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•Magnetic cellulose powders were derived from agricultural waste Juncus effusus fiber.•Magnetic cellulose powers were used for purification of dye-contaminated ethanol-water ...mixture.•99.9 % of adsorption efficiency should be corrected as Excellent adsorption efficiency.
Eco-friendly ethanol (EtOH)-water (H2O) mixture has demonstrated huge potential in the textile industry. However, the uncontrolled discharge of dye-contaminated EtOH-H2O mixture to the ecosystem has numerous adverse effects. Herein, a sustainable approach utilizing the agricultural waste biomass-Juncus effusus (JE) to synthesize magnetic cellulose JE powders (M-JEPs) has been proposed for purification of dye-contaminated EtOH-H2O mixture. Batch experiments and physical-chemical analyses were performed to explore the adsorption performance and mechanism. The as-prepared cellulose M-JEPs exhibited ultrafast adsorption performance, which can reach the adsorption equilibrium within 10 min. The adsorption isotherms and kinetics demonstrated that the adsorption fitted well with the Langmuir isotherm and pseudo-second-order kinetic models, exhibiting the maximum adsorption capacity towards C.I. Reactive Red 195 and C.I. Reactive Blue 222 of 58.21 mg/g and 86.06 mg/g at the temperature of 303K. These findings indicate the feasibility of using cellulose M-JEPs for rapid purification of the dye-contaminated EtOH-H2O mixture.
Carbon fibers (CFs) have attracted attention in the automotive, aviation, and aerospace industries. However, the coloration of CFs is challenging due to their brittleness, inertness, complexity, and ...time/energy-intensive processes. Herein, inspired by the naturally grown protrusive nanostructures on the green central surface of peacock back feathers, we report an in-situ self-growing strategy for developing carbon spheres (CSs) on the CFs surface to achieve color tuning. This is achieved via the dynamic growth of CSs using glucose as the feeding material. Combined with the coloration process, the interaction between CSs and CFs promotes stable interfacial forces in integrated molding. This strategy allows the coloring system to continuously vary its color in a designated manner, thereby, endowing it with satisfactory mechanical robustness, acid durability, and light fastness. We anticipate this developed approach can be potentially competitive in the color construction of CFs with multi-colors due to its low-cost manufacturing.
Photodegradation shows a potential strategy for alleviating the excessive antibiotics crisis. The synergistic effect of various metal compounds immobilized on conductive substrates has been ...considered for wastewater treatment. However, developing a facile and universal approach for rational design and enhancing photocatalytic properties has endured extreme challenges. Herein, we develop a strategy to facilitate the photocatalytic reactions by designing a composite architecture of ZIF–8 ligand binding to the in–situ synthesis ZnO seed layer on carbon fiber. In this architecture, the dissolution and release of the seed layer in the excessive 2–Methylimidazole methanol solution were used as the binder to enhance the interplay between organic ligand and substrate. As an evaluated system for antibiotic contaminants, the photodegradation of tetracycline hydrochloride was performed with a removal efficiency of 88.47% (TC = 50 mg/L, pH = 4, 0.08 g of photocatalyst, illumination within 100 min). Moreover, the photocatalyst exhibited a steady photocatalytic activity (75.0%) after five cycles. The present work demonstrated a strategy for enhancing the photocatalytic performances of carbon fiber and accordingly provided useful perception into the design of the synergistic structure.
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•EtOH-CCl4-H2O ternary solvent system was used for reactive dyeing of wool.•Chemical damage of wool fibers was reduced.•Water consumption and effluents discharge were reduced using ...the proposed method.
Severe effluent pollution and chemical damage to protein fibers generated from conventional aqueous dyeing process have stimulated interest in exploiting sustainable dyeing of wool. Herein, an ethanol (EtOH)-carbon tetrachloride (CCl4)-water (H2O) ternary solvent system was used as the dyeing medium to protect wool fibers from being damaged in the dyeing process. The wool fibers were firstly pretreated in an aqueous acid solution, followed by dyeing in the EtOH-CCl4-H2O (45:50:5) ternary solvent system with reactive dyes. The results indicated that the acid pretreatment solution could be reused for several times, the samples dyed in the EtOH-CCl4-H2O mixture with the investigated dyes showed higher K/S values compared to the conventional approach, implying the increased dye utilization and decreased effluents discharge were realized. Furthermore, acceptable permeability, good colorfastness, and satisfactory leveling properties of the dyed samples were achieved using the developed method. Additionally, the solvent-assisted dyed samples showed improved mechanical properties compared with the conventionally dyed samples. The dyeing mechanisms of wool fibers in the EtOH-CCl4-H2O mixture were illustrated in detail. The proposed dyeing technology consumes fewer energy, freshwater, and chemicals compared with the conventional wool dyeing method. Future work will principally concentrate on the reuse of the dye-contaminated EtOH-CCl4-H2O mixture.
