The synthesis, characterization and biological assays of two new rhodium carboxylate sugar derivatives and respective cyclosphosphamide adducts are described. The compounds, characterized by (13)C ...and (1)H NMR, infrared and UV-visible spectra, presented high water solubility and hydration grades were confirmed given the concordance between thermal and CHN analyses. The adducts were active in vitro against K-562 cells.
We report the discovery of a highly eccentric, double-lined spectroscopic binary star system (TYC 3010-1494-1), comprising two solar-type stars that we had initially identified as a single star with ...a brown dwarf companion. At the moderate resolving power of the MARVELS spectrograph and the spectrographs used for subsequent radial-velocity (RV) measurements (R ~ <30,000), this particular stellar binary mimics a single-lined binary with an RV signal that would be induced by a brown dwarf companion (Msin(i)~50 M_Jup) to a solar-type primary. At least three properties of this system allow it to masquerade as a single star with a very low-mass companion: its large eccentricity (e~0.8), its relatively long period (P~238 days), and the approximately perpendicular orientation of the semi-major axis with respect to the line of sight (omega~189 degrees). As a result of these properties, for ~95% of the orbit the two sets of stellar spectral lines are completely blended, and the RV measurements based on centroiding on the apparently single-lined spectrum is very well fit by an orbit solution indicative of a brown dwarf companion on a more circular orbit (e~0.3). Only during the ~5% of the orbit near periastron passage does the true, double-lined nature and large RV amplitude of ~15 km/s reveal itself. The discovery of this binary system is an important lesson for RV surveys searching for substellar companions; at a given resolution and observing cadence, a survey will be susceptible to these kinds of astrophysical false positives for a range of orbital parameters. Finally, for surveys like MARVELS that lack the resolution for a useful line bisector analysis, it is imperative to monitor the peak of the cross-correlation function for suspicious changes in width or shape, so that such false positives can be flagged during the candidate vetting process.
We describe the discovery of a likely brown dwarf (BD) companion with a minimum mass of 31.7 +/- 2.0 M_Jup to GSC 03546-01452 from the MARVELS radial velocity survey, which we designate as ...MARVELS-6b. For reasonable priors, our analysis gives a probability of 72% that MARVELS-6b has a mass below the hydrogen-burning limit of 0.072 M_Sun, and thus it is a high-confidence BD companion. It has a moderately long orbital period of 47.8929 +0.0063/-0.0062 days with a low eccentricty of 0.1442 +0.0078/-0.0073, and a semi-amplitude of 1644 +12/-13 m/s. Moderate resolution spectroscopy of the host star has determined the following parameters: T_eff = 5598 +/- 63, log g = 4.44 +/- 0.17, and Fe/H = +0.40 +/- 0.09. Based upon these measurements, GSC 03546-01452 has a probable mass and radius of M_star = 1.11 +/- 0.11 M_Sun and R_star = 1.06 +/- 0.23 R_Sun with an age consistent with less than ~6 Gyr at a distance of 219 +/- 21 pc from the Sun. Although MARVELS-6b is not observed to transit, we cannot definitively rule out a transiting configuration based on our observations. There is a visual companion detected with Lucky Imaging at 7.7 arcsec from the host star, but our analysis shows that it is not bound to this system. The minimum mass of MARVELS-6b exists at the minimum of the mass functions for both stars and planets, making this a rare object even compared to other BDs.
We report the discovery of a candidate brown dwarf or a very low mass stellar companion (MARVELS-5b) to the star HIP 67526 from the Multi-object APO Radial Velocity Exoplanet Large-area Survey ...(MARVELS). The radial velocity curve for this object contains 31 epochs spread over 2.5 years. Our Keplerian fit using a Markov Chain Monte Carlo approach, reveals that the companion has an orbital period of \(90.2695^{+0.0188}_{-0.0187}\) days, an eccentricity of \(0.4375 \pm 0.0040\) and a semi-amplitude of \(2948.14^{+16.65}_{-16.55}\) m s\(^{-1}\). Using additional high-resolution spectroscopy, we find the host star has an effective temperature \(T_{\rm{eff}}=6004 \pm 34\) K, a surface gravity \(\log g\) cgs \(=4.55 \pm 0.17\) and a metallicity Fe/H \(=+0.04 \pm 0.06\). The stellar mass and radius determined through the empirical relationship of Torres et al. (2010), yields 1.10\(\pm\)0.09 \(M_{\sun}\) and 0.92\(\pm\)0.19 \(R_{\sun}\). The minimum mass of MARVELS-5b is \(65.0 \pm 2.9 M_{Jup}\), indicating that it is likely to be either a brown dwarf or a very low mass star, thus occupying a relatively sparsely-populated region of the mass function of companions to solar-type stars. The distance to this system is 101\(\pm\)10 pc from the astrometric measurements of Hipparcos. No stellar tertiary is detected in the high-contrast images taken by either FastCam lucky imaging or Keck adaptive optics imaging, ruling out any star with mass greater than 0.2\(M_{\sun}\) at a separation larger than 40 AU.
