Evidence from iron meteorites indicates that a large number of differentiated planetesimals formed early in Solar System history. These bodies should have had well-developed olivine-rich mantles and ...consequentially such materials ought to be abundant both as asteroids and meteorites, which they are not. To investigate this “Great Dunite Shortage” we have undertaken a geochemical and oxygen isotope study of main-group pallasites and dunitic rocks from mesosiderites.
Oxygen isotope analysis of 24 main-group pallasites (103 replicates) yielded a mean Δ17O value of −0.187±0.016‰ (2σ), which is fully resolved from the HED Δ17O value of −0.246±0.014 (2σ) obtained in our earlier study and demonstrates that both groups represent distinct populations and were derived from separate parent bodies. Our results show no evidence for Δ17O bimodality within the main-group pallasites, as suggested by a number of previous studies.
Olivine-rich materials from the Vaca Muerta, Mount Padbury and Lamont mesosiderites, and from two related dunites (NWA 2968 and NWA 3329), have Δ17O values within error of the mesosiderite average. This indicates that these olivine-rich materials are co-genetic with other mesosiderite clasts and are not fragments from an isotopically distinct pallasite-like impactor. Despite its extreme lithologic diversity the mesosiderite parent body was essentially homogeneous with respect to Δ17O, a feature best explained by an early phase of large-scale melting (magma ocean), followed by prolonged igneous differentiation.
Based on the results of magma ocean modeling studies, we infer that Mg-rich olivines in mesosiderites formed as cumulates in high-level chambers and do not represent samples of the underlying mantle. By analogy, recently documented Mg-rich olivines in howardites may have a similar origin.
Although the Dawn mission did not detect mesosiderite-like material on Vesta, evidence linking the mesosiderites and HEDs includes: (i) their nearly identical oxygen isotope compositions; (ii) the presence in both of coarse-grained Mg-rich olivines; (iii) both have synchronous Lu-Hf and Mn-Cr ages; (iv) there are compositional similarities between the metal in both; and (v) mesosiderite-like material has been identified in a howardite breccia. The source of the mesosiderites remains an outstanding question in meteorite science.
The underrepresentation of olivine-rich materials amongst both asteroids and meteorites results from a range of factors. However, evidence from pallasites and mesosiderites indicates that the most important reason for this olivine shortage lies in the early, catastrophic destruction of planetesimals in the terrestrial planet-forming region and the subsequent preferential loss of their olivine-rich mantles.
The Zag meteorite which is a thermally-metamorphosed H ordinary chondrite contains a primitive xenolithic clast that was accreted to the parent asteroid after metamorphism. The cm-sized clast ...contains abundant large organic grains or aggregates up to 20 μm in phyllosilicate-rich matrix. Here we report organic and isotope analyses of a large (~10 μm) OM aggregate in the Zag clast. The X-ray micro-spectroscopic technique revealed that the OM aggregate has sp2 dominated hydrocarbon networks with a lower abundance of heteroatoms than in IOM from primitive (CI,CM,CR) carbonaceous chondrites, and thus it is distinguished from most of the OM in carbonaceous meteorites. The OM aggregate has high D/H and (sup 15)N/(sup 14)N ratios (δD = 2,370 ± 74‰ and δ(sup 15)N = 696 ± 100‰), suggesting that it originated in a very cold environment such as the interstellar medium or outer region of the solar nebula, while the OM is embedded in carbonate-bearing matrix resulting from aqueous activities. Thus, the high D/H ratio must have been preserved during the extensive late-stage aqueous processing. It indicates that both the OM precursors and the water had high D/H ratios. Combined with (sup 16)O-poor nature of the clast, the OM aggregate and the clast are unique among known chondrite groups. We further propose that the clast possibly originated from D/P type asteroids or trans-Neptunian Objects.
Northwest Africa (NWA) 6112, Miller Range (MIL) 090206 (plus its pairs: MIL 090340 and MIL 090405), and Divnoe are olivine‐rich ungrouped achondrites. We investigated and compared their petrography, ...mineralogy, and olivine fabrics. We additionally measured the oxygen isotopic compositions of NWA 6112. They show similar petrography, mineralogy, and oxygen isotopic compositions and we concluded that these five meteorites are brachinite clan meteorites. We found that NWA 6112 and Divnoe had a c axis concentration pattern of olivine fabrics using electron backscattered diffraction (EBSD). NWA 6112 and Divnoe are suggested to have been exposed to magmatic melt flows during their crystallization on their parent body. On the other hand, the three MIL meteorites have b axis concentration patterns of olivine fabrics. This indicates that the three MIL meteorites may be cumulates where compaction of olivine grains was dominant. Alternatively, they formed as residues and were exposed to olivine compaction. The presence of two different olivine fabric patterns implies that the parent body(s) of brachinite clan meteorites experienced diverse igneous processes.
