Context. One of the important questions of astrochemistry is how complex organic molecules, including potential prebiotic species, are formed in the envelopes around embedded protostars. The ...abundances of minor isotopologues of a molecule, in particular the D- and 13C-bearing variants, are sensitive to the densities, temperatures and timescales characteristic of the environment in which they form, and can therefore provide important constraints on the formation routes and conditions of individual species. Aims. The aim of this paper is to systematically survey the deuteration and the 13C content of a variety of oxygen-bearing complex organic molecules on solar system scales toward the “B component” of the protostellar binary IRAS16293–2422. Methods. We have used the data from an unbiased molecular line survey of the protostellar binary IRAS16293−2422 between 329 and 363 GHz from the Atacama Large Millimeter/submillimeter Array (ALMA). The data probe scales of 60 AU (diameter) where most of the organic molecules are expected to have sublimated off dust grains and be present in the gas phase. The deuterated and 13C isotopic species of ketene, acetaldehyde and formic acid, as well as deuterated ethanol, are detected unambiguously for the first time in the interstellar medium. These species are analysed together with the 13C isotopic species of ethanol, dimethyl ether and methyl formate along with mono-deuterated methanol, dimethyl ether and methyl formate. Results. The complex organic molecules can be divided into two groups with one group, the simpler species, showing a D/H ratio of ≈2% and the other, the more complex species, D/H ratios of 4–8%. This division may reflect the formation time of each species in the ices before or during warm-up/infall of material through the protostellar envelope. No significant differences are seen in the deuteration of different functional groups for individual species, possibly a result of the short timescale for infall through the innermost warm regions where exchange reactions between different species may be taking place. The species show differences in excitation temperatures between 125 and 300 K. This likely reflects the binding energies of the individual species, in good agreement with what has previously been found for high-mass sources. For dimethyl ether, the 12C/13C ratio is found to be lower by up to a factor of 2 compared to typical ISM values similar to what has previously been inferred for glycolaldehyde. Tentative identifications suggest that the same may apply for 13C isotopologues of methyl formate and ethanol. If confirmed, this may be a clue to their formation at the late prestellar or early protostellar phases with an enhancement of the available 13C relative to 12C related to small differences in binding energies for CO isotopologues or the impact of FUV irradiation by the central protostar. Conclusions. The results point to the importance of ice surface chemistry for the formation of these complex organic molecules at different stages in the evolution of embedded protostars and demonstrate the use of accurate isotope measurements for understanding the history of individual species.
Context.
The chemical composition of protoplanetary disks is expected to impact the composition of the forming planets. Characterizing the diversity of chemical composition in disks and the ...physicochemical factors that lead to this diversity is consequently of high interest.
Aims.
The aim of this study is to investigate the chemical evolution from the prestellar phase to the formation of the disk, and to determine the impact that the chemical composition of the cold and dense core has on the final composition of the disk.
Methods.
We performed 3D nonideal magneto-hydrodynamic (MHD) simulations of a dense core collapse using the adaptive-mesh-refinement RAMSES code. For each particle ending in the young rotationally supported disk, we ran chemical simulations with the three-phase gas-grain chemistry code Nautilus. Two different sets of initial abundances, which are characteristic of cold cores, were considered. The final distributions of the abundances of common species were compared to each other, as well as with the initial abundances of the cold core.
Results.
We find that the spatial distributions of molecules reflect their sensitivity to the temperature distribution. The main carriers of the chemical elements in the disk are usually the same as the ones in the cold core, except for the S-bearing species, where HS is replaced by H
2
S
3
, and the P-bearing species, where atomic P leads to the formation of PO, PN, HCP, and CP. However, the abundances of less abundant species change over time. This is especially the case for “large” complex organic molecules (COMs) such as CH
3
CHO, CH
3
NH
2
, CH
3
OCH
3
, and HCOOCH
3
which see their abundances significantly increase during the collapse. These COMs often present similar abundances in the disk despite significantly different abundances in the cold core. In contrast, the abundances of many radicals decrease with time. A significant number of species still show the same abundances in the cold core and the disk, which indicates efficient formation of these molecules in the cold core. This includes H
2
O, H
2
CO, HNCO, and “small” COMs such as CH
3
OH, CH
3
CN, and NH
2
CHO. We computed the MHD resistivities within the disk for the full gas–grain chemical evolution and find results in qualitative agreement with the literature assuming simpler chemical networks.
Conclusions.
In conclusion, the chemical content of prestellar cores is expected to affect the chemical composition of disks. The impact is more or less important depending on the type of species. Users of stand-alone chemical models of disks should pay special attention to the initial abundances they choose.
Context.
Complex organic molecules are detected in many sources in the warm inner regions of envelopes surrounding deeply embedded protostars. Exactly how these species form remains an open question.
