We calculated the organic matter to organic carbon mass ratios (OM/OC mass ratios) in PM2.5 collected from 14 Chinese cities during summer and winter of 2003 and analyzed the causes for their ...seasonal and spatial variability. The OM/OC mass ratios were calculated two ways. Using a mass balance method, the calculated OM/OC mass ratios averaged 1.92 ± 0.39 year-round, with no significant seasonal or spatial variation. The second calculation was based on chemical species analyses of the organic compounds extracted from the PM2.5 samples using dichloromethane/methanol and water. The calculated OM/OC mass ratio in summer was relatively high (1.75 ± 0.13) and spatially-invariant due to vigorous photochemistry and secondary organic aerosol (OA) production throughout the country. The calculated OM/OC mass ratio in winter (1.59 ± 0.18) was significantly lower than that in summer, with lower values in northern cities (1.51 ± 0.07) than in southern cities (1.65 ± 0.15). This likely reflects the wider usage of coal for heating purposes in northern China in winter, in contrast to the larger contributions from biofuel and biomass burning in southern China in winter. On average, organic matter constituted 36% and 34% of Chinese urban PM2.5 mass in summer and winter, respectively. We report, for the first time, a high regional correlation between Zn and oxalic acid in Chinese urban aerosols in summer. This is consistent with the formation of stable Zn oxalate complex in the aerosol phase previously proposed by Furukawa and Takahashi (2011). We found that many other dicarboxylic acids were also highly correlated with Zn in the summer Chinese urban aerosol samples, suggesting that they may also form stable organic complexes with Zn. Such formation may have profound implications for the atmospheric abundance and hygroscopic properties of aerosol dicarboxylic acids.
The 2020 magnetism roadmap Vedmedenko, E Y; Kawakami, R K; Sheka, D D ...
Journal of physics. D, Applied physics,
11/2020, Letnik:
53, Številka:
45
Journal Article
Recenzirano
Odprti dostop
Andreas Berger CICnanoGUNE BRTA Following the success and relevance of the 2014 and 2017 Magnetism Roadmap articles, this 2020 Magnetism Roadmap edition takes yet another timely look at newly ...relevant and highly active areas in magnetism research. The overall layout of this article is unchanged, given that it has proved the most appropriate way to convey the most relevant aspects of today's magnetism research in a wide variety of sub-fields to a broad readership. A different group of experts has again been selected for this article, representing both the breadth of new research areas, and the desire to incorporate different voices and viewpoints. The latter is especially relevant for thistype of article, in which one's field of expertise has to be accommodated on two printed pages only, so that personal selection preferences are naturally rather more visible than in other types of articles. Most importantly, the very relevant advances in the field of magnetism research in recent years make the publication of yet another Magnetism Roadmap a very sensible and timely endeavour, allowing its authors and readers to take another broad-based, but concise look at the most significant developments in magnetism, their precise status, their challenges, and their anticipated future developments. While many of the contributions in this 2020 Magnetism Roadmap edition have significant associations with different aspects of magnetism, the general layout can nonetheless be classified in terms of three main themes: (i) phenomena, (ii) materials and characterization, and (iii) applications and devices. While these categories are unsurprisingly rather similar to the 2017 Roadmap, the order is different, in that the 2020 Roadmap considers phenomena first, even if their occurrences are naturally very difficult to separate from the materials exhibiting such phenomena. Nonetheless, the specifically selected topics seemed to be best displayed in the order presented here, in particular, because many of the phenomena or geometries discussed in (i) can be found or designed into a large variety of materials, so that the progression of the article embarks from more general concepts to more specific classes of materials in the selected order. Given that applications and devices are based on both phenomena and materials, it seemed most appropriate to close the article with the application and devices section (iii) once again. The 2020 Magnetism Roadmap article contains 14 sections, all of which were written by individual authors and experts, specifically addressing a subject in terms of its status, advances, challenges and perspectives in just two pages. Evidently, this two-page format limits the depth to which each subject can be described. Nonetheless, the most relevant and key aspects of each field are touched upon, which enables the Roadmap as whole to give its readership an initial overview of and outlook into a wide variety of topics and fields in a fairly condensed format. Correspondingly, the Roadmap pursues the goal of giving each reader a brief reference frame