To better understand the role of aqueous alteration on the CR chondrite parent asteroid, a whole-rock oxygen isotopic study of 20 meteorites classified as Renazzo-like carbonaceous chondrites (CR) ...was conducted. The CR chondrites analyzed for their oxygen isotopes were Dhofar 1432, Elephant Moraine (EET) 87770, EET 92042, EET 96259, Gao-Guenie (b), Graves Nunataks (GRA) 95229, GRA 06100, Grosvenor Mountains (GRO) 95577, GRO 03116, LaPaz Ice Field (LAP) 02342, LAP 04720, Meteorite Hills (MET) 00426, North West Africa (NWA) 801, Pecora Escarpment (PCA) 91082, Queen Alexandra Range (QUE) 94603, QUE 99177, and Yamato-793495 (Y-793495). Three of the meteorites, Asuka-881595 (A-881595), GRA 98025, and MET 01017, were found not to be CR chondrites. The remaining samples concur petrographically and with the well-established oxygen-isotope mixing line for the CR chondrites. Their position along this mixing line is controlled both by the primary oxygen-isotopic composition of their individual components and their relative degree of aqueous alteration. Combined with literature data and that of this study, we recommend the slope for the CR-mixing line to be 0.70
±
0.04 (2σ), with a δ
17O-intercept of −2.23
±
0.14 (2σ).
Thin sections of Al Rais, Shişr 033, Renazzo, and all but 3 samples analyzed for oxygen isotopes were studied petrographically. The abundance of individual components is heterogeneous among the CR chondrites, but FeO-poor chondrules and matrix are the most abundant constituents and therefore, dominate the whole-rock isotopic composition. The potential accreted ice abundance, physico-chemical conditions of aqueous alteration (e.g. temperature and composition of the fluid) and its duration control the degree of alteration of individual CR chondrites. Combined with literature data, we suggest that LAP 02342 was exposed to lower temperature fluid during alteration than GRA 95229. With only two falls, terrestrial alteration of the CR chondrites complicates the interpretation of their whole rock isotopic composition, particularly in the most aqueously altered samples, and those with relatively higher matrix abundances. We report that QUE 99177 is the isotopically lightest whole rock CR chondrite known (δ
18O
=
−2.29‰, δ
17O
=
−4.08‰), possibly due to isotopically light unaltered matrix; which shows that the anhydrous component of the CR chondrites is isotopically lighter than previously thought. Although it experienced aqueous alteration, QUE 99177 provides the best approximation of the pristine CR-chondrite parent body’s oxygen-isotopic composition, before aqueous alteration took place. Using this value as a new upper limit on the anhydrous component of the CR chondrites, water/rock ratios were recalculated and found to be higher than previously thought; ratios now range from 0.281 to 1.157. We also find that, according to their oxygen isotopes, a large number of CR chondrites appear to be minimally aqueously altered; although sample heterogeneity complicates this interpretation.
Oxygen isotope measurements of a suite of 22 diogenites demonstrate that they have a restricted range of Δ17O values: −0.246±0.014(2σ). These results indicate that the diogenites form a single ...population consistent with a single parent body source, rather than multiple sources as has recently been suggested. Our previously published analysis of eucrites and cumulate eucrites (n=34) give very similar results to the diogenites, with ΔO17=−0.241±0.016‰(2σ) and confirm that diogenites and eucrites are from the same parent asteroid. The isotopic homogeneity displayed by diogenites, eucrites and cumulate eucrites, provides strong evidence for an early large-scale melting event on the HED parent body, possibly resulting in the formation of a magma ocean. The paradox, whereby diogenites show isotopic evidence in favor of global melting, but also geochemical features indicative of late stage interaction with eucritic crust, may reflect a rapid transition from global to serial magmatism on their parent body. The fact that all the lithologically varied HED units have an isotopically homogeneous composition supports the proposal that they are derived from a single, large, diverse asteroid, most likely 4 Vesta. The recent suggestion that the HEDs are not from Vesta, but instead represent material from the same asteroidal source as the main-group pallasites and IIIAB irons can be excluded by our oxygen isotope data.
