Thermodynamics, which describes vast systems, has been reconciled with small scales, relevant to single-molecule experiments, in resource theories. Resource theories have been used to model exchanges ...of energy and information. Recently, particle exchanges were modeled; and an umbrella family of thermodynamic resource theories was proposed to model diverse baths, interactions, and free energies. This paper motivates and details the family's structure and prospective applications. How to model electrochemical, gravitational, magnetic, and other thermodynamic systems is explained. Szilárd's engine and Landauer's Principle are generalized, as resourcefulness is shown to be convertible not only between information and gravitational energy, but also among diverse degrees of freedom. Extensive variables are associated with quantum operators that might fail to commute, introducing extra nonclassicality into thermodynamic resource theories. An early version of this paper partially motivated the later development of noncommutative thermalization. This generalization expands the theories' potential for modeling realistic systems with which small-scale statistical mechanics might be tested experimentally.
We review recent work on the foundations of thermodynamics in the light of quantum information theory. We adopt a resource-theoretic perspective, wherein thermodynamics is formulated as a theory of ...what agents can achieve under a particular restriction, namely, that the only state preparations and transformations that they can implement for free are those that are thermal at some fixed temperature. States that are out of thermal equilibrium are the resources. We consider the special case of this theory wherein all systems have trivial Hamiltonians (that is, all of their energy levels are degenerate). In this case, the only free operations are those that add noise to the system (or implement a reversible evolution) and the only nonequilibrium states are states of informational nonequilibrium, that is, states that deviate from the maximally mixed state. The degree of this deviation we call the state’s nonuniformity; it is the resource of interest here, the fuel that is consumed, for instance, in an erasure operation. We consider the different types of state conversion: exact and approximate, single-shot and asymptotic, catalytic and noncatalytic. In each case, we present the necessary and sufficient conditions for the conversion to be possible for any pair of states, emphasizing a geometrical representation of the conditions in terms of Lorenz curves. We also review the problem of quantifying the nonuniformity of a state, in particular through the use of generalized entropies, and that of quantifying the gap between the nonuniformity one must expend to achieve a single-shot state preparation or state conversion and the nonuniformity one can extract in the reverse operation. Quantum state-conversion problems in this resource theory can be shown to be always reducible to their classical counterparts, so that there are no inherently quantum-mechanical features arising in such problems. This body of work also demonstrates that the standard formulation of the second law of thermodynamics is inadequate as a criterion for deciding whether or not a given state transition is possible.
Abstract
The complexity of quantum states has become a key quantity of interest across various subfields of physics, from quantum computing to the theory of black holes. The evolution of generic ...quantum systems can be modelled by considering a collection of qubits subjected to sequences of random unitary gates. Here we investigate how the complexity of these random quantum circuits increases by considering how to construct a unitary operation from Haar-random two-qubit quantum gates. Implementing the unitary operation exactly requires a minimal number of gates—this is the operation’s exact circuit complexity. We prove a conjecture that this complexity grows linearly, before saturating when the number of applied gates reaches a threshold that grows exponentially with the number of qubits. Our proof overcomes difficulties in establishing lower bounds for the exact circuit complexity by combining differential topology and elementary algebraic geometry with an inductive construction of Clifford circuits.
Quantum advantage in postselected metrology Arvidsson-Shukur, David R M; Yunger Halpern, Nicole; Lepage, Hugo V ...
Nature communications,
07/2020, Letnik:
11, Številka:
1
Journal Article
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In every parameter-estimation experiment, the final measurement or the postprocessing incurs a cost. Postselection can improve the rate of Fisher information (the average information learned about an ...unknown parameter from a trial) to cost. We show that this improvement stems from the negativity of a particular quasiprobability distribution, a quantum extension of a probability distribution. In a classical theory, in which all observables commute, our quasiprobability distribution is real and nonnegative. In a quantum-mechanically noncommuting theory, nonclassicality manifests in negative or nonreal quasiprobabilities. Negative quasiprobabilities enable postselected experiments to outperform optimal postselection-free experiments: postselected quantum experiments can yield anomalously large information-cost rates. This advantage, we prove, is unrealizable in any classically commuting theory. Finally, we construct a preparation-and-postselection procedure that yields an arbitrarily large Fisher information. Our results establish the nonclassicality of a metrological advantage, leveraging our quasiprobability distribution as a mathematical tool.