of relevant and current topics in modern applied magnetism research, even if not all sub-fields can be represented here. The first block of this 2020 Magnetism Roadmap, which is focussed on (i) phenomena, contains five contributions, which address the areas of interfacial Dzyaloshinskii-Moriya interactions, and two-dimensional and curvilinear magnetism, as well as spin-orbit torque phenomena and all optical magnetization reversal. All of these contributions describe cutting edge aspects of rather fundamental physical processes and properties, associated with new and improved magnetic materials' properties, together with potential developments in terms of future devices and technology. As such, they form part of a widening magnetism 'phenomena reservoir' for utilization in applied magnetism and related device technology. The final block (iii) of this article focuses on such applications and device-related fields in four contributions relating to currently active areas of research, which are of course utilizing magnetic phenomena to enable specific functions. These contributions highlight the role of magnetism or spintronics in the field of neuromorphic and reservoir computing, terahertz technology, and domain wall-based logic. One aspect common to all of these application-related contributions is that they are not yet being utilized in commercially available technology; it is currently still an open question, whether or not such technological applications will be magnetism-based at all in the future, or if other types of materials and phenomena will yet outperform magnetism. This last point is actually a very good indication of the vibrancy of applied magnetism research today, given that it demonstrates that magnetism research is able to venture into novel application fields, based upon its portfolio of phenomena, effects and materials. This materials portfolio in particular defines the central block (ii) of this article, with its five contributions interconnecting phenomena with devices, for which materials and the characterization of their properties is the decisive discriminator between purely academically interesting aspects and the true viability of real-life devices, because only available materials and their associated fabrication and characterization methods permit reliable technological implementation. These five contributions specifically address magnetic films and multiferroic heterostructures for the purpose of spin electronic utilization, multi-scale materials modelling, and magnetic materials design based upon machine-learning, as well as materials characterization via polarized neutron measurements. As such, these contributions illustrate the balanced relevance of research into experimental and modelling magnetic materials, as well the importance of sophisticated characterization methods that allow for an ever-more refined understanding of materials. As a combined and integrated article, this 2020 Magnetism Roadmap is intended to be a reference point for current, novel and emerging research directions in modern magnetism, just as its 2014 and 2017 predecessors have been in previous years.
The OPTIMAL study was the first study to compare efficacy and tolerability of the epidermal growth factor receptor (EGFR)-tyrosine kinase inhibitor (TKI) erlotinib, versus standard chemotherapy in ...first-line treatment of patients with EGFR mutation-positive advanced non-small-cell lung cancer (NSCLC). Findings from final overall survival (OS) analysis and assessment of post-study treatment impact are presented.
Of 165 randomised patients, 82 received erlotinib and 72 gemcitabine plus carboplatin. Final OS analyses were conducted when 70% of deaths had occurred in the intent-to-treat population. Subgroup OS was analysed by Cox proportional hazards model and included randomisation stratification factors and post-study treatments.
Median OS was similar between the erlotinib (22.8 months) and chemotherapy (27.2 months) arms with no significant between-group differences in the overall population hazard ratio (HR), 1.19; 95% confidence interval (CI) 0.83–1.71; P = 0.2663, the exon 19 deletion subpopulation (HR, 1.52; 95% CI 0.91–2.52; P = 0.1037) or the exon 21 L858 mutation subpopulation (HR, 0.92; 95% CI 0.55–1.54; P = 0.7392). More patients in the erlotinib arm versus the chemotherapy arm did not receive any post-study treatment (36.6% versus 22.2%). Patients who received sequential combination of EGFR-TKI and chemotherapy had significantly improved OS compared with those who received EGFR-TKI or chemotherapy only (29.7 versus 20.7 or 11.2 months, respectively; P < 0.0001). OS was significantly shorter in patients who did not receive post-study treatments compared with those who received subsequent treatments in both arms.
The significant OS benefit observed in patients treated with EGFR-TKI emphasises its contribution to improving survival of EGFR mutant NSCLC patients, suggesting that erlotinib should be considered standard first-line treatment of EGFR mutant patients and EGFR-TKI treatment following first-line therapy also brings significant benefits to those patients.
