Household air pollution generated from cooking is severe, especially for Chinese-style cooking. We measured the emission rates of multiple air pollutants including fine particles (PM2.5), ultrafine ...particles (UFPs), and volatile organic compounds (VOCs, including formaldehyde, benzene, and toluene) that were generated from typical Chinese cooking in a residential kitchen. The experiment was designed through five-factor and five-level orthogonal testing. The five key factors were cooking method, ingredient weight, type of meat, type of oil, and meat/vegetable ratio. The measured emission rates (mean value ± standard deviation) of PM2.5, UFPs, formaldehyde, total volatile organic compounds (TVOCs), benzene, and toluene were 2.056 ± 3.034 mg/min, 9.102 ± 6.909 × 1012 #/min, 1.273 ± 0.736 mg/min, 1.349 ± 1.376 mg/min, 0.074 ± 0.039 mg/min, and 0.004 ± 0.004 mg/min. Cooking method was the most influencing factor for the emission rates of PM2.5, UFPs, formaldehyde, TVOCs, and benzene but not for toluene. Meanwhile, the emission rate of PM2.5 was also significantly influenced by ingredient weight, type of meat, and meat/vegetable ratio. Exhausting the range hood decreased the emission rates by approximately 58%, with a corresponding air change rate of 21.38/h for the kitchen room.
Epidemiologic evidence indicates a relationship between outdoor particle exposure and adverse health effects, while most people spend 85–90% of their time indoors, thus understanding the relationship ...between indoor and outdoor particles is quite important. This paper aims to provide an up-to-date revision for both experiment and modeling on relationship between indoor and outdoor particles. The use of three different parameters: indoor/outdoor (I/O) ratio, infiltration factor and penetration factor, to assess the relationship between indoor and outdoor particles were reviewed. The experimental data of the three parameters measured both in real houses and laboratories were summarized and analyzed. The I/O ratios vary considerably due to the difference in size-dependent indoor particle emission rates, the geometry of the cracks in building envelopes, and the air exchange rates. Thus, it is difficult to draw uniform conclusions as detailed information, which make I/O ratio hardly helpful for understanding the indoor/outdoor relationship. Infiltration factor represents the equilibrium fraction of ambient particles that penetrates indoors and remains suspended, which avoids the mixture with indoor particle sources. Penetration factor is the most relevant parameter for the particle penetration mechanism through cracks and leaks in the building envelope. We investigate the methods used in previously published studies to both measure and model the infiltration and penetration factors. We also discuss the application of the penetration factor models and provide recommendations for improvement.
•A detailed introduction and analysis of radiative cooling was reviewed.•The mathematical description of radiative cooling was reviewed and discussed.•The emitters’ materials and radiative properties ...were compiled and analyzed.•The potential applications of radiative cooling were excavated.•Several recommendations on radiative cooling were presented.
As a passive, effective, and renewable way of decreasing cooling energy requirements without power input, radiative cooling has attracted considerable attention in the field of energy-saving applications. Historically, radiative cooling was limited at nighttime because radiators with strong thermal radiation lack high reflectivity in the solar radiation band. With the recent technological advancements in radiators, such as the development of photonic radiators and metamaterials, the advantages of diurnal radiative cooling has been demonstrated. In this paper, the current state of the art in passive radiative cooling technology is reviewed and updated. First, the fundamental principles of radiative cooling, which comprise different mathematical and physical descriptions, are introduced. Then, the advanced materials and structures of various radiators, which are popular topics in radiative cooling, are presented. Furthermore, application developments in radiative cooling are also summarized and its prospects are preliminarily analyzed. This study provides a detailed introduction and analysis of radiative cooling technology, thereby serving as a key reference for promoting the development of radiative cooling utilization.