...Aims.
This study aims to constrain the formation of complex organic molecules through comparisons of their abundances towards the Class 0 protostellar binary IRAS 16293–2422.
Methods.
We utilised observations from the ALMA Protostellar Interferometric Line Survey of IRAS 16293–2422. The species identification and the rotational temperature and column density estimation were derived by fitting the extracted spectra towards IRAS 16293–2422 A and IRAS 16293–2422 B with synthetic spectra. The majority of the work in this paper pertains to the analysis of IRAS 16293–2422 A for a comparison with the results from the other binary component, which have already been published.
Results.
We detect 15 different complex species, as well as 16 isotopologues towards the most luminous companion protostar IRAS 16293–2422 A. Tentative detections of an additional 11 isotopologues are reported. We also searched for and report on the first detections of methoxymethanol (CH
3
OCH
2
OH) and trans-ethyl methyl ether (t-C
2
H
5
OCH
3
) towards IRAS 16293–2422 B and the follow-up detection of deuterated isotopologues of acetaldehyde (CH
2
DCHO and CH
3
CDO). Twenty-four lines of doubly-deuterated methanol (CHD
2
OH) are also identified.
Conclusions.
The comparison between the two protostars of the binary system shows significant differences in abundance for some of the species, which are partially correlated to their spatial distribution. The spatial distribution is consistent with the sublimation temperature of the species; those with higher expected sublimation temperatures are located in the most compact region of the hot corino towards IRAS 16293–2422 A. This spatial differentiation is not resolved in IRAS 16293–2422 B and will require observations at a higher angular resolution. In parallel, the list of identified CHD
2
OH lines shows the need of accurate spectroscopic data including their line strength.
Context. Complex organic molecules are readily detected in the inner regions of the gaseous envelopes of forming protostars. Their detection is crucial to understanding the chemical evolution of the ...Universe and exploring the link between the early stages of star formation and the formation of solar system bodies, where complex organic molecules have been found in abundance. In particular, molecules that contain nitrogen are interesting due to the role nitrogen plays in the development of life and the compact scales such molecules have been found to trace around forming protostars. Aims. The goal of this work is to determine the inventory of one family of nitrogen-bearing organic molecules, complex nitriles (molecules with a –C≡N functional group) towards two hot corino sources in the low-mass protostellar binary IRAS 16293–2422. This work explores the abundance differences between the two sources, the isotopic ratios, and the spatial extent derived from molecules containing the nitrile functional group. Methods. Using data from the Protostellar Interferometric Line Survey (PILS) obtained with ALMA, we determine abundances and excitation temperatures for the detected nitriles. We also present a new method for determining the spatial structure of sources with high line density and large velocity gradients – Velocity-corrected INtegrated emission (VINE) maps. Results. We detect methyl cyanide (CH3CN) as well as five of its isotopologues, including CHD2CN, which is the first detection in the interstellar medium (ISM). We also detect ethyl cyanide (C2H5CN), vinyl cyanide (C2H3CN), and cyanoacetylene (HC3N). We find that abundances are similar between IRAS 16293A and IRAS 16293B on small scales except for vinyl cyanide which is only detected towards the latter source. This suggests an important difference between the sources either in their evolutionary stage or warm-up timescales. We also detect a spatially double-peaked emission for the first time in molecular emission in the A source, suggesting that this source is showing structure related to a rotating toroid of material. Conclusions. With high-resolution observations, we have been able to show for the first time a number of important similarities and differences in the nitrile chemistry in these objects. These illustrate the utility of nitriles as potential tracers of the physical conditions in star-forming regions.
Context. How water is delivered to planetary systems is a central question in astrochemistry. The deuterium fractionation of water can serve as a tracer for the chemical and physical evolution of ...water during star formation and can constrain the origin of water in Solar System bodies. Aims. The aim is to determine the HDO/H2O ratio in the inner warm gas toward three low-mass Class 0 protostars selected to be in isolated cores, i.e., not associated with any cloud complexes. Previous sources for which the HDO/H2O ratio have been established were all part of larger star-forming complexes. Determining the HDO/H2O ratio toward three isolated protostars allows comparison of the water chemistry in isolated and clustered regions to determine the influence of local cloud environment. Methods. We present ALMA Band 6 observations of the HDO 31,2–22,1 and 21,1–21,2 transitions at 225.897 GHz and 241.562 GHz along with the first ALMA Band 5 observations of the H 218 $_2^{18}$ 218 O 31,3–22,0 transition at 203.407 GHz. The high angular resolution observations (0′′.3–1′′.3) allow the study of the inner warm envelope gas. Model-independent estimates for the HDO/H2O ratios are obtained and compared with previous determinations of the HDO/H2O ratio in the warm gas toward low-mass protostars. Results. We successfully detect the targeted water transitions toward the three sources with signal-to-noise ratio (S/N) > 5. We determine the HDO/H2O ratio toward L483, B335 and BHR71–IRS1 to be (2.2 ± 0.4) × 10−3, (1.7 ± 0.3) × 10−3, and (1.8 ± 0.4) × 10−3, respectively, assuming Tex = 124 K. The degree of water deuteration of these isolated protostars are a factor of 2–4 higher relative to Class 0 protostars that are members of known nearby clustered star-forming regions. Conclusions. The results indicate that the water deuterium fractionation is influenced by the local cloud environment. This effect can be explained by variations in either collapse timescales or temperatures, which depends on local cloud dynamics and could provide a new method to decipher the history of young stars.