We present an eccentric, short-period brown dwarf candidate orbiting the active, slightly evolved subgiant star TYC 2087-00255-1, which has effective temperature T_eff = 5903+/-42 K, surface gravity ...log (g) = 4.07+/-0.16 (cgs), and metallicity Fe/H = -0.23+/-0.07. This candidate was discovered using data from the first two years of the Multi-object APO Radial Velocity Exoplanets Large-area Survey (MARVELS), which is part of the third phase of Sloan Digital Sky Survey. From our 38 radial velocity measurements spread over a two-year time baseline, we derive a Keplerian orbital fit with semi-amplitude K=3.571+/-0.041 km/s, period P=9.0090+/-0.0004 days, and eccentricity e=0.226+/-0.011. Adopting a mass of 1.16+/-0.11 Msun for the subgiant host star, we infer that the companion has a minimum mass of 40.0+/-2.5 M_Jup. Assuming an edge-on orbit, the semimajor axis is 0.090+/-0.003 AU. The host star is photometrically variable at the \sim1% level with a period of \sim13.16+/-0.01 days, indicating that the host star spin and companion orbit are not synchronized. Through adaptive optics imaging we also found a point source 643+/-10 mas away from TYC 2087-00255-1, which would have a mass of 0.13 Msun if it is physically associated with TYC 2087-00255-1 and has the same age. Future proper motion observation should be able to resolve if this tertiary object is physically associated with TYC 2087-00255-1 and make TYC 2087-00255-1 a triple body system. Core Ca II H and K line emission indicate that the host is chromospherically active, at a level that is consistent with the inferred spin period and measured v_{rot}*sin i, but unusual for a subgiant of this T_eff. This activity could be explained by ongoing tidal spin-up of the host star by the companion.
TYC 4110-01037-1 has a low-mass stellar companion, whose small mass ratio and short orbital period are atypical amongst solar-like (Teff ~< 6000 K) binary systems. Our analysis of TYC 4110-01037-1 ...reveals it to be a moderately aged (~<5 Gyr) solar-like star having a mass of 1.07 +/- 0.08 MSun and radius of 0.99 +/- 0.18 RSun. We analyze 32 radial velocity measurements from the SDSS-III MARVELS survey as well as 6 supporting radial velocity measurements from the SARG spectrograph on the 3.6m TNG telescope obtained over a period of ~2 years. The best Keplerian orbital fit parameters were found to have a period of 78.994 +/- 0.012 days, an eccentricity of 0.1095 +/- 0.0023, and a semi-amplitude of 4199 +/- 11 m/s. We determine the minimum companion mass (if sin i = 1) to be 97.7 +/- 5.8 MJup. The system's companion to host star mass ratio, >0.087 +/- 0.003, places it at the lowest end of observed values for short period stellar companions to solar-like (Teff ~< 6000 K) stars. One possible way to create such a system would be if a triple-component stellar multiple broke up into a short period, low q binary during the cluster dispersal phase of its lifetime. A candidate tertiary body has been identified in the system via single-epoch, high contrast imagery. If this object is confirmed to be co-moving, we estimate it would be a dM4 star. We present these results in the context of our larger-scale effort to constrain the statistics of low mass stellar and brown dwarf companions to FGK-type stars via the MARVELS survey.
We report the discovery via radial velocity of a short-period (P = 2.430420 \pm 0.000006 days) companion to the F-type main sequence star TYC 2930-00872-1. A long-term trend in the radial velocities ...indicates the presence of a tertiary stellar companion with \(P > 2000\) days. High-resolution spectroscopy of the host star yields T_eff = 6427 +/- 33 K, log(g) = 4.52 +/- 0.14, and Fe/H=-0.04 +/- 0.05. These parameters, combined with the broad-band spectral energy distribution and parallax, allow us to infer a mass and radius of the host star of M_1=1.21 +/- 0.08 M_\odot and R_1=1.09_{-0.13}^{+0.15} R_\odot. We are able to exclude transits of the inner companion with high confidence. The host star's spectrum exhibits clear Ca H and K core emission indicating stellar activity, but a lack of photometric variability and small v*sin(I) suggest the primary's spin axis is oriented in a pole-on configuration. The rotational period of the primary from an activity-rotation relation matches the orbital period of the inner companion to within 1.5 \sigma, suggesting they are tidally locked. If the inner companion's orbital angular momentum vector is aligned with the stellar spin axis, as expected through tidal evolution, then it has a stellar mass of M_2 ~ 0.3-0.4 M_\odot. Direct imaging limits the existence of stellar companions to projected separations < 30 AU. No set of spectral lines and no significant flux contribution to the spectral energy distribution from either companion are detected, which places individual upper mass limits of M < 1.0 M_\odot, provided they are not stellar remnants. If the tertiary is not a stellar remnant, then it likely has a mass of ~0.5-0.6 M_\odot, and its orbit is likely significantly inclined from that of the secondary, suggesting that the Kozai-Lidov mechanism may have driven the dynamical evolution of this system.
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