In this study, cobalt (Co) was recycled from spent lithium ion batteries (LIBs) and used to synthesize cobalt ferrite (CoFe2O4-LIBs), which was applied as a catalyst for heterogeneous photo Fenton ...reactions that discolored methylene blue (MB) dye. The co-precipitation method was used to synthesize CoFe2O4-LIBs and CoFe2O4-R nanoparticles with spinel structures using as raw materials of the LIB cathodes and commercial reagents. X-ray diffraction (XRD) identified the formation of spinel-type CoFe2O4, which formed clusters that could be seen under scanning electron microscopy (SEM) analysis and nanometric particles seen under transmission electron microscopy (TEM). Inductively Coupled Plasma Optical Emission Spectrometer (ICP OES) analysis was used to determine the concentrations of metals present in the ferrite, which reached 6.5% (w/w) of Co. The optimal conditions for discoloring the dye were evaluated using a factorial design. Using CoFe2O4 as a catalyst, the best conditions for catalytic reaction were pH 3, 30.0 mg of catalyst, and 8.0 mL of H2O2 73% (v/v). Discoloration efficiencies of 87.3% and 87.7% were obtained from CoFe2O4-R and CoFe2O4-LIBs, respectively. Therefore, CoFe2O4-LIBs proved to be an efficient catalyst for discoloring MB dye using heterogeneous photo-Fenton reactions. This work is of scientific, social, economic, and environmental interest. It investigates the process of synthesizing,characterizing CoFe2O4LIBs and the efficiency of degrading MB dye, subjects that have economic and environmental, and therefore, social interest. The work has scientific interest particularly because of the correlation between the structure of the recycled material and its catalytic properties.
Nanoparticles of CoFe2O4 synthesized using the cathodes of LIBs as raw materials. Display omitted
•Cobalt was recycled from spent lithium ion batteries to synthesize CoFe2O4.•Nanoparticles of CoFe2O4 with type spinel structures was synthesized.•CoFe2O4 was applied as a catalyst in heterogeneous photo Fenton reactions.•CoFe2O4 was characterized by XRD, SEM, TEM, and ICP OES techniques.
•Household slow sand filter is one of the most promising home scale treatments.•HSSF is efficient in improving drinking water quality in isolated communities.•Modification in the HSSF design and ...operation may encourage research.•There is a lack of literature on protozoa, cyanobacteria, and emerging pollutants.
Household, or point-of-use (POU), water treatments are effective alternatives to provide safe drinking water in locations isolated from a water treatment and distribution network. The household slow sand filter (HSSF) is amongst the most effective and promising POU alternatives available today. Since the development of the patented biosand filter in the early 1990s, the HSSF has undergone a number of modifications and adaptations to improve its performance, making it easier to operate and increase users’ acceptability. Consequently, several HSSF models are currently available, including those with alternative designs and constant operation, in addition to the patented ones. In this scenario, the present paper aims to provide a comprehensive overview from the earliest to the most recent publications on the HSSF design, operational parameters, removal mechanisms, efficiency, and field experiences. Based on a critical discussion, this paper will contribute to expanding the knowledge of HSSF in the peer-reviewed literature.
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Universalising actions aimed at water supply in rural communities and indigenous populations must focus on simple and low-cost technologies adapted to the local context. In this setting, this ...research studied the dynamic gravel filter (DGF) as a pre-treatment to household slow-sand filters (HSSFs), which is the first description of a household multistage filtration scale to treat drinking water. DGFs (with and without a non-woven blanket on top of the gravel layer) followed by HSSFs were tested. DGFs operated with a filtration rate of 3.21 m3 m−2.d−1 and HSSFs with 1.52 m3 m−2.d−1. Influent water contained kaolinite, humic acid and suspension of coliforms and protozoa. Physical-chemical parameters were evaluated, as well as Escherichia coli, Giardia spp. cysts and Cryptosporidium spp. oocyst reductions. Removal was low (up to 6.6%) concerning true colour, total organic carbon and absorbance (λ = 254 nm). Nevertheless, HMSFs showed turbidity decrease above 60%, E. coli reduction up to 1.78 log, Giardia cysts and Cryptosporidium oocysts reductions up to 3.15 log and 2.24 log, respectively. The non-woven blanket was shown as an important physical barrier to remove solids, E. coli and protozoa.