As a natural polymer, leather and its associated industries are known to be the leading economic sector in many countries. However, the huge amounts of leather waste generated from the leather ...industry causes severe environmental pollution. Herein, cow leather (CL) powders were prepared using a homemade machine and used as a low-cost adsorbent for the effective removal of reactive dyes from wastewater. The as-prepared CL powders exhibited dot-like, rod-like, and fiber-like morphologies. A Fourier transform infrared analysis and an x-ray diffraction analysis demonstrated that the CL powders retained the main structure of the protein contained in it. In addition, an improvement in thermal stability was also observed for the CL powders. Dye adsorption experiments indicate that the CL powders showed the highly effective removal of C.I. Reactive Red 120 (RR120), C.I. Reactive Yellow 127 (RY127), and C.I. Reactive Blue 222 (RB222) with the adsorption capacity of 167.0, 178.9, and 129.6 mg·g
, respectively. The Langmuir, pseudo-second order, and intraparticle diffusion models could well depict the adsorption equilibrium and kinetics of CL powders toward the investigated reactive dyes. The as-prepared CL powders can be used as a potential adsorbent in the treatment of dye contaminated wastewater. Future studies will mainly focus on the application of the adsorbed CL powders for the pigment printing of textile materials.
Conventional cellulose diacetate filter tips of cigarette (CDFTC) are poor filtration performance of toxic compounds. However, environmentally benign filter tips can be made by replacing cellulose ...diacetate fibers with various types of natural fibers. In the present work, the blocking and filtering effect of natural fibers such as cotton and wool was examined with regards to the polycyclic aromatic hydrocarbons (PAHs) present cigarette smoke. Using various techniques, including scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and Fluorescence detection, the blocking and filtering mechanisms were investigated in detail. The results showed that compared with CDFTC, the filter tips made from natural fibers (cotton or wool) were investigated superior at filtering out toxic particles, which is mainly due to the natural twist or crimp along with their longitudinal directions. The efficiency of PHAs removal by the cotton and wool fibers reached 71.0% (with absorption of up to 71.0 µg cig
−1
) and 60.5% (with absorption of up to 60.5 µg cig
−1
), respectively. Compared with the Zhongnanhai filter tip used in this study (54.0%), the filtration efficiency of the cotton and wool fibers was increased by 17.0% and 6.5%, respectively.
Accurately forecasting the influence of disturbances in High-Speed Railways (HSR) has great significance for improving real-time train dispatching and operation management. In this paper, we show how ...to use historical train operation records to estimate the influence of high-speed train disturbances (HSTD), including the number of affected trains (NAT) and total delayed time (TDT), considering the timetable and disturbance characteristics. We first extracted data about the disturbances and their affected train groups from historical train operation records of Wuhan-Guangzhou (W-G) HSR in China. Then, in order to recognize the concatenations and differences of disturbances, we used a K-Means clustering algorithm to classify them into four categories. Next, parametric and nonparametric density estimation approaches were applied to fit the distributions of NAT and TDT of each clustered category, and the goodness-of-fit testing results showed that Log-normal and Gamma distribution probability densities are the best functions to approximate the distribution of NAT and TDT of different disturbance clusters. Specifically, the validation results show that the proposed models accurately revealed the characteristics of HSTD and that these models can be used in real-time dispatch to predict the NAT and TDT, once the basic features of disturbances are known.
Primulina cangwuensis X. Hong & F. Wen (Gesneriaceae), a new species growing in rocky crevices on a limestone hill in Guangxi, China, is described and illustrated. It is morphologically similar to P. ...repanda, P. subulata, P. jianghuaensis and P. lobulata, but can be distinguished from its congeners by the different shape of leaves, bracts and calyx, as well as by the different indumentum of pedicels and stamens.
The leakage reactance of the compensation transformer in Dynamic Voltage Restorer (DVR) has no corresponding national standards. The paper proposes the LCL filter composed of leakage inductance of ...the transformer and the LC filter at the arm side. According to the design requirements of LCL filter, the transformer leakage inductance and impedance voltage drop are determined, and the parameter selection principles of LCL filter are analyzed combined with the characteristics of DVR. Using the method, the simulations and experimental results of 30 kVA capacity of DVR voltage drop compensation demonstrate that the method can meet the performance indicators, and the harmonic distortion rate of gird voltage after the compensation is less than 5%.
is a new species of Gesneriaceae from Yunnan, China and is described and illustrated here. It is morphologically similar to
,
and
, but the congeners of this new taxon can be distinguished by several ...salient characters. A description of
, together with illustrations and photographs, a distribution map and conservation assessment are presented.
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