Recognizing that bioenergy with carbon capture and storage (BECCS) may still take years to mature, this study focuses on another photosynthesis-based, negative-carbon technology that is readier to ...implement in China: biomass intermediate pyrolysis poly-generation (BIPP). Here we find that a BIPP system can be profitable without subsidies, while its national deployment could contribute to a 61% reduction of carbon emissions per unit of gross domestic product in 2030 compared to 2005 and result additionally in a reduction in air pollutant emissions. With 73% of national crop residues used between 2020 and 2030, the cumulative greenhouse gas (GHG) reduction could reach up to 8620 Mt CO
-eq by 2050, contributing 13-31% of the global GHG emission reduction goal for BECCS, and nearly 4555 Mt more than that projected for BECCS alone in China. Thus, China's BIPP deployment could have an important influence on achieving both national and global GHG emissions reduction targets.
This paper presents a LCA study about household heat from Short Rotation Coppice wood pellets combustion. The overall process, from field growth to ash disposal, was considered; environmental ...analysis was carried out using a LCA software programme (Simapro 7.0) and adopting the EcoIndicator 99 model for the evaluation of the global burden; analysis with EPS 2000 and EDIP methodologies were also carried out, in order to compare the different approaches. For the pellet production process, mass and energy flows were measured on an existing Italian plant, while other data were obtained from the Literature; a comparison between results obtained using only data from Literature and using data from the existing plant was made, showing for the pelleting phase a value of about 23% lower if measured data are used. The LCA study showed that agricultural operations account for most of the environmental impact if evaluated both with EcoIndicator 99 and EPS 2000; EDIP gave results that were not very reliable for this chain, due to the high weight given to the infra-structures and machinery construction. The comparison between data obtained considering and not considering the infra-structures contribution in the LCA analysis with EcoIndicator 99 showed a modest contribution of infra-structures on the final score (about 2%). The overall impact evaluated with EcoIndicator 99 is considerably less than the one caused by natural gas heating. The Energy Return Ratio was finally calculated; a value of 3.25 was found, good if compared to the one for the methane combustion, equal to 6.
Microalgae cultivation is booming in agriculture, aquaculture, and bioenergy sectors. A wide range of bioactive compounds with attractive properties can be produced with microalgae, including ...pigments, vitamins, proteins, carbohydrates, and lipids. The biofuel yields from microalgae can exceed the yields obtained with energy crops by 10–100 times. Therefore, such cultivation is promising for the regulation of the biosynthesis of microalagae with phytohormones, which can enhance the production of high-valued bioproducts. This review reports the effect of auxins, abscisic acid, cytokinins, gibberellins, and ethylene on microalgal growth and metabolites, as well as the crosstalk of different phytohormones. The use of phytohormones is also promising because it can also reduce the inputs necessary to grow the selected microalgae and maximize the yields.
The solid fraction obtained by mechanical separation of digestate from anaerobic digestion plants is an attractive feedstock for the pyrolysis process. Especially in the case of digestate obtained ...from biogas plants fed with energy crops, this can be considered a lignin rich residue. The aim of this study is to investigate the pyrolytic kinetic characteristics of solid digestate. The Starink model-free method has been used for the kinetic analysis of the pyrolysis process. The average Activation Energy value is about 204.1 kJ/mol, with a standard deviation of 25 kJ/mol, which corresponds to the 12% of the average value. The activation energy decreased along with the conversion degree. The variation range of the activation energy is about 99 kJ/mol, this means that the average value cannot be used to statistically represent the whole reaction. The Master-plots method was used for the determination of the kinetic model, obtaining that n-order was the most probable one. On the other hand, the process cannot be modeled with a single-step reaction. For this reason it has been used an independent parallel reactions scheme to model the complete process.
•Anaerobic digestion is a viable method for the conversion of food waste.•The maximum biogas production observed at the pH equal 7.0.•Methane yield variations range from 216 to 1476 mL CH4/ g VS.•The ...range of phosphorus content was: 0–3.66.%•The range of potassium content was: 0–10.45% and that of nitrogen was 0.05–6.15%.
Considerable amounts of expired food waste are generated every day. They are rich in organic carbon and in other elements, including nitrogen, phosphorus and potassium, which cannot be wasted. The present work tested expired food waste in terms of biogas production efficiency in anaerobic digestion (AD) process. A database was extrapolated from the tests carried out in order to obtain a complete list of physico-chemical and biochemical methane potential (BMP) of 88 expired food waste. Many studies are based on the analysis of a small number of samples, which are don't present a complete picture of all the types of food waste. The organic composition and other factors such as pH, temperature, C/N ratio of the samples varies considerably with the region, the season and the processing characteristics, resulting in methane yield variations, ranging from 216 to 1476 mL CH4/gVS. Therefore, knowledge of the appropriate physical and chemical properties of the feedstock, working conditions and the effects of the inhibition of various components on the anaerobic digestion processes is a key element, necessary to optimize energy production from food waste.