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•Household Multistage Filter removed over 60% of turbidity and 1.5 log of E. coli.•Dynamic Gravel Filter was an effective pre-treatment for household slow-sand filter.•Blanket improved the filtered water in gravel filter and household slow-sand filter.•Household Multistage Filter achieved more than 3 log of Giardia cyst reduction.•Household Multistage Filter obtained more than 2 log of Cryptosporidium oocyst reduction.
The consumption of probiotic-enriched dairy products has been associated with many health benefits, including anti-hyperglycemic activity. The effect on health is dependent on the type of probiotic ...culture used and the dairy product consumed. This study evaluated the effect of different probiotic-enriched dairy matrices (Minas Frescal cheese, Prato cheese, and whey dairy beverage) containing Lactobacillus casei on in vitro and in vivo anti-hyperglycemic activity. For this purpose, in vitro anti-hyperglycemic activity was determined by the inhibition of α-glucosidase and α-amylase activities, and a human study was performed with healthy individuals (n = 15, consumption of bread as a control; bread + Minas Frescal cheese; bread + Prato cheese; bread + dairy beverage) to assess the effects of different probiotic foods on postprandial glycemia. In vitro data showed that Prato cheese presented the highest lipid (36.9 g/100 g) and protein (26.5 g/100 g) contents as well as the highest α-amylase (60.7%) and α-glucosidase (52.6%) inhibition. The consumption of Prato cheese resulted in a lesser increase in blood glucose level (13 mg/dL) compared with the consumption of bread alone (19 mg/dL), Minas Frescal cheese (20 mg/dL), and whey dairy beverage (30 mg/dL), with glycemic indices similar to that observed for the control. The present results demonstrated a good correlation between in vitro and in vivo data, in which the type of dairy matrix affects the anti-hyperglycemic activity. It is concluded that the consumption of probiotic Prato cheese can contribute to the reduction of postprandial glycemia in healthy individuals.
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► This novel work addresses the level of intraspecific variability in the lipophosphoglycan (LPG) of Leishmania infantum. ► The polymorphism in this species was very low. ► It was ...found that there are three types of LPG in L. infantum.► All Leishmania parasites with different LPG types were able to sustain infection in Lutzomyia longipalpis. ► Higher nitric oxide production by murine macrophages was observed with LPG type II compared with types I and III.
Interspecies variations in lipophosphoglycan (LPG) have been the focus of intense study over the years due its role in specificity during sand fly-Leishmania interaction. This cell surface glycoconjugate is highly polymorphic among species with variations in sugars that branch off the conserved Gal(β1,4)Man(α1)-PO4 backbone of repeat units. However, the degree of intraspecies polymorphism in LPG of Leishmania infantum (syn. Leishmania chagasi) is not known. In this study, intraspecific variation in the repeat units of LPG was evaluated in 16 strains of L. infantum from Brazil, France, Algeria and Tunisia. The structural polymorphism in the L. infantum LPG repeat units was relatively slight and consisted of three types: type I does not have side chains; type II has one β-glucose residue that branches off the disaccharide-phosphate repeat units and type III has up to three glucose residues (oligo-glucosylated). The significance of these modifications was investigated during in vivo interaction of L. infantum with Lutzomyia longipalpis, and in vitro interaction of the parasites and respective LPGs with murine macrophages. There were no consequential differences in the parasite densities in sand fly midguts infected with Leishmania strains exhibiting type I, II and III LPGs. However, higher nitric oxide production was observed in macrophages exposed to glucosylated type II LPG.
The validation of many anuran species is based on a strictly descriptive, morphological analysis of a small number of specimens with a limited geographic distribution. The Scinax Wagler, 1830 genus ...is a controversial group with many doubtful taxa and taxonomic uncertainties, due a high number of cryptic species. One example is the pair of species Scinax constrictus and Scinax nebulosus, which share a similar morphology. Scinax constrictus is restricted to the Brazilian Cerrado savanna, while S. nebulosus is widely distributed throughout northern South America. Despite the validation of many anuran species, discriminations based only on morphological traits is quite difficult due to the high conservative morphology of some groups. In this context, the present study uses mitochondrial and nuclear genes to provide a more consistent diagnosis and test the validity of S. constrictus as a distinct species from S. nebulosus, as well as evaluate the position of these taxa within the Scinax genus. The topologies obtained herein uphold the monophyletic status of Scinax based on all molecular markers assessed in this study, in all analytical approaches, with high levels of statistical support.