NCT00874419.
Raindrop size distribution (DSD) characteristics within the complex area of Busan, Republic of Korea (35.12° N, 129.10° E), were studied using a Precipitation Occurrence Sensor System (POSS) ...disdrometer over a 4-year period from 24 February 2001 to 24 December 2004. Also, to find the dominant characteristics of polarized radar parameters, which are differential radar reflectivity (Zdr), specific differential phase (Kdp) and specific attenuation (Ah), T-matrix scattering simulation was applied in the present study. To analyze the climatological DSD characteristics in more detail, the entire period of recorded rainfall was divided into 10 categories not only covering different temporal and spatial scales, but also different rainfall types. When only convective rainfall was considered, mean values of mass-weighted mean diameter (Dm) and normalized number concentration (Nw) values for all these categories converged around a maritime cluster, except for rainfall associated with typhoons. The convective rainfall of a typhoon showed much smaller Dm and larger Nw compared with the other rainfall categories. In terms of diurnal DSD variability, we analyzed maritime (continental) precipitation during the daytime (DT) (nighttime, NT), which likely results from sea (land) wind identified through wind direction analysis. These features also appeared in the seasonal diurnal distribution. The DT and NT probability density function (PDF) during the summer was similar to the PDF of the entire study period. However, the DT and NT PDF during the winter season displayed an inverse distribution due to seasonal differences in wind direction.
The Tibetan Plateau (TP) is representative of typical clean atmospheric conditions. Aerosol optical depth (AOD) retrieved by the Multi-angle Imaging SpectroRadiometer (MISR) is higher over Qaidam ...Basin than the rest of the TP throughout the year. Different monthly variation patterns of AOD are observed over the southern and northern TP, whereby the aerosol load is usually higher in the northern TP than in the southern part. The aerosol load over the northern part increases from April to June, peaking in May. The maximum concentration of aerosols over the southern TP occurs in July. Aerosols appear to be more easily transported to the main body of the TP across the northern edge rather than the southern edge. This is maybe partly because the altitude is lower at the northern edge than that of the Himalayas located along the southern edge of the TP. Three-dimensional distributions of dust, polluted dust, polluted continental aerosol and smoke are also investigated, based on Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) data. Dust is found to be the most prominent aerosol type on the TP, and other types of aerosols affect the atmospheric environment slightly. A dividing line of higher dust occurrence in the northern TP and lower dust occurrence in the southern TP can be observed clearly at an altitude of 6–8 km above sea level, especially in spring and summer. This demarcation appears around 33–35° N in the middle of the plateau, and it is possibly associated with the high-altitude terrain in the same geographic location. Comparisons of CALIPSO and MISR data show that the vertical dust occurrences are consistent with the spatial patterns of AOD. The different seasonal variation patterns between the northern and southern TP are primarily driven by atmospheric circulation, and are also related to the emission characteristics over the surrounding regions.
Coal combustion will continue to be a major component of energy production in the foreseeable future, owing to its abundance in China. A primary challenge will be to seek ways to utilize the coal ...resources in an environmentally acceptable manner. This paper presents the coal combustion scenario and its related air pollution in China. Some commonly used technologies for removing the pollutants from coal combustion had been introduced after comparison of its utilization efficiency, engineering investment-, and operation expense. In order to cost-effectively reduce the pollutant emission, it is necessary to enhance the coal utilization efficiency by implementing large-scale advanced technologies and increasing the coal-washing rate. There is dire need for indigenously developed techniques for the pollution control to reduce the engineering cost. The development of low-cost, low water-consuming flue gas desulfurization technologies, low-cost technologies for reducing NO
x emission, and low-cost advanced technologies for inhalable particle emission control, must be predominantly paid attention.
