Open systems of coupled qubits are ubiquitous in quantum physics. Finding a suitable master equation to describe their dynamics is therefore a crucial task that must be addressed with utmost ...attention. In the recent past, many efforts have been made toward the possibility of employing local master equations, which compute the interaction with the environment neglecting the direct coupling between the qubits, and for this reason may be easier to solve. Here, we provide a detailed derivation of the Markovian master equation for two coupled qubits interacting with common and separate baths, considering pure dephasing as well as dissipation. Then, we explore the differences between the local and global master equation, showing that they intrinsically depend on the way we apply the secular approximation. Our results prove that the global approach with partial secular approximation always provides the most accurate choice for the master equation when Born-Markov approximations hold, even for small inter-system coupling constants. Using different master equations we compute the stationary heat current between two separate baths, the entanglement dynamics generated by a common bath, and the emergence of spontaneous synchronization, showing the importance of the accurate choice of approach.
Synchronization phenomena have been recently reported in the quantum realm at the atomic level due to collective dissipation. In this work we propose a dimer lattice of trapped atoms realizing a ...dissipative spin model where quantum synchronization occurs instead in the presence of local dissipation. Atom synchronization is enabled by the inhomogeneity of staggered local losses in the lattice and is favored by an increase of spins detuning. A comprehensive approach to quantum synchronization based on different measures considered in the literature allows us to identify the main features of different synchronization regimes.
We explore the possibility of enhancing the performance of small thermal machines by the presence of common noise sources. In particular, we study a prototypical model for an autonomous quantum ...refrigerator comprised by three qubits coupled to thermal reservoirs at different temperatures. Our results show that engineering the coupling to the reservoirs to act as common environments lead to relevant improvements in the performance. The enhancements arrive to almost double the cooling power of the original fridge without compromising its efficiency. The greater enhancements are obtained when the refrigerator may benefit from the presence of a decoherence-free subspace. The influence of coherent effects in the dissipation due to one- and two-spin correlated processes is also examined by comparison with an equivalent incoherent yet correlated model of dissipation.
Closed quantum systems exhibit different dynamical regimes, like many-body localization or thermalization, which determine the mechanisms of spread and processing of information. Here we address the ...impact of these dynamical phases in quantum reservoir computing, an unconventional computing paradigm recently extended into the quantum regime that exploits dynamical systems to solve nonlinear and temporal tasks. We establish that the thermal phase is naturally adapted to the requirements of quantum reservoir computing and report an increased performance at the thermalization transition for the studied tasks. Uncovering the underlying physical mechanisms behind optimal information processing capabilities of spin networks is essential for future experimental implementations and provides a new perspective on dynamical phases.
Abstract
Quantum reservoir computing aims at harnessing the rich dynamics of quantum systems for machine-learning purposes. It can be used for online time series processing while having a remarkably ...low training cost. Here, we establish the potential of continuous-variable Gaussian states of linear dynamical systems for quantum reservoir computing. We prove that Gaussian resources are enough for universal reservoir computing. We find that encoding the input into Gaussian states is both a source and a means to tune the nonlinearity of the overall input-output map. We further show that the full potential of the proposed model can be reached by encoding to quantum fluctuations, such as squeezed vacuum, instead of classical fields or thermal fluctuations. Our results introduce a research paradigm for reservoir computing harnessing quantum systems and engineered Gaussian quantum states.
In this study, the ligands 23,24-dihydroxy-3,6,9,12-tetraazatricyclo17.3.1.1(14,18)eicosatetra-1(23),14,16,18(24),19,21-hexaene,
, and ...26,27-dihidroxy-3,6,9,12,15-pentaazatricyclo20.3.1.1(17,21)eicosaepta-1(26),17,19,21(27),22,24-hexaene,
, were synthesized: they represent a new class of molecules containing a biphenol unit inserted into a macrocyclic polyamine fragment. The previously synthesized
is obtained herein with a more advantageous procedure. The acid-base and Zn(II)-binding properties of
and
were investigated through potentiometric, UV-Vis, and fluorescence studies, revealing their possible use as chemosensors of H
and Zn(II). The new peculiar design of
and
afforded the formation in an aqueous solution of stable Zn(II) mono (LogK 12.14 and 12.98 for
and
, respectively) and dinuclear (LogK 10.16 for
) complexes, which can be in turn exploited as metallo-receptors for the binding of external guests, such as the popular herbicide glyphosate (
-(phosphonomethyl)glycine, PMG) and its primary metabolite, the aminomethylphosphonic acid (AMPA). Potentiometric studies revealed that PMG forms more stable complexes than AMPA with both
- and
-Zn(II) complexes, moreover PMG showed higher affinity for
than for
. Fluorescence studies showed instead that the
-Zn(II) complex could signal the presence of AMPA through a partial quenching of the fluorescence emission. These studies unveiled therefore the utility of polyamino-phenolic ligands in the design of promising metallo-receptors for elusive environmental targets.