Biomass is a potential energy source for the diversification of the Brazilian energy matrix. In this context, the biogas produced from the anaerobic digestion of residues is a relevant renewable ...resource that plays a significant role in the mitigation of environmental problems and the local generation of electric energy. This review presents the scenario of the biogas production and electricity distributed generation within the Brazilian context. Firstly, it presents an overview of the electric energy generation from biogas and the Brazilian plants that compose this electric matrix. Secondly, the main technologies to produce biogas and the possibilities of its use, followed by the comparison of technologies for distributed generation of electric energy from biogas in the Brazilian market. To illustrate the application of biogas technology, this paper presents a case study of a biogas plant operation and its connectivity to the grid, the Colombari Farm. The information presented here aims to enhance and to foment the recovering of biomass residues to produce biogas via anaerobic digestion and its utilization to generate electricity. Although the case study considers a specific plant in Brazil, the information and results presented can be applied to others areas of the country or regions of the world, so contributing to promote the expansion of biogas plants to generate electricity. Finally, a future perspectives section describes the practical implications of the biogas production and electricity generation in rural and urban areas and its contribution to the implementation of Brazilian environmental and social policies. This review also is useful to support the research development of biogas for electricity production.
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•Biogas applied Distributed Generation in the Brazilian Market.•Different types of biodigesters and its biogas production.•Technologies for biogas production and electric power generation.•Study of the first biogas generation plant: Colombari Farm at Parana, Brazil.
Considering that plasmid conjugation is a major driver for the dissemination of antimicrobial resistance in bacteria, this study aimed to investigate the effects of residual concentrations of ...antimicrobial growth promoters (AGPs) in poultry litter on the frequencies of IncFII‐FIB plasmid conjugation among Escherichia coli organisms. A 2 × 5 factorial trial was performed in vitro, using two types of litter materials (sugarcane bagasse and wood shavings) and five treatments of litter: non‐treated (CON), herbal alkaloid sanguinarine (SANG), AGPs monensin (MON), lincomycin (LCM) and virginiamycin (VIR). E. coli H2332 and E. coli J62 were used as donor and recipient strains, respectively. The presence of residues of monensin, lincomycin and virginiamycin increased the frequency of plasmid conjugation among E. coli in both types of litter materials. On the contrary, sanguinarine significantly reduced the frequency of conjugation among E. coli in sugarcane bagasse litter. The conjugation frequencies were significantly higher in wood shavings compared with sugarcane bagasse only in the presence of AGPs. Considering that the presence of AGPs in the litter can increase the conjugation of IncFII‐FIB plasmids carrying antimicrobial resistance genes, the real impact of this phenomenon on the dissemination of antimicrobial resistant bacteria in the poultry production chain must be investigated.
Significance and Impact of the Study: Although antimicrobial resistance represents an increasing threat to public health globally, information about the emergence and dissemination of antimicrobial resistant bacteria at the animal–environment interface is scarce. Conjugation is a process in which bacteria can transfer genes conferring resistance to other bacteria. This is an important phenomenon because genes are transferred through plasmids that may confer resistance to many antimicrobials at the same time. Our findings revealed that low concentrations of certain drugs in poultry litter increase conjugation rates of plasmids containing antimicrobial‐resistant genes among Escherichia coli, supporting the importance of drug stewardship practices for the control of antimicrobial transfer.
In this study, negative electrodes from spent Ni-Cd batteries were recycled as CdCO3, which was thermally treated to produce synthetized, nanostructured CdO. There is interest in CdO because of its ...energy band gap, high electrical conductivity and selective catalytic properties. CdO was characterized in this study by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and transmission electronic microscopy (TEM). The XRD pattern showed CdO peaks in a crystalline cubic phase, and the average crystallite diameter was 22.21 nm. TEM micrographs showed the formation of clusters containing nanostructures. We also tested the efficiency of CdO catalytic activity in degrading Reactive Black 5 (RB5) dye. Degradation was conducted in conditions of pH = 4.0, pH = 5.97 and pH = 8.0. The degradation efficiency was, respectively, 65.42%, 61.80% and 67.01% after 480 min of reaction. The determining step in the reaction mechanism for dye degradation was the formation of the radical ion OH. Therefore, the degradation exhibited a first-order reaction. The catalytic activity of CdO and the rate constant values were independent of the pH of the solution. This work presents potential solutions for two environmental problems: recycling Cd and dye degradation.
