Ti, Zn, and Bi were doped into the Sb2S3 extremely thin absorber (ETA) of an all-solid-state, fully inorganic printed solar cell. Bi doping shifted the Sb2S3 absorption edge to longer wavelength and ...Bi-doped Sb2S3 was aggregated on the TiO2 electrodes, which resulted in photocurrent deterioration. In contrast, Ti and Zn doping did not shift the absorption edge, but improved the photocurrent. The best photocurrent density of 16.3 mA cm−2 was achieved with Ti doping (5 at% to Sb), resulting in the best conversion efficiency of 5.7%.
► All-solid-state, fully inorganic printed solar cells were fabricated. ► The structure was <glass/FTO/TiO2/Sb2S3/CuSCN/Au>. ► The Sb2S3 was extremely thin absorber (ETA). ► To improve the efficiency, Ti, Zn, and Bi were doped into the Sb2S3. ► The results is the best record as printed full-inorganic porous-TiO2 solar cells.
This study investigates distribution, pollution indices, and potential risk assessment for human health and ecology of eight heavy metals in twenty-five street dust samples collected from ...metropolitan area—Ho Chi Minh City, Vietnam. Results showed that Zn was of the highest concentration (466.4 ± 236.5 mg/kg), followed by Mn (393.9 ± 93.2 mg/kg), Cu (153.7 ± 64.7 mg/kg), Cr (102.4 ± 50.5 mg/kg), Pb (49.6 ± 21.4 mg/kg), Ni (36.2 ± 15.4 mg/kg), Co (7.9 ± 1.9 mg/kg), and Cd (0.5 ± 0.5 mg/kg). The principal component analysis revealed that three sources of heavy metals measured in street dust include vehicular activities (32.38%), mixed source of vehicular and residential activities (26.72%), and mixture of industrial and natural sources (20.23%). The geo-accumulation index values showed levels of non-pollution to moderately pollution for Mn and Co; moderately pollution for Ni; moderately to strongly pollution for Cd, Cr, and Pb; and strongly pollution for Cu and Zn. The potential ecological risk values of all sampling sites were close to the high-risk category. Zn (28.9%), Cu (25.4%), and Mn (24.4%) dominantly contributed to the ecological risk. For non-carcinogenic risk, the hazard quotient values for both children and adults were within a safety level. For carcinogenic risk, the TCR
Children
was about 3 times higher than TCR
Adults
, but still within a tolerable limit (1 × 10
−6
to 1 × 10
−4
) of cancer risk. Cr was a major contribution to potential risks in humans. Such studies on heavy metal in street dust are crucial but are still limited in Vietnam/or metropolitan area in Southeast Asia. Therefore, this study can fill the information gap about heavy metal contaminated street dust in a metropolitan area of Vietnam.
The present study focused on investigating the contamination and risk assessment for 16 metals in street dust from Ha Noi highway, Ho Chi Minh City. The results indicated that the concentrations of ...metals (mg/kg) were found, in decreasing order, to be Ti (676.3 ± 155.4) > Zn (519.2 ± 318.9) > Mn (426.6 ±113.1) > Cu (144.7 ± 61.5) > Cr (81.4 ± 22.6) > Pb (52.2 ± 22.9) > V (35.5 ± 5.6) > Ni (30.9 ± 9.5) > Co (8.3 ± 1.2) > As (8.3 ± 2.5) > Sn (7.0 ± 3.6) > B (5.7 ± 0.9) > Mo (4.1 ± 1.7) > Sb (0.8 ± 0.3) > Cd (0.6 ± 0.2) > Se (0.4 ± 0.1). The geo-accumulation index (Igeo) showed moderate contamination levels for Pb, Cd, Cu, Sn, Mo, and Zn. The enrichment factor (EF) values revealed moderate levels for Cd, Cu, Mo, and Sn but moderate–severe levels for Zn. The pollution load index of the heavy metals was moderate. The potential ecological risk (207.43) showed a high potential. Notably, 40.7% and 33.5% of the ecological risks were contributed by Zn and Mn, respectively. These findings are expected to provide useful information to decision-makers about environmental quality control strategies.