Highly crystallized ZnO–Ga2O3 core–shell heterostructure microwire is synthesized by a simple one‐step chemical vapor deposition method, and constructed into a self‐powered solar‐blind (200–280 nm) ...photodetector with a sharp cutoff wavelength at 266 nm. The device shows an ultrahigh responsivity (9.7 mA W−1) at 251 nm with a high UV/visible rejection ratio (R251 nm/R400 nm) of 6.9 × 102 under zero bias. The self‐powered device has a fast response speed with rise time shorter than 100 µs and decay time of 900 µs, respectively. The ultrahigh responsivity, high UV/visible rejection ratio, and fast response speed make it highly suitable in practical self‐powered solar‐blind detection. Additinoally, this microstructure heterojunction design method would provide a new approach to realize the high‐performance self‐powered photodetectors.
Highly crystallized ZnO–Ga2O3 heterostructure microwire is synthesized using a simple one‐step chemical vapor deposition method and the growth mechanism is discussed. A self‐powered solar‐blind photodetector based on individual ZnO–Ga2O3 heterostructures is demonstrated, and has responsivity as high as 9.7 mA W−1 at the wavelength of 251 nm without any external power source.
Dendrite growth of alkali metal anodes limited their lifetime for charge/discharge cycling. Here, we report near-perfect anodes of lithium, sodium, and potassium metals achieved by electrochemical ...polishing, which removes microscopic defects and creates ultra-smooth ultra-thin solid-electrolyte interphase layers at metal surfaces for providing a homogeneous environment. Precise characterizations by AFM force probing with corroborative in-depth XPS profile analysis reveal that the ultra-smooth ultra-thin solid-electrolyte interphase can be designed to have alternating inorganic-rich and organic-rich/mixed multi-layered structure, which offers mechanical property of coupled rigidity and elasticity. The polished metal anodes exhibit significantly enhanced cycling stability, specifically the lithium anodes can cycle for over 200 times at a real current density of 2 mA cm
with 100% depth of discharge. Our work illustrates that an ultra-smooth ultra-thin solid-electrolyte interphase may be robust enough to suppress dendrite growth and thus serve as an initial layer for further improved protection of alkali metal anodes.
Most photoredox catalysts in current use are precious metal complexes or synthetically elaborate organic dyes, the cost of which can impede their application for large-scale industrial processes. We ...found that a combination of triphenylphosphine and sodium iodide under 456-nanometer irradiation by blue light-emitting diodes can catalyze the alkylation of silyl enol ethers by decarboxylative coupling with redox-active esters in the absence of transition metals. Deaminative alkylation using Katritzky's N-alkylpyridinium salts and trifluoromethylation using Togni's reagent are also demonstrated. Moreover, the phosphine/iodide-based photoredox system catalyzes Minisci-type alkylation of N-heterocycles and can operate in tandem with chiral phosphoric acids to achieve high enantioselectivity in this reaction.
High-performance solar-blind (200–280 nm) avalanche photodetectors (APDs) were fabricated based on highly crystallized ZnO–Ga2O3 core–shell microwires. The responsivity can reach up to 1.3 × 103 A/W ...under −6 V bias. Moreover, the corresponding detectivity was as high as 9.91 × 1014 cm·Hz1/2/W. The device also showed a fast response, with a rise time shorter than 20 μs and a decay time of 42 μs. The quality of the detectors in solar-blind waveband is comparable to or even higher than that of commercial Si APD (APD120A2 from Thorlabs Inc.), with a responsivity ∼8 A/W, detectivity ∼1012 cm·Hz1/2/W, and response time ∼20 ns. The high performance of this APD make it highly suitable for practical applications as solar-blind photodetectors, and this core–shell microstructure heterojunction design method would provide a new approach for realizing an APD device.