We numerically investigate the interaction between propagating spin waves and a transverse domain wall in a nanowire by using micromagnetic simulations. In order to understand the mechanisms that ...lead to domain wall motions, we calculate domain wall velocity in a defect-free nanowire and the depinning fields for a pinned domain wall that is depinned in and against the direction of the spin-wave propagation. We find that the physical origin of the spin-wave-induced domain wall motion strongly depends on the propagating spin-wave frequency. At certain spin-wave frequencies, transverse domain wall vibrations lead to transverse wall displacements by the spin waves, while at other frequencies, large spin-wave reflection drives domain wall motion. By analyzing the depinning field calculations, the different underlying physical mechanisms are distinguished.
The Eastern Lau Spreading Center (ELSC) is the southernmost part of the back-arc spreading axis in the Lau Basin, west of the Tonga trench and the active Tofua volcanic arc. Over its 397-km length it ...exhibits large and systematic changes in spreading rate, magmatic/tectonic processes, and proximity to the volcanic arc. In 2005, we collected 81 samples of vent water from six hydrothermal fields along the ELSC. The chemistry of these waters varies both within and between vent fields, in response to changes in substrate composition, temperature and pressure, pH, water/rock ratio, and input from magmatic gases and subducted sediment. Hot-spring temperatures range from 229° to 363
°C at the five northernmost fields, with a general decrease to the south that is reversed at the Mariner field. The southernmost field, Vai Lili, emitted water at up to 334
°C in 1989 but had a maximum venting temperature of only 121
°C in 2005, due to waning activity and admixture of bottom seawater into the subseafloor plumbing system. Chloride varies both within fields and from one field to another, from a low of 528
mmol/kg to a high of 656
mmol/kg, and may be enriched by phase separation and/or leaching of Cl from the rock. Concentrations of the soluble elements K, Rb, Cs, and B likewise increase southward as the volcanic substrate becomes more silica-rich, especially on the Valu Fa Ridge. Iodine and δ
7Li increase southward, and δ
11B decreases as B increases, apparently in response to increased input from subducted sediment as the arc is approached. Species that decrease southward as temperature falls are Si, H
2S, Li, Na/Cl, Fe, Mn, and
87Sr/
86Sr, whereas pH, alkalinity, Ca, and Sr increase. Oxygen isotopes indicate a higher water/rock ratio in the three systems on Valu Fa Ridge, consistent with higher porosity in more felsic volcanic rocks. Vent waters at the Mariner vent field on the Valu Fa Ridge are significantly hotter, more acid and metal-rich, less saline, and richer in dissolved gases and other volatiles, including H
2S, CO
2, and F, than the other vent fields, consistent with input of magmatic gases. The large variations in geologic and geophysical parameters produced by back-arc spreading along the ELSC, which exceed those along mid-ocean ridge spreading axes, produce similar large variations in the composition of vent waters, and thus provide new insights into the processes that control the chemistry of submarine hot springs.
We demonstrate the process of obtaining memristive multi-states Hall resistance (R
) change in a single Hall cross (SHC) structure. Otherwise, the working mechanism successfully mimics the behavior ...of biological neural systems. The motion of domain wall (DW) in the SHC was used to control the ascend (or descend) of the R
amplitude. The primary synaptic functions such as long-term potentiation (LTP), long-term depression (LTD), and spike-time-dependent plasticity (STDP) could then be emulated by regulating R
. Applied programmable magnetic field pulses are in varying conditions such as intensity and duration to adjust R
. These results show that analog readings of DW movement can be closely resembled with the change of synaptic weight and have great potentials for bioinspired neuromorphic computing.
Abstract
The study uses rigid-plastic finite element (FE) DEFORM TM 3D software to investigate the plastic deformation behaviour of spiral flat bottom engraving. The finite element analysis assumes ...that the spiral flat bottom is a rigid body. During the engraving process, the deformation causes an increase in temperature and wear inside the blank. The FE analyses investigate the effects of cutting speed, depth of cut, and the feed of the workpiece on the damage, effective strain, stress, temperature, and wear induced within the workpiece. The simulation results confirm the suitability of the DEFORM TM 3D software for modelling the spiral flat bottom engraving. Comparisons of engraving of spiral flat bottom with clockwise and counter-clockwise have been performed. The analysis of following stress-strain simulation has been predicted by machine learning in this study. Eventually, the experiment of spiral flat bottom engraving is used.
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