In this study, biochar derived from spent coffee grounds (SCGB) was used to adsorb norfloxacin (NOR) in water. The biochar properties were interpreted by analysis of the specific surface area, ...morphology, structure, thermal stability, and functional groups. The impacts of pH, NOR, and ion's present on SCGB performance were examined. The NOR adsorption mode of SCGB is best suited to the Langmuir model (R2 = 0.974) with maximum absorption capacity (69.8 mg g−1). By using a Response Surface Method (RSM), optimal adsorption was also found at pH of 6.26, NOR of 24.69 mg L−1, and SCGB of 1.32 g L−1. Compared with biochars derived from agriculture such as corn stalks, willow branches, potato stem, reed stalks, cauliflower roots, wheat straw, the NOR adsorption capacity of SCGB was 2–30 times higher, but less than 3–4 times for biochars made from Salix mongolica, luffa sponge and polydopamine microspheres. These findings reveal that spent coffee grounds biochar could effectively remove NOR from aqueous solutions. Approaching biochar derived from coffee grounds would be a promising eco-friendly solution because it utilizes solid waste, saves costs, and creates adsorbents to deal with emerging pollutants like antibiotics.
Display omitted
•Norfloxacin was removed using biochar derived from spent coffee grounds (SCGB).•pH significantly influenced the Norfloxacin (NOR) adsorption of the SCGB.•Based on Langmuir model, the maximum absorption capacity was 69.8 mg g−1 at pH 6.•The adsorption process was optimized by using the response surface methodology.•Optimal adsorption conditions were achieved at pH of 6.26 and SCGB of 1.32 g L−1.
We present the results of a multiplicity survey of 212 T Tauri stars in the Chamaeleon I and Taurus-Auriga star-forming regions, based on high-resolution spectra from the Magellan Clay 6.5 m ...telescope. From these data, we achieved a typical radial velocity (RV) precision of ~80 m s super(-1) with slower rotators yielding better precision, in general. For 174 of these stars, we obtained multi-epoch data with sufficient time baselines to identify binaries based on RV variations. We identified eight close binaries and four close triples, of which three and two, respectively, are new discoveries. The spectroscopic multiplicity fractions we find for Chamaeleon I (7%) and Taurus-Auriga (6%) are similar to each other, and to the results of field star surveys in the same mass and period regime. However, unlike the results from imaging surveys, the frequency of systems with close companions in our sample is not seen to depend on primary mass. Additionally, we do not find a strong correlation between accretion and close multiplicity. This implies that close companions are not likely the main source of the accretion shut down observed in weak-lined T Tauri stars. Our results also suggest that sufficient RV precision can be achieved for at least a subset of slowly rotating young stars to search for hot Jupiter planets.
Error bounds revisited Cuong, Nguyen Duy; Kruger, Alexander Y.
Optimization,
04/2022, Letnik:
71, Številka:
4
Journal Article
Recenzirano
Odprti dostop
We propose a unifying general framework of quantitative primal and dual sufficient and necessary error bound conditions covering linear and nonlinear, local and global settings. The function is not ...assumed to possess any particular structure apart from the standard assumptions of lower semicontinuity in the case of sufficient conditions and (in some cases) convexity in the case of necessary conditions. We expose the roles of the assumptions involved in the error bound assertions, in particular, on the underlying space: general metric, normed, Banach or Asplund. Employing special collections of slope operators, we introduce a succinct form of sufficient error bound conditions, which allows one to combine in a single statement several different assertions: nonlocal and local primal space conditions in complete metric spaces, and subdifferential conditions in Banach and Asplund spaces.
ABSTRACT In its three years of operation, the Sloan Digital Sky Survey Apache Point Observatory Galactic Evolution Experiment (APOGEE-1) observed >14,000 stars with enough epochs over a sufficient ...temporal baseline for the fitting of Keplerian orbits. We present the custom orbit-fitting pipeline used to create this catalog, which includes novel quality metrics that account for the phase and velocity coverage of a fitted Keplerian orbit. With a typical radial velocity precision of ∼100-200 m s−1, APOGEE can probe systems with small separation companions down to a few Jupiter masses. Here we present initial results from a catalog of 382 of the most compelling stellar and substellar companion candidates detected by APOGEE, which orbit a variety of host stars in diverse Galactic environments. Of these, 376 have no previously known small separation companion. The distribution of companion candidates in this catalog shows evidence for an extremely truncated brown dwarf (BD) desert with a paucity of BD companions only for systems with 0.1-0.2 AU, with no indication of a desert at larger orbital separation. We propose a few potential explanations of this result, some which invoke this catalog's many small separation companion candidates found orbiting evolved stars. Furthermore, 16 BD and planet candidates have been identified around metal-poor (Fe/H < −0.5) stars in this catalog, which may challenge the core accretion model for companions . Finally, we find all types of companions are ubiquitous throughout the Galactic disk with candidate planetary-mass and BD companions to distances of ∼6 and ∼16 kpc, respectively.