•New oxygen isotope data shows that diogenites are homogeneous in terms of Δ17O.•HED Δ17O homogeneity was the result of early global, parent body, melting.•Our data is consistent with a single parent body source for the HEDs.•Oxygen isotope variation is consistent with 4 Vesta as the HED source asteroid.•Models for a common HED–IIIAB–pallasite source are not supported by our data.
Anfinogenov et al. (Anfinogenov et al. 2014. Icarus 243, 139–147) argue that a highly silicified gravelite sandstone referred to as “John’s stone” could be a fragment of the long-sought-after ...impactor from the 1908 Tunguska event. We have analyzed the oxygen isotopic composition of two distinct samples of John’s stone both kindly provided by Dr Yana Anfingenova. Both samples had very similar isotopic compositions, such that the average of the two was as follows: δ17O=6.67±0.15‰; δ18O=12.78±0.28‰; Δ17O=−0.01±0.01 (errors 1SD). This value is well within the range for samples of terrestrial quartz-bearing sedimentary and metamorphic rocks. John’s stone has an oxygen isotope composition and mineralogy that is unlike any known group of meteorites. If John’s stone is extraterrestrial this would imply that it represents a previously unknown type of meteorite, as suggested by Anfinogenov et al. However, since sandstones can only form on a parent body with liquid water and by inference, also an atmosphere, we argue that there are only two possible parent bodies in the Solar System: the Earth and Mars. Mars can be ruled out for several reasons, including the oxygen isotopic and noble gas composition of John’s stone, which is clearly distinct from martian meteorites. Consistent with the O study, the noble gases do not provide any evidence for an extraterrestrial origin of the samples. The lack of any cosmogenic noble gases (particularly striking in 3He, 21Ne, 38Ar) is consistent with a terrestrial origin or an extraterrestrial origin under large shielding.
Based on the combined evidence obtained in this study we infer that John’s stone is a terrestrial rock unrelated to the Tunguska impactor.
Oxygen isotopic compositions allow identification of potential parent bodies of extraterrestrial materials. We measured oxygen isotope ratios of 33 large (diameter >500μm) silicate melted ...micrometeorites (cosmic spherules) from Antarctica, using IR-laser fluorination coupled with mass spectrometry. It is the first time that this high-precision method is used on individual micrometeorites. The selected micrometeorites are representative of the influx of extraterrestrial materials to the Earth. Our results show that most micrometeorites are related to carbonaceous chondrites, which is consistent with previous studies. However, 20–50% of them seem to be related to CO/CV carbonaceous chondrites, whereas CM/CR carbonaceous chondrites were thought to be the main source for micrometeorites. Furthermore, ∼30% of measured samples have oxygen isotope ratios lying above the terrestrial fractionation line, which relates them to ordinary chondrites or other, as yet, unsampled parent bodies.
Maribo-A new CM fall from Denmark HAACK, Henning; GRAU, Thomas; BISCHOFF, Addi ...
Meteoritics & planetary science,
01/2012, Letnik:
47, Številka:
1
Journal Article
Recenzirano
– Maribo is a new Danish CM chondrite, which fell on January 17, 2009, at 19:08:28 CET. The fall was observed by many eye witnesses and recorded by a surveillance camera, an all sky camera, a few ...seismic stations, and by meteor radar observatories in Germany. A single fragment of Maribo with a dry weight of 25.8 g was found on March 4, 2009. The coarse‐grained components in Maribo include chondrules, fine‐grained olivine aggregates, large isolated lithic clasts, metals, and mineral fragments (often olivine), and rare Ca,Al‐rich inclusions. The components are typically rimmed by fine‐grained dust mantles. The matrix includes abundant dust rimmed fragments of tochilinite with a layered, fishbone‐like texture, tochilinite–cronstedtite intergrowths, sulfides, metals, and carbonates often intergrown with tochilinite. The oxygen isotopic composition: (δ17O = −1.27‰; δ18O = 4.96‰; Δ17O = −3.85‰) plots at the edge of the CM field, close to the CCAM line. The very low Δ17O and the presence of unaltered components suggest that Maribo is among the least altered CM chondrites. The bulk chemistry of Maribo is typical of CM chondrites. Trapped noble gases are similar in abundance and isotopic composition to other CM chondrites, stepwise heating data indicating the presence of gas components hosted by presolar diamond and silicon carbide. The organics in Maribo include components also seen in Murchison as well as nitrogen‐rich components unique to Maribo.
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