Abstract
Two-dimensional (2D) topological insulators (TIs) are promising platforms for low-dissipation spintronic devices based on the quantum-spin-Hall (QSH) effect, but experimental realization of ...such systems with a large band gap suitable for room-temperature applications has proven difficult. Here, we report the successful growth on bilayer graphene of a quasi-freestanding WSe
2
single layer with the 1
T
′ structure that does not exist in the bulk form of WSe
2
. Using angle-resolved photoemission spectroscopy (ARPES) and scanning tunneling microscopy/spectroscopy (STM/STS), we observe a gap of 129 meV in the 1
T
′ layer and an in-gap edge state located near the layer boundary. The system′s 2D TI characters are confirmed by first-principles calculations. The observed gap diminishes with doping by Rb adsorption, ultimately leading to an insulator–semimetal transition. The discovery of this large-gap 2D TI with a tunable band gap opens up opportunities for developing advanced nanoscale systems and quantum devices.
In this review we present new concepts and recent progress in the application of semiconductor quantum dots (QD) as labels in two important areas of biology, bioimaging and biosensing. We analyze the ...biologically relevant properties of QDs focusing on the following topics: QD surface treatment and stability, labeling of cellular structures and receptors with QDs, incorporation of QDs in living cells, cytotoxicity of QDs and influence of the biological environment on the biological and optical properties of QDs. Initially, we consider utilization of QDs as agents in high-resolution bioimaging techniques that can provide information at the molecular levels. The diverse range of modern live-cell QD-based imaging techniques with resolution far beyond the diffraction limit of light is examined. In each technique, we discuss the pros and cons of QD use and deliberate how QDs can be further engineered to facilitate their application in the respective imaging techniques and to produce significant improvements in resolution. Then we review QD-based point-of-care bioassays, bioprobes, and biosensors designed in different formats ranging from analytic biochemistry assays and ELISA, to novel point-of-care smartphone integrated QD-based biotests. Here, a wide range of QD-based fluorescence bioassays with optical transduction, elecrochemiluminescence and photoelectrochemical assays are discussed. Finally, this review provides an analysis of the prospects of application of QDs in selected important areas of biology.
In this review we present new concepts and recent progress in the application of semiconductor quantum dots (QD) as labels in two important areas of biology, bioimaging and biosensing.
Colloidal quantum dots for optoelectronics Litvin, A. P; Martynenko, I. V; Purcell-Milton, F ...
Journal of materials chemistry. A, Materials for energy and sustainability,
2017, Letnik:
5, Številka:
26
Journal Article
Recenzirano
This review is focused on new concepts and recent progress in the development of three major quantum dot (QD) based optoelectronic devices: photovoltaic cells, photodetectors and LEDs. In each ...application, we discuss recent champion devices with a range of architectures and discuss in detail the chronological steps taken to produce significant improvements in efficiency. We consider this relative to developments in colloidal quantum dots and their effects on these devices, covering alloyed, doped and core/shell QDs, quaternary Cu-Zn-In-S QDs, graphene and silicon QDs, and the wide range of highly promising NIR QDs. The diverse range of novel device designs is examined, including all-quantum dot devices, ternary hybrid compounds, plasmonic enhancements, and nano-heterojunction architectures. In addition, we analyse recent advances in charge transport layers, blocking layers, nanostructured photoanode fabrication and the importance of QD surface treatments. Throughout, we emphasise the use of hybrid composite materials including combinations of QDs with metal oxides, plasmonic nanoparticles, graphene and others. Finally, this review provides an analysis of prospects of these important selected quantum dot-based optoelectronic devices.
This review is focused on new concepts and recent progress in the development of three major quantum dot (QD) based optoelectronic devices: photovoltaic cells, photodetectors and LEDs.