Out-of-time-ordered correlators (OTOCs) have received considerable recent attention as qualitative witnesses of information scrambling in many-body quantum systems. Theoretical discussions of OTOCs ...typically focus on closed systems, raising the question of their suitability as scrambling witnesses in realistic open systems. We demonstrate empirically that the nonclassical negativity of the quasiprobability distribution (QPD) behind the OTOC is a more sensitive witness for scrambling than the OTOC itself. Nonclassical features of the QPD evolve with timescales that are robust with respect to decoherence and are immune to false positives caused by decoherence. To reach this conclusion, we numerically simulate spin-chain dynamics and three measurement protocols (the interferometric, quantum-clock, and weak-measurement schemes) for measuring OTOCs. We target experiments based on quantum-computing hardware such as superconducting qubits and trapped ions.
The grand canonical ensemble lies at the core of quantum and classical statistical mechanics. A small system thermalizes to this ensemble while exchanging heat and particles with a bath. A quantum ...system may exchange quantities represented by operators that fail to commute. Whether such a system thermalizes and what form the thermal state has are questions about truly quantum thermodynamics. Here we investigate this thermal state from three perspectives. First, we introduce an approximate microcanonical ensemble. If this ensemble characterizes the system-and-bath composite, tracing out the bath yields the system's thermal state. This state is expected to be the equilibrium point, we argue, of typical dynamics. Finally, we define a resource-theory model for thermodynamic exchanges of noncommuting observables. Complete passivity-the inability to extract work from equilibrium states-implies the thermal state's form, too. Our work opens new avenues into equilibrium in the presence of quantum noncommutation.
Thermodynamics has recently been extended to small scales with resource theories that model heat exchanges. Real physical systems exchange diverse quantities: heat, particles, angular momentum, etc. ...We generalize thermodynamic resource theories to exchanges of observables other than heat, to baths other than heat baths, and to free energies other than the Helmholtz free energy. These generalizations are illustrated with "grand-potential" theories that model movements of heat and particles. Free operations include unitaries that conserve energy and particle number. From this conservation law and from resource-theory principles, the grand-canonical form of the free states is derived. States are shown to form a quasiorder characterized by free operations, d majorization, the hypothesis-testing entropy, and rescaled Lorenz curves. We calculate the work distillable from-and we bound the work cost of creating-a state. These work quantities can differ but converge to the grand potential in the thermodynamic limit. Extending thermodynamic resource theories beyond heat baths, we open diverse realistic systems to modeling with one-shot statistical mechanics. Prospective applications such as electrochemical batteries are hoped to bridge one-shot theory to experiments.
Diverse many-body systems, from soap bubbles to suspensions to polymers, learn and remember patterns in the drives that push them far from equilibrium. This learning may be leveraged for computation, ...memory, and engineering. Until now, many-body learning has been detected with thermodynamic properties, such as work absorption and strain. We progress beyond these macroscopic properties first defined for equilibrium contexts: We quantify statistical mechanical learning using representation learning, a machine-learning model in which information squeezes through a bottleneck. By calculating properties of the bottleneck, we measure four facets of many-body systems' learning: classification ability, memory capacity, discrimination ability, and novelty detection. Numerical simulations of a classical spin glass illustrate our technique. This toolkit exposes self-organization that eludes detection by thermodynamic measures: Our toolkit more reliably and more precisely detects and quantifies learning by matter while providing a unifying framework for many-body learning.
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