The synthetic polymers used to protect artworks from deterioration process can be colonized by the fungi and bacteria responsible for the biodeterioration process. In this study, the susceptibility ...of synthetic polyacrylics and polyurethane resins to microorganisms (Aspergillus niger ATCC 9642, Aureobasidium pullulans ATCC 15233, Chaetomium globosum ATCC 6205, Cladosporium cladosporioides ATCC 16022, Alternaria alternata BC01, Penicillium citrinum LS1 and Pseudomonas aeruginosa ATCC 9027) was investigated. The microbial attack was simulated alone and with a biocide and the related growth was observed up to 21 days for bacteria and 28 days for fungi. The polyacrylic and polyurethane resins were subjected to microbial attack, regardless of the biocide treatment, with a fungal growth from 60% to the complete coverage of the plate surface. Penicillium citrinum showed the greatest adaptation ability and was found in all the examined resins. P. aeruginosa was visible in all the different resins, regardless of the presence of biocide. An environmental scanning electron microscope (ESEM) revealed the presence of fungal conidia and hyphae in the inoculated resins and the Fourier transform IR spectroscopy (FTIR-ATR) indicated chemical transformations in the IR spectra, particularly the hydrolysis of esters, with some differences between the polyacrylic and polyurethane resins, which were probably due to their different chemical features. Overall, our data stress that the chemical, physical and biological deterioration caused by microorganisms capable of degrading synthetic polymers is still a problem in art restoration and that new strategies must be considered to counteract this phenomenon.
Metastable quantum entrainment Cabot, Albert; Giorgi, Gian Luca; Zambrini, Roberta
New journal of physics,
10/2021, Letnik:
23, Številka:
10
Journal Article
Recenzirano
Odprti dostop
Quantum van der Pol oscillators are driven-dissipative systems displaying quantum synchronization phenomena. When forced by a squeezed drive, the frequency adjusts to half of the forcing displaying ...multiple preferred phases. Here we analyze the physical origin of this entrained response, establishing a connection with metastability in open quantum systems. We report a dynamical regime characterized by a huge separation of time scales, in which a dynamical mode displays a lifetime that can be orders of magnitude larger than the rest. In this regime, the long-time dynamics is captured by an incoherent process between two metastable states, which correspond to the preferred phases of the synchronized oscillator. In fact, we show that quantum entrainment is here characterized by fluctuations driving an incoherent process between two metastable phases, which ultimately limits its temporal coherence when moving into the quantum regime. Finally, we discuss connections with the phenomena of dissipative phase transitions and transient synchronization in open quantum systems.
Under the Born–Markov approximation, a qubit system, such as a two-level atom, is known to undergo a memoryless decay of quantum coherence or excitation when weakly coupled to a featureless ...environment. Recently, it has been shown that unavoidable disorder in the environment is responsible for non-Markovian effects and information backflow from the environment into the system owing to Anderson localization. This turns disorder into a resource for enhancing non-Markovianity in the system–environment dynamics, which could be of relevance in cavity quantum electrodynamics. Here we consider the decoherence dynamics of a qubit weakly coupled to a two-dimensional bath with a nontrivial topological phase, such as a two-level atom embedded in a two-dimensional coupled-cavity array with a synthetic gauge field realizing a quantum-Hall bath, and show that Markovianity is protected against moderate disorder owing to the robustness of chiral edge modes in the quantum-Hall bath. Interestingly, switching off the gauge field, i.e., flipping the bath into a topological trivial phase, allows one to re-introduce non-Markovian effects. Such a result indicates that changing the topological phase of a bath by a tunable synthetic gauge field can be harnessed to control non-Markovian effects and quantum information backflow in a qubit-environment system.