Recycling of spent Ni-Cd batteries as CdO nanoparticles. Display omitted
•This work presents solutions for Cd recycling and dye degradation.•Anodes of Ni-Cd batteries were recycled as CdO with nanometer-sized particles.•CdO presents catalytic activity in the degradation of reactive black dye.•Decoloration of reactive black dye exhibits first-order reaction.•The rate constant values are independent of the pH solution.
Abstract Cowpea (Vigna unguiculata (L.) Walp.) is a legume widely cultivated by small, medium and large producers in several Brazilian regions. However, one of the concerns for the production of ...cowpea in Brazil in recent years is the low rainfall activity in these regions, which generates the accumulation of salts on the surface. The objective of this work was to evaluate the effects of salt stress on growth parameters and enzyme activity in cowpea plants at different concentrations of brassinosteroids. Experiment was developed in a greenhouse using a completely randomized experimental design in a 3 x 3 factorial scheme. The treatments consisted of three levels of brassinosteroids (0, 3 and 6 µM EBL) and three levels of salt stress (0, 50 and 100 mM NaCl). Growth factors (height, diameter and number of leaves) decreased in the saline condition. With the presence of brassinosteroid the height did not increase, but the number of leaves did, mainly in the saline dosage of 100 mM NaCl. In the variable membrane integrity, brassinosteroid was efficient in both salinity dosages, the same not happening with the relative water content, where the saline condition did not affect the amount of water in the vegetable, with the application of brassino it remained high, decreasing only at dosage 100 mM NaCl. The nitrate reductase enzyme was greatly affected in the root system even with the application of increasing doses of brassino. Therefore, brassinosteroids as a promoter of saline tolerance in cowpea seedlings was positive. The concentration of 3µM of EBL provided the most satisfactory effect in tolerating the deleterious effects of the saline condition. The same cannot be concluded for the concentration of 6µM of EBL that did not promote tolerance to some variables.
Resumo O feijão-caupi (Vigna unguiculata (L.) Walp.) é uma leguminosa amplamente cultivada por pequenos, médios e grandes produtores em diversas regiões brasileiras. No entanto, uma das preocupações para a produção de feijão-caupi no Brasil nos últimos anos é a baixa atividade pluviométrica nessas regiões, o que gera o acúmulo de sais na superfície. O objetivo deste trabalho foi avaliar os efeitos do estresse salino nos parâmetros de crescimento e atividade enzimática em plantas de feijão-caupi em diferentes concentrações de brassinosteróides. O experimento foi desenvolvido em casa de vegetação com delineamento experimental inteiramente casualizado em esquema fatorial 3 x 3. Os tratamentos consistiram de três níveis de brassinosteróides (0, 3 e 6 µM EBL) e três níveis de estresse salino (0, 50 e 100 mM NaCl). Os fatores de crescimento (altura, diâmetro e número de folhas) diminuíram na condição salina. Com a presença do brassinosteroide a altura não aumentou, mas o número de folhas sim, principalmente na dosagem salina de 100 mM NaCl. Na variável integridade de membrana, o brassinosteróide foi eficiente em ambas as dosagens de salinidade, o mesmo não ocorrendo com o teor relativo de água, onde a condição salina não afetou a quantidade de água na hortaliça, com a aplicação de brassino manteve-se elevada, diminuindo apenas na dosagem de NaCl 100 mM. A enzima nitrato redutase foi bastante afetada no sistema radicular mesmo com a aplicação de doses crescentes de brassino. Portanto, o uso de brassinosteroides como promotor de tolerância salina em plântulas de feijão-caupi foi positivo. A concentração de 3µM de EBL proporcionou o efeito mais satisfatório em tolerar os efeitos deletérios da condição salina. O mesmo não pode ser concluído para a concentração de 6µM de EBL que não promoveu tolerância a algumas variáveis.
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