The benzene dimer, an important prototype for studying noncovalent interactions, exhibits characteristic splitting patterns in its rotational spectrum, which for a long time were not understood. A ...new theoretical model reveals their origin: a concerted internal motion involving sixfold hindered rotation tunneling of the molecule forming the stem of the T‐shaped structure and tilt tunneling of the cap.
Cosmogenic activation of silicon Saldanha, R.; Thomas, R.; Tsang, R. H. M. ...
Physical review. D,
11/2020, Letnik:
102, Številka:
10
Journal Article
Recenzirano
Odprti dostop
The production of 3H, 7Be, and 22Na by interactions of cosmic-ray particles with silicon can produce radioactive backgrounds in detectors used to search for rare events. Through controlled ...irradiation of silicon CCDs and wafers with a neutron beam that mimics the cosmic-ray neutron spectrum, followed by direct counting, we determined that the production rate from cosmic-ray neutrons at sea level is ( 112 ± 24 ) atoms / ( kg day ) for 3H, ( 8.1 ± 1.9 ) atoms / ( kg day ) for 7Be, and ( 43.0 ± 7.2 ) atoms / ( kg day ) for 22Na. Complementing these results with the current best estimates of activation cross sections for cosmic-ray particles other than neutrons, we obtain a total sea-level cosmic-ray production rate of ( 124 ± 25 ) atoms / ( kg day ) for 3H, ( 9.4 ± 2.0 ) atoms / ( kg day ) for 7Be, and ( 49.6 ± 7.4 ) atoms / ( kg day ) for 22Na. These measurements will help constrain background estimates and determine the maximum time that silicon-based detectors can remain unshielded during detector fabrication before cosmogenic backgrounds impact the sensitivity of next-generation rare-event searches.
: This paper presents a review of the publicly available knowledge base concerning turbine blade tip heat transfer, from the early fundamental research which laid the foundations of our knowledge, to ...current experimental and numerical studies utilizing engine‐scaled blade cascades and turbine rigs. Focus is placed on high‐pressure, high‐temperature axial‐turbine blade tips, which are prevalent in the majority of today's aircraft engines and power generating turbines. The state of our current understanding of turbine blade tip heat transfer is in the transitional phase between fundamentals supported by engine‐based experience, and the ability to a priori correctly predict and efficiently design blade tips for engine service.
We report a combined theoretical and microwave spectroscopy study of the internal dynamics of the benzene dimer, a benchmark system for dispersion forces. Although the extensive ab initio ...calculations and experimental work on the equilibrium geometry of this dimer have converged to a tilted T-shaped structure, the rich internal dynamics due to low barriers for internal rotation have remained largely unexplored. We present new microwave spectroscopy data for both the normal (C6H6)2 and partially deuterated (C6D6)(C6H6) dimers. The splitting patterns obtained for both species are unraveled and understood using a reduced-dimensionality theoretical approach. The hindered sixfold rotation of the stem can explain the observed characteristic 1 : 2 : 1 tunneling splitting pattern, but only the concerted stem rotation and tilt tunneling motion, accompanied by overall rotation of the dimer, yield the correct magnitude of the splittings and their strong dependence on the dimer angular momentum J that is essential to explain the experimental data. Also the surprising observation that the splittings are reduced by 30% for the mixed (C6D6)(C)(C6H6)(S) dimer in which only the cap (C) in the T-shaped structure is deuterated, while the rotating stem (S) monomer is the same as in the homodimer, is understood using this approach. Stark shift measurements allowed us to determine the dipole moment of the benzene dimer, μ = 0.58 ± 0.051 D. The assumption that this dipole moment is the vector sum of the dipole moments induced in the monomers by the electric field of the quadrupole on the other monomer yields a calculated value of μ = 0.63 D. Furthermore, the observed Stark behavior is typical for a symmetric top, another confirmation of our analysis.
An improved intermolecular potential surface for the benzene dimer is constructed from interaction energies computed by symmetry-adapted perturbation theory, SAPT(DFT), with the inclusion of ...third-order contributions. Twelve characteristic points on the surface have been investigated also using the coupled-cluster method with single, double, and perturbative triple excitations, CCSD(T), and triple-zeta quality basis sets with midbond functions. The SAPT and CCSD(T) results are in close agreement and provide the best representation of these points to date. The potential was used in calculations of vibration-rotation-tunneling (VRT) levels of the dimer by a method appropriate for large amplitude intermolecular motions and tunneling between multiple equivalent minima in the potential. The resulting VRT levels were analyzed with the use of the permutation-inversion full cluster tunneling (FCT) group G(576) and a chain of subgroups that starts from the molecular symmetry group C(s)(M) of the rigid dimer at its equilibrium C(s) geometry and leads to G(576) if all possible intermolecular tunneling mechanisms are feasible. Further information was extracted from the calculated wave functions. It was found, in agreement with the experimental data, that for all of the 54 G(576) symmetry species (with different nuclear spin statistical weights) the lower VRT states have a tilted T-shape (TT) structure; states with the parallel-displaced structure are higher in energy than the ground state of A symmetry by at least 30 cm(-1). The dissociation energy D(0) equals 870 cm(-1), while the depth D(e) of the TT minimum in the potential is 975 cm(-1). Hindered rotation of the cap in the TT structure and tilt tunneling lead to level splittings on the order of 1 cm(-1). Also intermolecular vibrations with excitation energies starting at a few cm(-1) were identified. A further small, but probably significant, level splitting was assigned to cap turnover, although in scans of the potential surface we could not find a plausible 'reaction path' for this process. Rotational constants were extracted from energy levels calculated for total angular momentum J = 0 and 1, and from expectation values of the inertia tensor. Although the end-over-end rotational constant B + C agrees well with the measured microwave spectra, there is disagreement with the measurements concerning the (a)symmetric rotor character of the benzene dimer. It is concluded from calculations for the 54 nuclear spin species that the microwave spectrum should show overlapping contributions from many different species. Another interesting conclusion regards the role of the quantum number K, for a prolate near-symmetric rotor the projection of the total angular momentum on the prolate axis. For the benzene dimer, K has a substantial effect on the energy levels associated with the intermolecular motions of the complex.