Abstract
High-harmonic (HH) frequencies in microcantilevers impose several applications in precision detection thanks to the higher sensitivity of the higher modes in comparison to the fundamental ...modes. In this study, we showed that by tuning the cantilever length by changing the clamped position, the dimensional ratio of the overhang to the main cantilever part is altered and the HHs could be effectively obtained. Multiple HH frequencies have been achieved, from the 4th to 8th order of the second and from the 11th to 26th order of the third-mechanical mode versus the first mode, and these orders are much higher if higher modes are used. The analytical calculation is in agreement with available results of other groups. HH behavior when the cantilever interacts with the sample is also examined and is strongly dependent on the overhang parameters. These results could guide the experimentalist in the tuning and controlling of the HHs in detecting objects.
We present a novel photonic chip design for high bandwidth four-degree optical switches that support high-dimensional switching mechanisms with low insertion loss and low crosstalk in a low power ...consumption level and a short switching time. Such four-degree photonic chips can be used to build an integrated full-grid Photonic-on-Chip Network (PCN). With four distinct input/output directions, the proposed photonic chips are superior compared to the current bidirectional photonic switches, where a conventionally sizable PCN can only be constructed as a linear chain of bidirectional chips. Our four-directional photonic chips are more flexible and scalable for the design of modern optical switches, enabling the construction of multi-dimensional photonic chip networks that are widely applied for intra-chip communication networks and photonic data centers. More noticeably, our photonic networks can be self-controlling with our proposed Multi-Sample Discovery model, a deep reinforcement learning model based on Proximal Policy Optimization. On a PCN, we can optimize many criteria such as transmission loss, power consumption, and routing time, while preserving performance and scaling up the network with dynamic changes. Experiments on simulated data demonstrate the effectiveness and scalability of the proposed architectural design and optimization algorithm. Perceivable insights make the constructed architecture become the self-controlling photonic-on-chip networks.
Abstract
Background
Emergence of cross-resistance to current anti-malarial drugs has led to an urgent need for identification of potential compounds with novel modes of action and anti-malarial ...activity against the resistant strains. One of the most promising therapeutic targets of anti-malarial agents related to food vacuole of malaria parasite is haemozoin, a product formed by the parasite through haemoglobin degradation.
Methods
With this in mind, this study developed two-dimensional-quantitative structure–activity relationships (QSAR) models of a series of 21 haemozoin inhibitors to explore the useful physicochemical parameters of the active compounds for estimation of anti-malarial activities. The 2D-QSAR model with good statistical quality using partial least square method was generated after removing the outliers.
Results
Five two-dimensional descriptors of the training set were selected: atom count (a_ICM); adjacency and distance matrix descriptor (GCUT_SLOGP_2: the third GCUT descriptor using atomic contribution to logP); average total charge sum (h_pavgQ) in pKa prediction (pH = 7); a very low negative partial charge, including aromatic carbons which have a heteroatom-substitution in “ortho” position (PEOE_VSA-0) and molecular descriptor (rsynth: estimating the synthesizability of molecules as the fraction of heavy atoms that can be traced back to starting material fragments resulting from retrosynthetic rules), respectively. The model suggests that the anti-malarial activity of haemozoin inhibitors increases with molecules that have higher average total charge sum in pKa prediction (pH = 7). QSAR model also highlights that the descriptor using atomic contribution to logP or the distance matrix descriptor (GCUT_SLOGP_2), and structural component of the molecules, including topological descriptors does make for better anti-malarial activity.
Conclusions
The model is capable of predicting the anti-malarial activities of anti-haemozoin compounds. In addition, the selected molecular descriptors in this QSAR model are helpful in designing more efficient compounds against the P
. falciparum
3D7A strain.
Celotno besedilo
Dostopno za:
DOBA, IZUM, KILJ, NUK, PILJ, PNG, SAZU, SIK, UILJ, UKNU, UL, UM, UPUK
PDF
