and intermediate facies show two main subgroups of ages that yielded 194.7 ± 1.5 Ma to 188.3 ± 2.1 Ma and 193.1 ± 2.2 Ma to 185.5 ± 1.4 Ma respectively. These differences are related to the variations in the magmatic addition rates, which may extend the super-solidus conditions in the eastern domain of the magmatic reservoir as is confirmed by the wider age ranges yielded by these magmatic facies. Zircon overgrowths in the host rocks yield similar ages (around 220 Ma and 205 Ma) than the oldest results obtained in the intrusive facies, indicating that metamorphism correlates with the initial stages of plutonic emplacement.
Geochronological results differ between 9 Myr and 41 Myr in the eight studied samples for non-inherited ages and gave very close mean ages (within analytical uncertainty) for all the intrusive units. However, we examine other characteristics such as zircon morphology, internal structure, geochemistry and statistical data to assess if the scattering of the geochronological data may be related to the different processes involved in the construction of the Flamenco pluton. We concluded that this detailed study of U–Pb zircon ages, including individual and significative groups of analyses, is useful to determine accurately the emplacement sequence and the genetic relation between the intrusive units, together with the evidences depicted by the geochemistry and field relations.
Display omitted
•Andean Cordilleran-type Upper Triassic to Lower Jurassic zoned pluton.•Different emplacement relations in coeval geochemically similar magmatic batches.•The significance of different methodological approaches to U–Pb geochronology results.•Geochemical and field relations evidences constrain the analysis of U–Pb zircon ages.•A normally (outer mafic to inner felsic) zoned pluton with an inverse (older inner facies) emplacement sequence.
The 500 m long section through the upper part of the Permo-Carboniferous Landsberg laccolith (Halle Volcanic Complex) was sampled every 25 meters. The modal proportions between plagioclase and ...K-feldspar phenocrysts vary in the section and the laccolith may be divided into four parts with different proportions of Pl/Kfs, which, in subvolcanic rocks, should reflect different proportions of these minerals in the magma plumbing system. Chemical composition of whole rock samples is uniform, but the correlations of Si and other elements with depth within all of the four sections suggest that the sections based on modal composition are also reflected in chemical composition of the rock. Also, the uppermost 100 meters of the laccolith has slightly higher contents of Fe, Ti, Zr and Nb compared to those in the rest of the laccolith and this is consistent with it being a separate magma pulse derived from a distinct source. Detailed analyses of chemical variations within each section are consistent with the model that the upper 500 meters of the Landsberg laccolith was formed by three successive pulses with slightly different chemical compositions. The best documented is the uppermost pulse, which was over-accreted on the first pulse. Another pulse was probably emplaced in the middle of the first pulse. The thickness of the pulses was 100–300 m, which is consistent with previous 2D and 3D emplacement models of the Halle laccoliths. However, the contacts between the pulses based on modal and chemical compositional variations are not always concurrent with the presence of shearing zones, the discrepancy that is not yet well understood. In general, because silica-rich laccoliths are relatively small bodies that cool quickly due to high level of emplacement, they may preserve better evidence for separate magma pulses compared to plutonic batholiths.
PDF