Abstract
Two-dimensional materials constitute a promising platform for developing nanoscale devices and systems. Their physical properties can be very different from those of the corresponding ...three-dimensional materials because of extreme quantum confinement and dimensional reduction. Here we report a study of TiTe
2
from the single-layer to the bulk limit. Using angle-resolved photoemission spectroscopy and scanning tunneling microscopy and spectroscopy, we observed the emergence of a (2 × 2) charge density wave order in single-layer TiTe
2
with a transition temperature of 92 ± 3 K. Also observed was a pseudogap of about 28 meV at the Fermi level at 4.2 K. Surprisingly, no charge density wave transitions were observed in two-layer and multi-layer TiTe
2
, despite the quasi-two-dimensional nature of the material in the bulk. The unique charge density wave phenomenon in the single layer raises intriguing questions that challenge the prevailing thinking about the mechanisms of charge density wave formation.
The experiment Neutrino-4 started in 2014 with a detector model and continued with a full-scale detector in 2016–2021. In this article, we describe all the steps of the preparatory work on this ...experiment. We present all results of the Neutrino-4 experiment with increased statistical accuracy provided to date. The experimental setup is constructed to measure the flux and spectrum of the reactor antineutrinos as a function of distance to the center of the active zone of the SM-3 reactor (Dimitrovgrad, Russia) in the range of 6–12 meters. Using all the collected data, we performed a model-independent analysis to determine the oscillation parameters Δm214 and sin22θ14. The method of coherent summation of measurement results allows us to directly demonstrate the oscillation effect. We present the analysis of possible systematic errors and the MC model of the experiment, which considers the possibility of the effect manifestation at the present precision level. As a result of the analysis, we can conclude that at currently available statistical accuracy, we observe the oscillations at the 2.9 σ level with the parameters Δm214 = (7.3 ± 0.13st ± 1.16syst) eV2 = (7.3 ± 1.17) eV2 and sin22θ = 0.36 ± 0.12 stat(2.9σ). Monte Carlo based statistical analysis gave an estimation of the confidence level at 2.7σ. We plan to improve the currently working experimental setup and create a completely new setup in order to increase the accuracy of the experiment by 3 times. We also provide a brief analysis of the general experimental situation in the search for sterile neutrinos.
A single molecular layer of titanium diselenide (TiSe2) is a promising material for advanced electronics beyond graphene-a strong focus of current research. Such molecular layers are at the quantum ...limit of device miniaturization and can show enhanced electronic effects not realizable in thick films. We show that single-layer TiSe2 exhibits a charge density wave (CDW) transition at critical temperature TC=232±5 K, which is higher than the bulk TC=200±5 K. Angle-resolved photoemission spectroscopy measurements reveal a small absolute bandgap at room temperature, which grows wider with decreasing temperature T below TC in conjunction with the emergence of (2 × 2) ordering. The results are rationalized in terms of first-principles calculations, symmetry breaking and phonon entropy effects. The observed Bardeen-Cooper-Schrieffer (BCS) behaviour of the gap implies a mean-field CDW order in the single layer and an anisotropic CDW order in the bulk.
Single layers of transition metal dichalcogenides (TMDCs) are excellent candidates for electronic applications beyond the graphene platform; many of them exhibit novel properties including charge ...density waves (CDWs) and magnetic ordering. CDWs in these single layers are generally a planar projection of the corresponding bulk CDWs because of the quasi-two-dimensional nature of TMDCs; a different CDW symmetry is unexpected. We report herein the successful creation of pristine single-layer VSe2, which shows a (7×3) CDW in contrast to the (4×4) CDW for the layers in bulk VSe2. Angle-resolved photoemission spectroscopy from the single layer shows a sizable (7×3) CDW gap of ~100 meV at the zone boundary, a 220 K CDW transition temperature twice the bulk value, and no ferromagnetic exchange splitting as predicted by theory. This robust CDW with an exotic broken symmetry as the ground state is explained via a first-principles analysis. The results illustrate a unique CDW phenomenon in the two-dimensional limit.