Context. The enhanced degrees of deuterium fractionation observed in envelopes around protostars demonstrate the importance of chemistry at low temperatures, relevant in pre- and protostellar cores. ...Formaldehyde is an important species in the formation of methanol and more complex molecules. Aims. Here, we aim to present the first study of formaldehyde deuteration on small scales around the prototypical low-mass protostar IRAS 16293–2422 using high spatial and spectral resolution Atacama Large Millimeter/submillimeter Array (ALMA) observations. We determine the excitation temperature, abundances and fractionation level of several formaldehyde isotopologues, including its deuterated forms. Methods. Excitation temperature and column densities of formaldehyde in the gas close to one of the components of the binary were constrained through modeling of optically thin lines assuming local thermodynamical equilibrium. The abundance ratios were compared to results from previous single dish observations, astrochemical models and local ISM values. Results. Numerous isotopologues of formaldehyde are detected, among them H2C17O, and D213CO$D_2^{13}CO$D213CO for the first time in the ISM. The large range of upper energy levels covered by the HDCO lines help constrain the excitation temperature to 106 ± 13 K. Using the derived column densities, formaldehyde shows a deuterium fractionation of HDCO/H2CO = 6.5 ± 1%, D2CO/HDCO = 12.8–4.1+3.3%$12.8_{-4.1}^{+3.3}\%$12.8–4.1+3.3%, and D2CO/H2CO = 0.6(4) ± 0.1%. The isotopic ratios derived are 16O/18O = 805–79+43$805_{-79}^{+43}$805–79+43, 18O/17O = 3.2–0.3+0.2$3.2_{-0.3}^{+0.2}$3.2–0.3+0.2, and 12C/13C = 56–11+8$56_{-11}^{+8}$56–11+8. Conclusions. The HDCO/H2CO ratio is lower than that found in previous studies, highlighting the uncertainties involved in interpreting single dish observations of the inner warm regions. The D2CO/HDCO ratio is only slightly larger than the HDCO/H2CO ratio. This is consistent with formaldehyde forming in the ice as soon as CO has frozen onto the grains, with most of the deuteration happening toward the end of the prestellar core phase. A comparison with available time-dependent chemical models indicates that the source is in the early Class 0 stage.
Abstract
Methyl isocyanate (CH3NCO) belongs to a select group of interstellar molecules considered to be relevant precursors in the formation of larger organic compounds, including those with peptide ...bonds. The molecule has only been detected in a couple of high-mass protostars and potentially on comets. A formation route on icy grains has been postulated for this molecule but experimental evidence is lacking. Here we extend the range of environments where methyl isocyanate is found and unambiguously identify CH3NCO through the detection of 43 unblended transitions in the ALMA Protostellar Interferometric Line Survey (PILS) of the low-mass solar-type protostellar binary IRAS 16293−2422. The molecule is detected towards both components of the binary with a ratio HNCO/CH3NCO ∼ 4–12. The isomers CH3CNO and CH3OCN are not identified, resulting in upper abundance ratios of CH3NCO/CH3CNO > 100 and CH3NCO/CH3OCN > 10. The resulting abundance ratios compare well with those found for related N-containing species towards high-mass protostars. To constrain its formation, a set of cryogenic UHV experiments is performed. VUV irradiation of CH4:HNCO mixtures at 20 K strongly indicate that methyl isocyanate can be formed in the solid state through CH3 and (H)NCO recombinations. Combined with gas-grain models that include this reaction, the solid-state route is found to be a plausible scenario to explain the methyl isocyanate abundances found in IRAS 16293−2422.
Context.
Establishing the origin of the water D/H ratio in the Solar System is central to our understanding of the chemical trail of water during the star and planet formation process. Recent ...modeling suggests that comparisons of the D
2
O/HDO and HDO/H
2
O ratios are a powerful way to trace the chemical evolution of water and, in particular, determine whether the D/H ratio is inherited from the molecular cloud or established locally.
Aims.