Stark Effect in the Benzene Dimer Schnell, Melanie; Bunker, P. R; von Helden, Gert ...
The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory,
12/2013, Letnik:
117, Številka:
50
Journal Article
Recenzirano
Ab initio calculations of the six-dimensional intermolecular potential have shown the benzene dimer to be an asymmetric top molecule at equilibrium with one benzene moiety forming the “stem” and the ...other a “tilted cap” in a T-shaped structure. Internal rotation of the cap about its C 6 axis is essentially free; the barriers for cap tilting and for internal rotation of the stem about its C 6 axis are hindered by successively higher barriers. In previous work we have validated these theoretical results using Fourier transform microwave spectroscopy in conjunction with dynamics calculations. We have also measured the Stark effect, and despite the fact that the equilibrium structure is that of an asymmetric top, the assigned transitions involving K = 0 exhibit a second-order Stark effect whereas those involving K = 1 exhibit a first-order Stark effect. This is typical for a symmetric-top molecule, but anomalous for an asymmetric-top molecule. We use symmetry arguments to explain how this asymmetric-top molecule can have a first-order Stark effect in certain states that have excitation of cap internal rotation. Cap internal rotation is essentially the twisting of the monomers relative to each other about the intermolecular axis, and such torsional motion occurs in other asymmetric top dimers such as benzene–CO and benzene–H2O. These latter dimers will also have levels that exhibit a first-order Stark effect, which we can explain using our symmetry arguments.
Abstract
The SuperCDMS SNOLAB dark matter search experiment aims to
be sensitive to energy depositions down to
(1 eV). This imposes requirements on the resolution,
signal efficiency, and noise ...rejection of the trigger system. To
accomplish this, the SuperCDMS level-1 trigger system is implemented
in an FPGA on a custom PCB. A time-domain optimal filter algorithm
realized as a finite impulse response filter provides a baseline
resolution of 0.38 times the standard deviation of the noise,
σ
n
, and a 99.9% trigger efficiency for signal
amplitudes of 1.1 σ
n
in typical noise
conditions. Embedded in a modular architecture, flexible trigger
logic enables reliable triggering and vetoing in a dead-time-free
manner for a variety of purposes and run conditions. The trigger
architecture and performance are detailed in this article.
In accordance with previous studies in our group on Be, Mg, and Ca hypermetallic oxides, we find that SrOSr has a linear X̃ 1Σg + ground electronic state and a very low lying first excited ã 3Σu + ...triplet electronic state. No gas-phase spectrum of this molecule has been assigned yet, and to encourage and assist in its discovery we present a complete ab initio simulation, with absolute intensities, of the infrared absorption spectrum for both electronic states. The three-dimensional potential energy surfaces and the electric dipole moment surfaces of the X̃ 1Σg + and ã 3Σu + electronic states are calculated using a multireference configuration interaction (MRCISD) approach in combination with internally contracted multireference perturbation theory (RS2C) based on complete active space self-consistent field (CASSCF) wave functions applying a Sadlej pVTZ basis set for both O and Sr and the Stuttgart relativistic small-core effective core potential for Sr. The infrared spectra are simulated using the MORBID program system. We also calculate vertical excitation energies and transition moments for several excited singlet and triplet electronic states in order to predict the positions and intensities of the most prominent singlet and triplet electronic absorption bands. Finally, for this heavy molecule, we calculate the singlet–triplet interaction matrix elements between close-lying vibronic levels of the X̃ and ã electronic states and find them to be very small.
Separation of glow stick dyes adhered to a cotton swab using liquid CO
2
provides an engaging demonstration of several chemical concepts including polarity, kinetics, chemiluminescence, and the ...importance of CO
2
a green solvent. The simple protocol allows access to a broad range of students. Differential polarities of the glow stick dyes allow certain dyes to be preferentially dissolved in liquid CO
2
, leaving other dyes adhered onto cotton. Both TCPO (bis(2,4,6-trichlorophenyl)oxalate) and H
2
O
2
, which together provide the necessary reaction for chemiluminescence, are present in both the extracted liquid and cotton upon dissipation of CO
2
. Thus, it is possible to compare the emission spectrum of the extracted fluid to that of the original glow stick and the residue left on the cotton swab. Emission peaks resulting from the presence of polar dyes in the original glow stick and on the cotton are routinely observed to be missing in the extracts.
The 2007 flora “Green Seaweeds of Britain and Ireland” did not present the molecular data underpinning the Ulvaceae treatment, mostly ITS sequences. Subsequently, names have changed as type material ...of
species is sequenced and intensive sampling with DNA barcoding adds new European species. To update the Ulvaceae, we systematically sampled from 2007 to 2021, identifying specimens using various molecular markers alongside DNA from type material of four species. We show here that
, based on
L,
A and ITS sequences of its holotype, is assigned to
, as is the lectotype of
.
sensu GenBank and
are conspecific. The correct name is
based on
L sequences of the lectotype. Two species of monostromatic Ulvaceae were included in the 2007 flora, but we show that both of them and all earlier British monostromatic collections represent
, a species originally described from Alaska. Analysis of two
L amplicons of the
lectotype shows that it is conspecific with
. Our first genuine collections of
from SW England and SW Wales correspond to topotype material from the Bay of Biscay, recent samples from Galicia and unpublished
A sequences from Britanny.
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