Cooking is an important source of air pollutants in Chinese residences. Cooking emissions are influenced by many factors, among which oil temperature is one of the most influential. In this study, 15 ...typical Chinese dishes, prepared using oil-based cooking methods (stir-, pan- and deep-frying), were chosen. The experiment was repeated three times with each dish—freshly prepared for each subsequent analysis—considering five key factors, to determine the emission rates of fine particulate matter (PM2.5), ultrafine particles (UFPs), formaldehyde, and total volatile organic compounds (TVOC). The oil temperature and oil consumption were measured. A partial correlation analysis was performed to identify the influence of oil temperature on air pollutant emission rates during Chinese residential cooking. The zero-order correlation coefficients for all air pollutants, excluding UFPs, and partial correlation coefficients for all air pollutants, were not significant, implying that the influence of oil temperature on air pollutant emission rates was not significant, because practical peak oil temperatures (112–177 °C) were mostly below the oil smoke point (107–234 °C).
•Cooking 15 typical Chinese dishes were repeated 3 times.•Emission rates of PM2.5, UFPs, VOCs and oil temperatures were measured.•Correlation between oil temperature and emission rate was analyzed.•The influence of oil temperature on emission rates was not so significant.
Some organic dyes and photosensitizers with strong visible absorption can behave as photo-responsive oxidase mimics. However, the relationship between the photo-oxidase activity and molecular ...structure remains unclear to date. In this work, a new type of photosensitizer with the characteristics of molecular rotors, namely DPPy, served as the molecular scaffold for further investigation. To adjust the photocatalytic oxidation ability, DAPy and CBPy were designed and synthesized based on the enhancement and diminishment of the intramolecular charge transfer (ICT) process, respectively. Kinetic studies revealed that DAPy and CBPy both exhibited highly efficient photo-activated oxidase-like activity with 3,3',5,5'-tetramethylbenzidine (TMB) as the substrate, which were in good accordance with their molecular engineering to promote either type I or type II reactive oxygen species (ROS) generation. Impressively a colorimetric method based on the visible light induced oxidase-like activity of molecular rotors was developed to determine the environmental temperature for the first time. Both DAPy and CBPy showed distinct sensitivities toward temperature as compared with several molecular rotors based on the typical fluorimetric detection. This work provides a new strategy for the application of molecular rotors to overcome the non-emissive challenge in temperature sensing.
The rampant encroachment of Spartina alterniflora into coastal wetlands of China over the past decades has adversely affected both coastal ecosystems and socio-economic systems. However, there are no ...annual or multi-year epoch maps of Spartina saltmarsh in China, which hinders our understanding and management of Spartina invasion. In this study, we selected Chongming island, China, where Spartina saltmarsh had expanded rapidly since its introduction in the 1990s. We investigated phenology of Spartina, Phragmites and Scirpus saltmarshes, and the time series vegetation indices derived from Landsat images showed that Spartina saltmarsh did not green-up in April–May and stayed green in December–January, which differed from the phenology of Phragmites and Scirpus saltmarshes. We developed a pixel- and phenology-based algorithm that used time series Landsat data to identify and map Spartina saltmarsh, and we applied it to quantify the temporal dynamics (expansion and removal) of Spartina saltmarsh on Chongming island during 1995–2018. The resultant maps showed that Spartina saltmarsh area on Chongming island increased from ~4 ha in 1995 to ~2067 ha in 2012 but dropped substantially to ~729 ha in 2016 after a large-scale ecological engineering project (US$ 186 million) was started to remove Spartina during 2013–2016. Chongming island still had ~1315 ha Spartina saltmarsh in 2018, and majority of it was distributed outside the Chongming Dongtan National Nature Reserve, which could serve as the sources for reinvasion in the near future. This study demonstrates the feasibility of using time series Landsat images, pixel- and phenology-based algorithm, and GEE platform to identify and map Spartina saltmarsh over years in the region, which is useful to the management of invasive plants in coastal wetlands.
•Time series Landsat images tracked phenology of Spartina saltmarsh in a year.•A pixel- and phenology-based algorithm was developed to map Spartina saltmarsh.•Expansion and removal of Spartina saltmarsh during 1995–2018 were documented.
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