We seek to determine the D
2
O column density and derive the D
2
O/HDO ratios in the warm region toward the low-mass Class 0 sources B335 and L483. The results are compared with astrochemical models and previous observations to determine their implications for the chemical evolution of water.
Methods.
We present ALMA observations of the D
2
O 1
1,0
–1
0,1
transition at 316.8 GHz toward B335 and L483 at ≲0.′′5 (≲100 au) resolution, probing the inner warm envelope gas. The column densities of D
2
O, HDO, and H
2
18
O are determined by synthetic spectrum modeling and direct Gaussian fitting, under the assumption of a single excitation temperature and similar spatial extent for the three water isotopologs.
Results.
D
2
O is detected toward both sources in the inner warm envelope. The derived D
2
O/HDO ratio is (1.0 ± 0.2) × 10
−2
for L483 and (1.4 ± 0.1) × 10
−2
for B335. These values indicate that the D
2
O/HDO ratio is higher than the HDO/H
2
O ratios by a factor of ≳2 toward both sources.
Conclusions.
The high D
2
O/HDO ratios are a strong indication of chemical inheritance of water from the prestellar phase down to the inner warm envelope. This implies that the local cloud conditions in the prestellar phase, such as temperatures and timescales, determine the water chemistry at later stages and could provide a source of chemical differentiation in young systems. In addition, the observed D
2
O/H
2
O ratios support an observed dichotomy in the deuterium fractionation of water toward isolated and clustered protostars, namely, a higher D/H ratio toward isolated sources.
Context. The Class 0 protostellar binary IRAS 16293–2422 is an interesting target for (sub)millimeter observations due to, both, the rich chemistry toward the two main components of the binary and ...its complex morphology. Its proximity to Earth allows the study of its physical and chemical structure on solar system scales using high angular resolution observations. Such data reveal a complex morphology that cannot be accounted for in traditional, spherical 1D models of the envelope. Aims. The purpose of this paper is to study the environment of the two components of the binary through 3D radiative transfer modeling and to compare with data from the Atacama Large Millimeter/submillimeter Array. Such comparisons can be used to constrain the protoplanetary disk structures, the luminosities of the two components of the binary and the chemistry of simple species. Methods. We present 13CO, C17O and C18O J = 3–2 observations from the ALMA Protostellar Interferometric Line Survey (PILS), together with a qualitative study of the dust and gas density distribution of IRAS 16293–2422. A 3D dust and gas model including disks and a dust filament between the two protostars is constructed which qualitatively reproduces the dust continuum and gas line emission. Results. Radiative transfer modeling in our sampled parameter space suggests that, while the disk around source A could not be constrained, the disk around source B has to be vertically extended. This puffed-up structure can be obtained with both a protoplanetary disk model with an unexpectedly high scale-height and with the density solution from an infalling, rotating collapse. Combined constraints on our 3D model, from observed dust continuum and CO isotopologue emission between the sources, corroborate that source A should be at least six times more luminous than source B. We also demonstrate that the volume of high-temperature regions where complex organic molecules arise is sensitive to whether or not the total luminosity is in a single radiation source or distributed into two sources, affecting the interpretation of earlier chemical modeling efforts of the IRAS 16293–2422 hot corino which used a single-source approximation. Conclusions. Radiative transfer modeling of source A and B, with the density solution of an infalling, rotating collapse or a protoplanetary disk model, can match the constraints for the disk-like emission around source A and B from the observed dust continuum and CO isotopologue gas emission. If a protoplanetary disk model is used around source B, it has to have an unusually high scale-height in order to reach the dust continuum peak emission value, while fulfilling the other observational constraints. Our 3D model requires source A to be much more luminous than source B; LA ~ 18 L⊙ and LB ~ 3 L⊙.
Formamide (NH2CHO) has previously been detected in several star-forming regions and is thought to be a precursor for different prebiotic molecules. Its formation mechanism is still debated, however. ...Observations of formamide, related species, and their isopotologues may provide useful clues to the chemical pathways leading to their formation. The Protostellar Interferometric Line Survey (PILS) represents an unbiased, high angular resolution and sensitivity spectral survey of the low-mass protostellar binary IRAS 16293–2422 with the Atacama Large Millimeter/submillimeter Array (ALMA). For the first time, we detect the three singly deuterated forms of NH2CHO (NH2CDO, cis- and trans-NHDCHO), as well as DNCO towards the component B of this binary source. The images reveal that the different isotopologues are all present in the same region. Based on observations of the 13C isotopologues of formamide and a standard 12C/13C ratio, the deuterium fractionation is found to be similar for the three different forms with a value of about 2%. The DNCO/HNCO ratio is also comparable to the D/H ratio of formamide (~1%). These results are in agreement with the hypothesis that NH2CHO and HNCO are chemically related through grain-surface formation.
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