Internal concentration polarization (ICP) is currently a major bottleneck in the forward osmosis process. Proper modelling of the internal concentration polarization is therefore vital for improving ...the process performance and efficiency. This study assessed the feasibility of several machine learning methods for internal concentration polarization prediction, including artificial neural networks, extreme gradient boosting (XGBoost), Categorical boosting (CatBoost), Random forest, and linear regression. Among the many algorithms evaluated, the CatBoost regression outperformed other methods in terms of coefficient of determination (R2) and the mean square error. The CatBoost algorithm's prediction power was then evaluated using non-training (user-provided) data and compared to solution diffusion models. The results indicated that the machine learning algorithms could predict ICP in the process with high accuracy for the provided dataset and excellent generalizability for future testing data. Furthermore, machine learning algorithms may offer insights into the input features that majorly affect ICP modelling in the forward osmosis process.
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•Internal concentration polarization is predicted through machine learning models.•Artificial Neural networks and gradient tree boosting models are compared.•Neural network and Categorial boosting models showed better predictive power.•Categorical boosting outperformed other machine learning models.•Comparison against solution diffusion models is made.
The increasing global demand for biofuels for energy security and to reduce the effects of climate change has created an opportunity to explore new sources of biomass, of which, microalgae is the ...most promising one. The Laboratory of the Biomass Research Centre (CRB, University of Perugia) is equipped with a photobioreactor that is used to cultivate microalgae under batch conditions. Tests were carried out a temperature of 22 °C and a Photosynthetic Photon Flux Density of 140 µE·m−2·s−1. Cultures were characterized in terms of biomass produced and lipid fraction distribution. The novelty of this paper is the measure of the fuel properties of Selenastrum capricornutum, a new strain for biodiesel production. In particular, after the microalgae have been collected and oil has been extracted, this has been transesterified using a methanol/NaOH solution. The resulting biodiesel has been analyzed with a high-resolution gas chromatograph to determine the concentration of the different methylesters.
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Catalytic pyrolysis of digestate to produce aromatic hydrocarbons can be combined with anaerobic fermentation to effectively transform and utilize all biomass components, which can ...achieve the meaningful purpose of transforming waste into high-value products. This study explored whether catalytic pyrolysis of digestate is feasible to prepare aromatic hydrocarbons by analyzing the thermogravimetric characteristics, pyrolysis characteristics, and catalytic pyrolysis characteristics of digestate. For digestate pyrolysis, an increase in temperature was found to elevate the CO, CH4, and monocyclic aromatic hydrocarbon (benzene, toluene, and xylene; BTX) content, whereas it decreased the contents of phenols, acids, aldehydes, and other oxygenates. Furthermore, the catalytic pyrolysis process effectively inhibited the acids, phenols, and furans in the liquid, whereas the yield of BTX increased from 25.45% to 45.99%, and the selectivity of xylene was also increased from 10.32% to 28.72% after adding ZSM-5. ZSM-5 also inhibited the production of nitrogenous compounds.
Bioenergy with Carbon Capture and Storage (BECCS) technologies are fundamental to reach negative CO2 emissions by removing it from the atmosphere and storing it underground. A promising solution to ...implement BECCS is pressurized Chemical Looping Combustion (CLC), which involves coupling a pressurized CLC reactor system to a turboexpander. The typical configuration chosen is to have an air reactor and a fuel reactor based on coupled circulating fluidized beds. The fluidization regime in both reactors is preferred to be fast fluidization to enhance gas particle contact and solids circulation among reactors. To design the two reactors, Aspen Plus software was used, given that the new version has a module for fluidized bed modeling. At first, the oxygen carrier was designed ex novo, but given that it is a composite compound mainly made by nickel oxide freeze-granulated on alumina (Ni40Al-FG), the molecular structure has been inserted in Aspen Plus. Then, based on the power of the gas turbine, the power output per kg of evolving fluid (in this case, depleted air) is calculated using Aspen Plus. Once the nitrogen content in the depleted air is known, the total air at the inlet of the air reactor is calculated. The fuel reactor is modeled by inserting the reduction reactions for nickel-based oxygen carriers. The paper presents a useful methodology for developing pressurized Chemical Looping Combustors to be coupled to gas turbines for power generation. The provided data will be cross-validated with 0D-models and experimental results.
This paper provides a simple methodology for the design of the air reactor of a chemical looping combustor to optimize its characteristics when it is employed connected to a turbo expander to produce ...power. The design process, given a certain objective (e.g., electric power) defines the reactor specifics, namely height and diameter, taking into account the following aspects: solids inventory of the air reactor; gas velocity; air reactor transport disengaging height (TDH); solids concentration profile along the reactor height, dense bed height; freeboard height; pressure drop depending on air reactor injectors design and configuration. The total air reactor height was about 9.5 m, while the diameter was about 1.8 m. The total inventory was about 10,880 kg; while the circulation rate in the air reactor was about 110 kg/s. The operating pressure and temperature were, respectively, 12 bar and 1200 °C. The average velocity of the gases inside the reactor was about 4 m/s. The fluidization regime resulted to be comprised between turbulent and fast fluidization. Further work must be directed into the estimate of the pressure drop of the reactor, which will affect the plant efficiency in a considerable way.
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