This paper presents the results of the simulation of a sewage sludge combustion plant with a productivity of 6 tons per hour using the ASPEN Plus. It is shown that catalytic combustion technology can ...be used for the efficient utilization of mechanically dehydrated sludge with the moisture of ~75% in autothermal mode (without the use of additional fuel). At the same time, the plant for utilization of 6.0 tons of sludge per hour enables us to obtain 3.07 MW of heat energy. It is shown that the sludge moisture and its calorific value significantly affect the combustion process. Thus, at the moisture of less than 72%, additional water supply is necessary to avoid overheating of the catalyst bed. In the case of an increase in sludge moisture of more than 76%, an additional supply of fuel (for example, brown coal) is required. Also, the article discusses the emissions of harmful substances generated during sewage sludge combustion and methods for their utilization.
Display omitted
•The plant for sewage sludge combustion (6 tons/hour) is simulated using ASPEN Plus.•The technology enables to combust of sludge with moisture of 75% in autothermal mode.•The plant for utilization of sludge allows one to obtain 3.07 MW of heat energy.
About five to four million years ago, in the early Pliocene epoch, Earth had a warm, temperate climate. The gradual cooling that followed led to the establishment of modern temperature patterns, ...possibly in response to a decrease in atmospheric CO2 concentration, of the order of 100 parts per million, towards preindustrial values. Here we synthesize the available geochemical proxy records of sea surface temperature and show that, compared with that of today, the early Pliocene climate had substantially lower meridional and zonal temperature gradients but similar maximum ocean temperatures. Using an Earth system model, we show that none of the mechanisms currently proposed to explain Pliocene warmth can simultaneously reproduce all three crucial features. We suggest that a combination of several dynamical feedbacks underestimated in the models at present, such as those related to ocean mixing and cloud albedo, may have been responsible for these climate conditions.
Celotno besedilo
Dostopno za:
DOBA, IJS, IZUM, KILJ, NUK, PILJ, PNG, SAZU, SIK, UILJ, UKNU, UL, UM, UPUK
Helical Dirac fermions-charge carriers that behave as massless relativistic particles with an intrinsic angular momentum (spin) locked to its translational momentum-are proposed to be the key to ...realizing fundamentally new phenomena in condensed matter physics. Prominent examples include the anomalous quantization of magneto-electric coupling, half-fermion states that are their own antiparticle, and charge fractionalization in a Bose-Einstein condensate, all of which are not possible with conventional Dirac fermions of the graphene variety. Helical Dirac fermions have so far remained elusive owing to the lack of necessary spin-sensitive measurements and because such fermions are forbidden to exist in conventional materials harbouring relativistic electrons, such as graphene or bismuth. It has recently been proposed that helical Dirac fermions may exist at the edges of certain types of topologically ordered insulators-materials with a bulk insulating gap of spin-orbit origin and surface states protected against scattering by time-reversal symmetry-and that their peculiar properties may be accessed provided the insulator is tuned into the so-called topological transport regime. However, helical Dirac fermions have not been observed in existing topological insulators. Here we report the realization and characterization of a tunable topological insulator in a bismuth-based class of material by combining spin-imaging and momentum-resolved spectroscopies, bulk charge compensation, Hall transport measurements and surface quantum control. Our results reveal a spin-momentum locked Dirac cone carrying a non-trivial Berry's phase that is nearly 100 per cent spin-polarized, which exhibits a tunable topological fermion density in the vicinity of the Kramers point and can be driven to the long-sought topological spin transport regime. The observed topological nodal state is shown to be protected even up to 300 K. Our demonstration of room-temperature topological order and non-trivial spin-texture in stoichiometric Bi2Se3.Mx (Mx indicates surface doping or gating control) paves the way for future graphene-like studies of topological insulators, and applications of the observed spin-polarized edge channels in spintronic and computing technologies possibly at room temperature.
Celotno besedilo
Dostopno za:
DOBA, IJS, IZUM, KILJ, NUK, PILJ, PNG, SAZU, SIK, UILJ, UKNU, UL, UM, UPUK
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